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A criterium is derived to understand the relevance of thermal effects resulting from high rate mechanical actions on glass surface. The criterium is based on the concept of characteristic contact time of the load to the glass surface. This…

Materials Science · Physics 2023-04-18 Guglielmo Macrelli

A rigorous thermodynamic analysis has been done at the apparent horizon of a spatially flat Friedmann-Lemaitre-Robertson-Walker universe for the gravitationally induced particle creation scenario with constant specific entropy and an…

General Relativity and Quantum Cosmology · Physics 2019-10-24 Subhajit Saha , Anindita Mondal

Recent experiments and computer simulations show that supercooled liquids around the glass transition temperature are "dynamically heterogeneous" [1]. Such heterogeneity is expected from the random first order transition theory of the glass…

Disordered Systems and Neural Networks · Physics 2009-10-31 Xiaoyu Xia , Peter G. Wolynes

We clarify the relationship between freezing, melting, and the onset of glassy dynamics in a prototypical glass-forming mixture model. Our starting point is a precise operational definition of the onset of glassiness, as expressed by the…

Soft Condensed Matter · Physics 2025-02-20 Daniele Coslovich , Leonardo Galliano , Lorenzo Costigliola

Glass-forming liquids have only a modest tendency to crystallize and hence their dynamics can be studied even below the melting temperature. The relaxation dynamics of most of these liquids shows at a temperature $T_c$, somewhat above the…

Soft Condensed Matter · Physics 2025-01-17 Francesco Rusciano , Raffaele Pastore , Francesco Greco , Walter Kob

Rapid cooling of liquids below a certain temperature range can result in a transition to glassy states. The traditional understanding of glasses includes their thermodynamic metastability with respect to crystals. However, here we present…

Statistical Mechanics · Physics 2016-12-12 G. Zhang , F. H. Stillinger , S. Torquato

A quasi 2-dimensional recursive lattice formed by planar elements have been designed to investigate the surface thermodynamics of Ising spin glass system with the aim to study the metastability of supercooled liquids and the ideal glass…

Statistical Mechanics · Physics 2015-02-24 Ran Huang , Purushottam D. Gujrati

In this paper, with the corresponding formula for internal energy obtained in Ref. [J. Phys. Stud. {\bf 11}, 259 (2007)], combined with a simple calculation of the effective mass of interacting Bose particles, the behavior of the heat…

Quantum Gases · Physics 2011-10-19 I. O. Vakarchuk , V. S. Pastukhov , R. O. Prytula

We consider two non-mean-field models of structural glasses built on a hierarchical lattice. First, we consider a hierarchical version of the random energy model (HREM), and we prove the existence of the thermodynamic limit and…

Mathematical Physics · Physics 2014-09-09 Michele Castellana

We study thermodynamic and dynamic properties of a rigid model of the fragile glass forming liquid orthoterphenyl. A system of N=343 molecules is considered in a wide range of densities and temperatures, reaching simulation times up to 1…

Soft Condensed Matter · Physics 2009-11-07 S. Mossa , E. La Nave , H. E. Stanley , C. Donati , F. Sciortino , P. Tartaglia

The process of homogeneous crystal nucleation has been considered in a model liquid, where the interparticle interaction is described by a short-range spherical oscillatory potential. Mechanisms of initiating structural ordering in the…

Materials Science · Physics 2018-12-18 Bulat N. Galimzyanov , Dinar T. Yarullin , Anatolii V. Mokshin

Below the melting temperature $T_m$ crystals are the stable phase of typical elemental or molecular systems. However, cooling down a liquid below $T_m$, crystallization is anything but inevitable. The liquid can be supercooled, eventually…

Disordered Systems and Neural Networks · Physics 2017-03-07 M. Zanatta , L. Cormier , L. Hennet , C. Petrillo , F. Sacchetti

The classical nucleation equation, applied to two liquids, is completed by an additional enthalpy for solid supercluster formation governing the liquid and glass transformations. This model, successfully applied to d-mannitol, triphenyl…

Disordered Systems and Neural Networks · Physics 2020-02-19 Robert Felix Tournier

Glass stability (GS) indicates the glass reluctance or ability to crystallise upon heating; it can be characterised by several methods and parameters and is frequently used to retrieve glass-forming ability (GFA) of corresponding liquids as…

Geophysics · Physics 2018-03-01 G. Iezzi , A. L. Elbrecht , M. Davis , F. Vetere , V. Misiti , S. Mollo , A. Cavallo

The ro--vibrational spectra of molecules dissolved in liquid $^4$He nanodroplets display rotational structure. Where resolved, this structure has been used to determine a temperature that has been assumed to equal that of the intrinsic…

Chemical Physics · Physics 2009-11-10 Kevin K. Lehmann

Analysis of temperature dependence of structural relaxation time in supercooled liquids revealed a qualitatively distinct feature - a sharp, cusp-like maxumum in the second derivative of its logarithm. It suggests that the super-Arrhenius…

Soft Condensed Matter · Physics 2016-01-20 V. N. Novikov , A. P. Sokolov

Framing the glass formation within standard statistical mechanics is an outstanding problem of condensed matter theory. To provide new insight, we investigate the structural properties of the Lennard-Jones fluid in the very-low temperature…

Statistical Mechanics · Physics 2026-02-02 Bomont Jean-Marc , Bretonnet Jean-Louis , Costa Dino , Pastore Giorgio

Topological defects are typically quantified relative to ordered backgrounds. The importance of these defects to the understanding of physical phenomena including diverse equilibrium melting transitions from low temperature ordered to…

Statistical Mechanics · Physics 2019-02-19 Z. Nussinov , N. B. Weingartner , F. S. Nogueira

We propose a first principle computation of the equilibrium thermodynamics of simple fragile glasses starting from the two body interatomic potential. A replica formulation translates this problem into that of a gas of interacting…

Condensed Matter · Physics 2016-08-31 Marc Mezard , Giorgio Parisi

We develop a model for the thermodynamics and evaporation dynamics of aerosol droplets of a liquid such as water, surrounded by the gas. When the temperature and the chemical potential (or equivalently the humidity) are such that the vapour…

Soft Condensed Matter · Physics 2023-11-23 A. J. Archer , B. D. Goddard , R. Roth