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Tuning the thermal transport properties of hybrid halide perovskites is critical for their applications in optoelectronics, thermoelectrics, and photovoltaics. Here, we demonstrate an effective strategy to modulate the thermal transport…

Materials Science · Physics 2024-01-02 Guang Wang , Hongzhao Fan , Zhongwei Chen , Yufei Gao , Zuankai Wang , Zhigang Li , Haipeng Lu , Yanguang Zhou

Ruddlesden-Popper hybrid halide perovskite are quasi-two-dimensional materials with a layered structure and structural dynamics that are determined by the interplay between the organic and inorganic layers. While their optical properties…

Halide segregation in metal halide perovskites limits their bandgap tunability and hinders their adoption in tandem solar cells and light emitting diodes. Here, we reveal the thermodynamic driving force behind halide segregation in mixed…

Materials Science · Physics 2026-03-10 Abrar Fahim Navid , Zeeshan Ahmad

Over the last few years of the heyday of hybrid halide perovskites, so many metal cations additives have been tested to improve their optoelectronic properties that it is already difficult to find an element that has not yet been tried. In…

Organic-inorganic hybrid perovskites are considered to be most promising photovoltaic materials. Highest efficiencies of perovskite solar cells have been achieved by using appropriate cation and anion mixtures. Mixed perovskite solar cells…

Chemical Physics · Physics 2019-12-23 Gee Yeong Kim , Alessandro Senocrate , Yaru Wang , Davide Moia , Joachim Maier

Metal halide perovskites (MHPs) are nowadays one of the most studied semiconductors due to their exceptional performance as active layers in solar cells. Although MHPs are excellent solid-state semiconductors, they are also ionic compounds,…

It is now widely recognized that surface and interfacial defects exhibit distinct behavior compared to bulk defects in metal halide perovskites. However, the transition from bulk to surface behavior and the spatial extent of the surface's…

Materials Science · Physics 2024-12-23 Bilal Ahmad , Md Salman Rabbi Limon , Zeeshan Ahmad

We report modifications of the ferroelectric and electrocaloric properties of BaTiO$_3$ by defects. For this purpose, we have combined \textit{ab initio}-based molecular dynamics simulations with a simple model for defects. We find that…

Materials Science · Physics 2016-10-03 Anna Grünebohm , Takeshi Nishimatsu

The spin degree of freedom of charge carriers in halide-perovskite semiconductors can be highly useful for information photonics applications. The Faraday effect is known to be the best indicator of paramagnetism of the material and of the…

The perovskite crystal BaTiO3 is modeled using a first-principles based effective Hamiltonian and molecular dynamics simulations are performed to estimate the pyroelectric response. The electrocaloric temperature change, \DeltaT, is…

Materials Science · Physics 2012-08-30 S. P. Beckman , L. F. Wan , Jordan A. Barr , Takeshi Nishimatsu

Organolead halide perovskites have attracted substantial attention due to their excellent physical properties, which enable them to serve as the active material in emerging hybrid solid-state solar cells. Here we investigate the…

Materials Science · Physics 2015-10-28 Feng Li , Chun Ma , Hong Wang , Weijin Hu , Weili Yu , Arif D. Sheikh , Tom Wu

We report on the temperature dependence of thermal conductivity of single crystalline and polycrystalline organometallic perovskite CH3NH3PbI3. The comparable absolute values and temperature dependence of the two sample's morphologies…

An ab-initio calculation in the framework of DFT, as implemented in the FHI-aims package within GGA with the pbe parameterization was carried out in this work. Although methyl ammonium lead iodide, (CH3NH3PbI3) has proven to be an effective…

Materials Science · Physics 2018-06-29 Hassan Abdulsalam , Garba Babaji

Inorganic-organic perovskites semiconductors are becoming increasingly interesting due to their remarkable optical properties, such as a high photoluminescence quantum yield and the possibility to show optical gain in a broad range of…

Optics · Physics 2021-03-30 Michele Bellingeri , Francesco Scotognella

Instability of hybrid organic-inorganic halide perovskites hinders their development for photovoltaic applications. First-principle calculations are used for evaluation of a decomposition reaction enthalpy of hybrid halide perovskites,…

Materials Science · Physics 2017-06-19 Chao Zheng , Oleg Rubel

Solution-processed organic-inorganic lead halide perovskites have recently emerged as promising gain media for tunable semiconductor lasers, and have come to rival inorganic III-V group semiconductors as the material candidate for…

Halide perovskites make efficient solar cells due to their exceptional optoelectronic properties, but suffer from several stability issues. The characterization of the degradation processes is challenging because of the limitations in the…

Materials Science · Physics 2022-05-25 Mike Pols , José Manuel Vicent-Luna , Ivo Filot , Adri C. T. van Duin , Shuxia Tao

Due to their high photovoltaic efficiency and low-cost synthesis, lead halide perovskites have attracted wide interest for application in new solar cell technologies. The most stable and efficient ABX$_3$ perovskite solar cells employ mixed…

Materials Science · Physics 2023-05-23 Lucy D. Whalley

The role of data in modern materials science becomes more valuable and accurate when effects such as electron-phonon coupling and anharmonicity are included, providing a more realistic representation of finite-temperature material behavior.…

Lead-halide organic-inorganic perovskites consist of an inorganic host framework with an organic molecule occupying the interstitial space. The structure and dynamics of these materials have been heavily studied recently due to interest in…

Materials Science · Physics 2018-07-19 K. L. Brown , S. F. Parker , I. Robles Garcia , S. Mukhopadhyay , V. Garcia Sakai , C. Stock
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