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Transition-metal perovskite oxides constitute a series of functional material systems for electronics, catalysis and energy-conversion processes, in which oxygen migration and evolution play a key role. However, the stable metal-oxygen…

Materials Science · Physics 2021-11-02 Qian Wang , Youdi Gu , Wenxuan Zhu , Lei Han , Feng Pan , Cheng Song

Metallic oxide SrVO3 represents a prototype system for the study of the mechanism behind thickness-induced metal-to-insulator transition (MIT) or crossover in thin films due to its simple cubic symmetry with one electron in the 3d state in…

Strongly Correlated Electrons · Physics 2019-10-16 Gaomin Wang , Zhen Wang , Meng Meng , Mohammad Saghayezhian , Lina Chen , Chen Chen , Hangwen Guo , Yimei Zhu , Ward Plummer , Jiandi Zhang

Exotic electronic states are realized in novel quantum materials. This field is revolutionized by the topological classification of materials. Such compounds necessarily host unique states on their boundaries. Scanning tunneling microscopy…

Mesoscale and Nanoscale Physics · Physics 2021-09-01 Nurit Avraham , Jonathan Reiner , Abhay Kumar-Nayak , Noam Morali , Rajib Batabyal , Binghai Yan , Haim Beidenkopf

Organic-inorganic perovskite solar cells have attracted tremendous attention because of their remarkably high power conversion efficiencies (PCEs). To further improve the device performance, however, it is imperative to obtain fundamental…

Materials Science · Physics 2018-02-07 Zhaodong Chu , Mengjin Yang , Philip Schulz , Di Wu , Xin Ma , Edward Seifert , Liuyang Sun , Kai Zhu , Xiaoqin Li , Keji Lai

Drumhead surface states that link together loops of nodal lines arise in Dirac nodal-line semimetals as a consequence of the topologically non-trivial band crossings. We used low-temperature scanning tunneling microscopy and…

Recent research on perovskite solar cells has caught much attention for the application in renewable energy materials. However, the effect of external dopants on the performance of perovskite solar cell is yet to be understood properly.…

Materials Science · Physics 2024-01-18 Chongyao Yang , Wei Wu , Kwang-Leong Choy

For generation of sustainable, clean and highly efficient energy, the electrocatalytic oxygen evolution reaction represents an attractive platform, thus inviting immense research activities in recent years. However, designing the catalyst…

Halide perovskite semiconductors are a promising material for high-efficiency solar cells. Their optical properties can vary within and between crystallographic grains. We present spatially-resolved cathodoluminescence (CL) spectroscopy at…

The (001) surfaces of polar perovskites BaTiO$_3$ and PbTiO$_3$ have been studied from first principles at T=0 K. For both cases of polarization, the most stable TiO-terminated interfaces show intrinsic ferroelectricity. In the topmost…

Materials Science · Physics 2008-03-12 M. Fechner , S. Ostanin , I. Mertig

We have performed high resolution XPS experiments of the Ru(0001) surface, both clean and covered with well-defined amounts of oxygen up to 1 ML coverage. For the clean surface we detected two distinct components in the Ru 3d_{5/2} core…

The lattice constants of Strontium titanate perovskite has been studied using the Density functional theory formalism at the PBE and the HSE levels of theory. The study has been done in all the 3 existing phases; namely cubic, orthorhombic…

Materials Science · Physics 2021-12-22 Manaswita Kar

Motivated by recent realizations of Dy$_{2}$Ti$_{2}$O$_{7}$ and Ho$_{2}$Ti$_{2}$O$_{7}$ spin ice thin films, and more generally by the physics of confined gauge fields, we study a model of spin ice thin film with surfaces perpendicular to…

Statistical Mechanics · Physics 2017-05-24 L. D. C. Jaubert , T. Lin , T. S. Opel , P. C. W. Holdsworth , M. J. P. Gingras

Epitaxial strain is a proven route to enhancing the properties of complex oxides, however, the details of how the atomic structure accommodates strain are poorly understood due to the difficulty of measuring the oxygen positions in thin…

Materials Science · Physics 2015-05-18 S. J. May , J. -W. Kim , J. M. Rondinelli , E. Karapetrova , N. A. Spaldin , A. Bhattacharya , P. J. Ryan

Scanning tunneling microscopy visualizations of quasiparticle interference (QPI) enable powerful insights into the k-space properties of superconducting, topological, Rashba and other exotic electronic phases, but their reliance on…

First-principles total-energy calculations are carried out for (001) surfaces of the cubic perovskite ATiO3 compounds PbTiO3, BaTiO3, and SrTiO3. Both AO-terminated and TiO2-terminated surfaces are considered, and fully-relaxed atomic…

Materials Science · Physics 2015-06-25 B. Meyer , J. Padilla , David Vanderbilt

X-ray photoelectron spectroscopy and diffraction (XPS, XPD) and scanning tunneling microscopy (STM) have been used for study of NbOx-structures on the Nb(110) surface. It is shown that niobium atoms are ordered to form a two-dimensional…

Materials Science · Physics 2008-11-11 A. S. Razinkin , E. V. Shalaeva , M. V. Kuznetsov

SrTiO$_3$ (STO) is the substrate of choice to grow oxide thin-films and oxide heterojunctions, which can form quasi-two-dimensional electronic phases that exhibit a wealth of phenomena, and, thus, a workhorse in the emerging field of…

Strongly Correlated Electrons · Physics 2016-08-31 Soham S. Ghosh , Efstratios Manousakis

Scanning tunneling microscopy and spectroscopy are utilized to study the atomic-scale structure and electronic properties of infinite-layer Sr0.94La0.06CuO2+y films prepared on SrRuO3-buffered SrTiO3(001) substrate by ozone-assisted…

Superconductivity · Physics 2022-01-19 Rui-Feng Wang , Jiaqi Guan , Yan-Ling Xiong , Xue-Feng Zhang , Jia-Qi Fan , Jing Zhu , Can-Li Song , Xu-Cun Ma , Qi-Kun Xue

Oxygen vacancy ordering in perovskite-type transition-metal oxides plays an important role in the emergence of exotic electronic properties, as typified by superconducting cuprates. In this study, we predict the stability of…

Computational Physics · Physics 2020-04-15 Atsuto Seko , Shintaro Ishiwata

We present first-principles density-functional calculations using the local density approximation to investigate the structural instability of cubic perovskite BaBiO_3. This material might exhibit charge disproportionation and some evidence…

Other Condensed Matter · Physics 2007-05-23 T. Thonhauser , K. M. Rabe