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The recent discovery of superconductivity at 190~K in highly compressed H$_{2}$S is spectacular not only because it sets a record high critical temperature, but because it does so in a material that appears to be, and we argue here that it…

Superconductivity · Physics 2015-03-05 N. Bernstein , C. S. Hellberg , M. D. Johannes , I. I. Mazin , M. J. Mehl

The highest critical temperature of superconductivity Tc has been achieved in cuprates: 133 K at ambient pressure and 164 K at high pressures. As the nature of superconductivity in these materials is still not disclosed, the prospects for a…

Superconductivity · Physics 2014-12-02 A. P. Drozdov , M. I. Eremets , I. A. Troyan

The discovery of a record high superconducting transition temperature (Tc) of 288 K in a pressurized hydride inspires new hope to realize ambient condition superconductivity. Here, we give a perspective on the theoretical and experimental…

Superconductivity · Physics 2021-12-21 Dong Wang , Yang Ding , Ho-Kwang Mao

The rapid variation of the superconductivity Tc in hydride sulfur (H3S) under high pressure [A. Drozdov et al, Nature 525, 73 (2015); M. Einaga et al, arXiv: 1509.03156] in a vicinity Pcr=123GPa is interpreted in terms of the 1st order…

Superconductivity · Physics 2016-01-01 Lev P. Gor'kov , V. Z. Kresin

A superconductor is a material that can conduct electricity with no resistance below its critical temperature (Tc). The highest Tc that has been achieved in cuprates1 is 133 K at ambient pressure2 and 164 K at high pressures3. As the nature…

Superconductivity · Physics 2016-03-31 A. P. Drozdov , M. I. Eremets , I. A. Troyan , V. Ksenofontov , S. I. Shylin

Since the discovery of superconductivity at 200 K in H3S [1] similar or higher transition temperatures, Tcs, have been reported for various hydrogen-rich compounds under ultra-high pressures [2]. Superconductivity was experimentally proved…

At present, hydrogen-based compounds constitute one of the most promising classes of materials for applications as a phonon-mediated high-temperature superconductors. Herein, the behavior of the superconducting phase in tellurium hydride…

Superconductivity · Physics 2019-06-26 Tomasz P. Zemła , Klaudia M. Szczȩśniak , Adam Z. Kaczmarek , Svitlana V. Turchuk

Recently, an extremely high superconducting temperature (Tc) of ~200 K has been reported in the sulfur hydride system above 100 GPa. This result is supported by theoretical predictions and verified experimentally. The crystal structure of…

Due to the value of the isotope shift in sulfur hydrides, a phonon-mediated pairing scenario of superconductivity is generally accepted for these high-temperature superconductors which is consistent with the Bardeen-Cooper-Schrieffer (BCS)…

Superconductivity · Physics 2018-12-11 R. M. Méndez-Moreno

High pressure serves as a path finding tool towards novel structures, including those with very high Tc.The superconductivity in sulfur hydrides with record value (203 K) is caused by the phonon mechanism. However, the picture differs from…

Superconductivity · Physics 2018-02-14 Lev Gor'kov , Vladimir Kresin

Over the past six years (2015-2021), many superconducting hydrides with critical temperatures $T_{C}$ up to 250 K, which are currently record highs, have been discovered. Now we can already say that a special field of superconductivity has…

Hydrogen-sulfide (H2S) was studied by x-ray synchrotron diffraction (XRD) and Raman spectroscopy up to 150 GPa at 180-295 K and by quantum-mechanical variable-composition evolutionary simulations. The experiments show that H2S becomes…

A maximum superconductive transition temperature $T_\textrm{C}$ = 203.5 K has recently been reported for a sample of the binary compound tri-hydrogen sulfide (H$_\textrm{3}$S) prepared at high pressure and with room temperature annealing.…

Superconductivity · Physics 2017-03-14 Dale R. Harshman , Anthony T. Fiory

It is demonstrated that resistive transition at 203 K observed in metallic sulfur hydride system at high pressure can be magnetic (rather than superconducting (SC)) in nature. The onset temperature of genuine superconducting transition in…

Superconductivity · Physics 2015-10-02 L. S. Mazov

We calculate superconducting transition temperatures ($T_{\rm c}$) in sulfur hydrides H$_{2}$S and H$_{3}$S from first principles using the density functional theory for superconductors. At pressures of $\lesssim$150 GPa, the high values of…

Superconductivity · Physics 2015-07-08 Ryosuke Akashi , Mitsuaki Kawamura , Shinji Tsuneyuki , Yusuke Nomura , Ryotaro Arita

The discovery of superconductivity at 203 K in H3S brought attention back to conventional superconductors whose properties can be described by the Bardeen-Cooper-Schrieffer (BCS) and the Migdal-Eliashberg theories. These theories predict…

Recently BCS superconductivity at 203 K has been discovery in a highly compressed hydrogen sulfide. We use first-principles calculations to systematically examine the effects of partially substituting the chalcogen atoms on the…

Superconductivity · Physics 2016-06-29 Yanfeng Ge , Fan Zhang , Yugui Yao

Hydrogen-rich compounds are extensively explored as candidates for a high-temperature superconductors. Currently, the measured critical temperature of $203$ K in hydrogen sulfide (H$_3$S) is among the highest over all-known superconductors.…

Superconductivity · Physics 2016-05-05 A. P. Durajski , R. Szczesniak , L. Pietronero

While great scientific efforts focus on the synthesis and studies of near-room-temperature (NRT) superconductors exhibited record superconducting transition temperatures (for instance, laser annealed H3S, LaH10 and YHn (n = 4,6,7,9) with Tc…

Superconductivity · Physics 2020-04-21 E. F. Talantsev

Recent discovery of high-temperature superconductivity (Tc = 190 K) in sulfur hydrides at megabar pressures breaks the traditional belief on the Tc limit of 40 K for conventional superconductors, and open up the doors in searching new…

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