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In complex systems with many degrees of freedom such as spin glass and biomolecular systems, conventional simulations in canonical ensemble suffer from the quasi-ergodicity problem. A simulation in generalized ensemble performs a random…

Statistical Mechanics · Physics 2008-06-24 Y. Okamoto

A class of trigonometric integrator is proposed for the constrained ring polymer Hamiltonian dynamics, arising from the path integral molecular dynamics. The integrator is formulated by the composition of flows, thereby integrating the…

Quantum Physics · Physics 2016-01-05 Yunfeng Xiong

We propose a Gaussian ensemble as a description of the long-time dynamics of isolated quantum integrable systems. Our approach extends the Generalized Gibbs Ensemble (GGE) by incorporating fluctuations of integrals of motion. It is…

Statistical Mechanics · Physics 2017-05-24 Hyungwon Kim , Anatoli Polkovnikov , Emil A. Yuzbashyan

We present a deterministic algorithm called contact density dynamics that generates any prescribed target distribution in the physical phase space. Akin to the famous model of Nos\'e-Hoover, our algorithm is based on a non-Hamiltonian…

Statistical Mechanics · Physics 2016-03-02 A. Bravetti , D. Tapias

An extended Hamiltonian approach to conduct isothermal-isobaric molecular dynamics simulations with full cell flexibility is presented. The components of the metric tensor are used as the fictitious degrees of freedom for the cell, thus…

Chemical Physics · Physics 2009-11-07 E. Hernandez

Geometric aspects play an important role in the construction and analysis of structure-preserving numerical methods for a wide variety of ordinary and partial differential equations. Here we review the development and theory of symplectic…

Numerical Analysis · Mathematics 2017-10-12 Ludwig Gauckler , Ernst Hairer , Christian Lubich

We consider geometric numerical integration algorithms for differential equations evolving on symmetric spaces. The integrators are constructed from canonical operations on the symmetric space, its Lie triple system (LTS), and the…

Numerical Analysis · Mathematics 2023-08-31 Hans Munthe-Kaas

This paper is concerned with geometric exponential energy-preserving integrators for solving charged-particle dynamics in a magnetic field from normal to strong regimes. We firstly formulate the scheme of the methods for the system in a…

Numerical Analysis · Mathematics 2021-12-17 Ting Li , Bin Wang

A simple deterministic and time reversal invariant type of thermostat is proposed to be used for computer simulations of classical systems. It acts on collisions with the walls of the container exclusively. It maps the incoming and outgoing…

Statistical Mechanics · Physics 2014-11-13 Henk van Beijeren

Hamiltonian systems of ordinary and partial differential equations are fundamental mathematical models spanning virtually all physical scales. A critical property for the robustness and stability of computational methods in such systems is…

Quantum Physics · Physics 2025-02-25 Hsuan-Cheng Wu , Xiantao Li

We propose explicit symplectic integrators of molecular dynamics (MD) algorithms for rigid-body molecules in the canonical and isothermal-isobaric ensembles. We also present a symplectic algorithm in the constant normal pressure and lateral…

Statistical Mechanics · Physics 2007-05-23 Hisashi Okumura , Satoru G. Itoh , Yuko Okamoto

We implement the statistically sound G-JF thermostat for Langevin Dynamics simulations into the ESPREesSo molecular package for large-scale simulations of soft matter systems. The implemented integration method is tested against the…

Computational Physics · Physics 2016-08-17 Evyatar Arad , Oded Farago , Niels Grønbech-Jensen

Studying single-particle dynamics over many periods of oscillations is a well-understood problem solved using symplectic integration. Such integration schemes derive their update sequence from an approximate Hamiltonian, guaranteeing that…

Computational Physics · Physics 2016-03-23 Stephen D. Webb

Generalized Langevin Equation (GLE) thermostats have been used very effectively as a tool to manipulate and optimize the sampling of thermodynamic ensembles and the associated static properties. Here we show that a similar, exquisite level…

Chemical Physics · Physics 2017-09-06 Mariana Rossi , Venkat Kapil , Michele Ceriotti

Numerical methods that preserve geometric invariants of the system, such as energy, momentum or the symplectic form, are called geometric integrators. In this paper we present a method to construct symplectic-momentum integrators for…

Numerical Analysis · Mathematics 2014-11-07 Leonardo Colombo , Sebastián Ferraro , David Martín de Diego

Simulation schemes that allow to change molecular representation in a subvolume of the simulation box while preserving the equilibrium with the surrounding introduce conceptual problems of thermodynamic consistency. In this work we present…

Statistical Mechanics · Physics 2010-03-31 Simon Poblete , Matej Praprotnik , Kurt Kremer , Luigi Delle Site

We suggest a numerical integration procedure for solving the equations of motion of certain classical spin systems which preserves the underlying symplectic structure of the phase space. Such symplectic integrators have been successfully…

Statistical Mechanics · Physics 2007-05-23 Robin Steinigeweg , Heinz-Jürgen Schmidt

It is often difficult to quantitatively determine if a new molecular simulation algorithm or software properly implements sampling of the desired thermodynamic ensemble. We present some simple statistical analysis procedures to allow…

Statistical Mechanics · Physics 2013-03-04 Michael R. Shirts

A strong analog classical simulation of general quantum evolution is proposed, which serves as a novel scheme in quantum computation and simulation. The scheme employs the approach of geometric quantum mechanics and quantum informational…

Quantum Physics · Physics 2017-03-16 Dong-Sheng Wang

A new approach is developed to integrate numerically the equations of motion for systems of interacting rigid polyatomic molecules. With the aid of a leapfrog framework, we directly involve principal angular velocities into the integration,…

Computational Physics · Physics 2007-05-23 Igor P. Omelyan