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Structural, impedance, ferroelectric and magnetic properties were examined in multiferroic Bi_{2}Fe_{4(1-x)}Co_{4x}O_{9} (0$\leq$x$\leq$0.02) ceramics synthesized via solid-state reaction method. X-ray diffraction analysis and Rietveld…

Materials Science · Physics 2016-05-06 S. R. Mohapatra , B. Sahu , M. Chandrasekhar , P. Kumar , S. D. Kaushik , S. Rath , A. K. Singh

Temperature dependent impedance spectroscopy enables the many contributions to the dielectric and resistive properties of condensed matter to be deconvoluted and characterized separately. We have achieved this for multiferroic epitaxial…

Strongly Correlated Electrons · Physics 2007-06-20 Rainer Schmidt , Wilma Eerenstein , Thomas Winiecki , Finlay D. Morrison , Paul A. Midgley

Advancing the functional performance of bismuth ferrite (BiFeO$_3$) requires precise control over phase stability and microstructure, challenges often complicated by secondary phase formation within the Bi$_2$O$_3$-Fe$_2$O$_3$ system. In…

Materials Science · Physics 2025-11-27 Subir Majumder , Paul Ben Ishai , Gilad Orr

NdFeO3 modified polycrystalline ceramics with composition (NdFeO3)0.1-(Ba0.7Sr0.3TiO3)0.9 (NFBST) ceramics have been synthesized via solid-state reaction route. The Rietveld refinement of the XRD data confirmed the existence of a tetragonal…

Materials Science · Physics 2019-06-26 Anumeet Kaur , Lakhwant Singh

In this paper the synthesis and study of the structural, morphological, electrical, magnetic and electronic properties of the LaBiFe2O6 novel material are reported. The material was produced using the standard ceramic method. The Rietveld…

Ba1-xMgx(Ti0.9Zr0.1)O3(x= 0.01 and 0.02) ceramics were prepared using the conventional solid state reaction. Rietveld refinement performed on X-ray diffraction patterns indicates that the samples are tetragonal crystal structure with P4mm…

Chemical Physics · Physics 2018-10-31 S Ben Moumen , A Neqali , B Asbani , D Mezzane , M Amjoud , E Choukri , Y Gagou , M El Marssi , I. Lukyanchuk

The complex dielectric permittivity of a sintered ceramic tablet consisting of 70.5 % $BiFeO_{3}$ and 27.7% $Bi_{2}Fe_{4}O_{9}$ was analyzed as a function of temperature from -120 {\deg}C to 230 {\deg}C. The results reveal a complicated…

Materials Science · Physics 2022-11-22 Gilad Orr , Andrey Gorychev , Paul Ben Ishai

Bi1-xLaxFe1-xMnxO3 (x = 0.000 - 0.300) ceramics prepared by the tartaric acid modified sol-gel technique have been studied to analyze the effect of composition driven structural transition on the magnetic properties of bismuth ferrite…

Materials Science · Physics 2014-11-25 Pawan Kumar , Manoranjan Kar

An impedance spectroscopy (IS) is a versatile tool to study the effect of grains (bulk), grain boundaries and electrode-electrolyte interface on dielectric and electrical properties of electro-ceramics. This study only focuses the high…

Materials Science · Physics 2014-07-30 Hitesh Borkar , M Tomar , Vinay Gupta , Ashok Kumar

A detailed temperature and pressure investigation on BiGdO$_{3}$ is carried out by means of dielectric constant, piezoelectric current, polarization-electric field loop, Raman scattering and x-ray diffraction measurements. Temperature…

In this work structural refinement, complex impedance spectroscopy, and Raman spectroscopy have been investigated on Na$_{0.5}$(Bi$_{1-x}$Dy$_x$)$_{0.5}$TiO$_3$ (xDyNBT) ceramic systems. The pure NBT, 2DyNBT and 5DyNBT compounds crystallize…

We report remarkable multiferroic effects in polycrystalline Bi2Fe4O9. High-resolution X-ray diffraction shows that this compound has orthorhombic structure. Magnetic measurements confirm an antiferromagnetic transition around 260 K. A…

Materials Science · Physics 2009-11-13 A. K. Singh , S. D. Kaushik , Brijesh Kumar , A. Venimadhav , P. K. Mishra , V. Siriguri , S. Patnaik

Dielectric response as a function of frequency for high-permittivity dielectric and ferroelectric materials is discussed emphasizing the dynamic behaviour in the microwave and infrared range. After introducing the usual modelling of the…

Materials Science · Physics 2008-12-18 Jan Petzelt , Stanislav Kamba

Bismuth ferrite, BiFeO3, is a multiferroic solid that is attracting increasing attention as a potential photocatalytic material, because the ferroelectric polarisation enhances the separation of photogenerated carriers. With the motivation…

Materials Science · Physics 2022-08-05 Shivani Grover , Keith T. Butler , Umesh V Waghmare , Ricardo Grau-Crespo

We present a detailed temperature and frequency dependence of the optical conductivity measured on clean high quality single crystals of URu$_{2}$Si$_{2}$ of $ac$- and $ab$-plane surfaces. Our data demonstrate the itinerant character of the…

Strongly Correlated Electrons · Physics 2016-12-19 N. Bachar , D. Stricker , S. Muleady , K. Wang , J. A. Mydosh , Y. K. Huang , D. van der Marel

We present the detailed study of the temperature dependent dielectric properties, impedance spectroscopy and electrical conductivity of LaV$_{1-x}$Nb$_x$O$_4$ ($x=$ 0-1) samples prepared by the solid-state reaction method. The dielectric…

Materials Science · Physics 2023-11-07 Ashok Kumar , Vikas N. Thakur , Ajay Kumar , Vinod Singh , Anita Dhaka , Rajendra S. Dhaka

The polycrystalline Bi1-xHoxFeO3 (x=0, 0.05, 0.1) compounds were synthesized by conventional solid-state route. Rietveld refinement reveals that all the compounds were stabilized in rhombohedral structure with R3c (IUCr No. 161) space…

Materials Science · Physics 2015-01-06 T. Durga Rao , T. Karthik , Adiraj Srinivas , Saket Asthana

Due to its multiferroic properties and narrow optical bandgap, Bismuth ferrite has been widely explored for spintronics, photovoltaics, and photocatalysis applications. Bismuth ferrite can be synthesized in various forms like bulk, thin…

Materials Science · Physics 2025-09-10 Naresh Prajapati , G. Surya Prakash , Manoj Kumar , Himanshu Pandey

We discuss the first infrared reflectivity measurement on a BiFeO3 single crystal between 5 K and room temperature. The 9 predicted ab-plane E phonon modes are fully and unambiguously determined. The frequencies of the 4 A1 c-axis phonons…

Materials Science · Physics 2011-11-10 R. P. S. M. Lobo , R. L. Moreira , D. Lebeugle , D. Colson

We report the high temperature dielectric and {\it ac} impedance spectroscopy investigation of Nb substituted LaCo$_{0.7}$Nb$_{0.3}$O$_3$ polycrystalline sample. The maximum dielectric constant value was observed $\approx$1400 at around…

Materials Science · Physics 2022-08-17 Vikas N. Thakur , Ajay Kumar , Aakash Kaushik , Guru Dutt Gupt , Rajendra S. Dhaka
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