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Nonadiabatic effects in chemical reaction at metal surfaces, due to excitation of electron-hole pairs, stand at the frontier of the studies of gas-surface reaction dynamics. However, the first principles description of electronic excitation…

Chemical Physics · Physics 2019-12-20 Yaolong Zhang , Reinhard J. Maurer , Bin Jiang

We review techniques for simulating fully quantum nonadiabatic dynamics using the frozen-width moving Gaussian basis functions to represent the nuclear wavefunction. A choice of these basis functions is primarily motivated by the idea of…

Chemical Physics · Physics 2018-09-05 Loïc Joubert-Doriol , Artur F. Izmaylov

The main concern of the present paper is the study of the multi-scale dynamics of thermonuclear fusion plasmas via a multi-species Fokker-Planck kinetic model. One of the goals is the generalization of the standard Fokker-Planck collision…

Numerical Analysis · Mathematics 2022-10-19 Francis Filbet , Claudia Negulescu

A generalized formalism of the so-called non-adiabatic quantum molecular dynamics is presented, which applies for atomic many-body systems in external laser fields. The theory treats the nuclear dynamics and electronic transitions…

Atomic Physics · Physics 2007-05-23 Thomas Kunert , Ruediger Schmidt

In this article we develop convergence theory for a general class of adaptive approximation algorithms for abstract nonlinear operator equations on Banach spaces, and use the theory to obtain convergence results for practical adaptive…

Numerical Analysis · Mathematics 2010-01-12 Michael Holst , Gantumur Tsogtgerel , Yunrong Zhu

We consider the electrons of a molecule in the adiabatic time-dependent density functional theory approximation. We establish the well-posedness of the time evolution and its linear response close to a non-degenerate ground state, and prove…

Analysis of PDEs · Mathematics 2024-09-19 Mi-Song Dupuy , Eloïse Letournel , Antoine Levitt

Bogoliubov's 1947 approximation, originally developed in the microscopic theory of superfluidity, laid the foundation for solving previously intractable quantum models and later became part of "quantum mathematics". Regarding mathematically…

Functional Analysis · Mathematics 2026-05-26 Jean-Bernard Bru , Walter de Siqueira Pedra , Artur Oscar Lopes

In this paper, we continue the development of a generic adiabatic scheme for nonlinear evolutions. We consider an abstract gradient flow of some energy functional, together with a given manifold of static solutions arising from broken…

Analysis of PDEs · Mathematics 2022-04-13 Jingxuan Zhang

We interpret the Lorentz force equation as a geodesic equation associated with a non-linear connection. Using a geometric averaging procedure, we prove that for narrow and smooth one-particle distribution functions whose supports are…

Mathematical Physics · Physics 2024-11-07 Ricardo Gallego Torrome

We show that recent results on adiabatic theory for interacting gapped many-body systems on finite lattices remain valid in the thermodynamic limit. More precisely, we prove a generalised super-adiabatic theorem for the automorphism group…

Mathematical Physics · Physics 2024-06-19 Joscha Henheik , Stefan Teufel

We present an analysis of the stimulated Raman adiabatic passage processes based on the methods of differential geometry. The present work was inspired by an excellent article by Bruce W. Shore et al. (R. G. Unanyan, B. W. Shore, and K.…

Atomic Physics · Physics 2022-11-23 Arturs Cinins , Martins Bruvelis , Nikolai N. Bezuglov

The nonlinear behaviour of low-viscosity warped discs is poorly understood. We verified a nonlinear bending-wave theory, in which fluid columns undergo affine transformations, with direct 3D hydrodynamical simulations. We employed a…

Earth and Planetary Astrophysics · Physics 2022-04-06 Hongping Deng , Gordon Ogilvie

We introduce a novel methodology for simulating the excited-state dynamics of extensive molecular aggregates in the framework of the long-range corrected time-dependent density-functional tight-binding fragment molecular orbital method…

Chemical Physics · Physics 2024-04-23 Richard Einsele , Roland Mitrić

We develop and test a method that integrates many-electron weak-field asymptotic theory (ME-WFAT) [Phys. Rev. A 89, 013421 (2014)] in the integral representation (IR) into the density functional theory (DFT) framework. In particular, we…

This paper is devoted to the analysis of an abstract formula describing quantum adiabatic charge pumping in a general context. We consider closed systems characterized by a slowly varying time-dependent Hamiltonian depending on an external…

Mathematical Physics · Physics 2010-02-08 A. Joye , V. Brosco , F. Hekking

Time-dependent density-functional theory (TDDFT) is a central tool for studying the dynamical electronic structure of molecules and solids, yet aspects of its mathematical foundations remain insufficiently understood. In this work, we…

We set up a general density-operator approach to geometric steady-state pumping through slowly driven open quantum systems. This approach applies to strongly interacting systems that are weakly coupled to multiple reservoirs at high…

Mesoscale and Nanoscale Physics · Physics 2017-05-11 T. Pluecker , M. R. Wegewijs , J. Splettstoesser

Thouless's quantum adiabatic pumping is of fundamental interest to condensed-matter physics. It originally considered a zero-temperature equilibrium state uniformly occupying all the bands below a Fermi surface. In the light of recent…

Quantum Physics · Physics 2015-12-16 Longwen Zhou , Da Yang Tan , Jiangbin Gong

The localized states within the Heisenberg model of magnetism should be represented by best localized Wannier functions forming a unitary transformation of the Bloch functions of the narrowest partly filled energy bands in the metals.…

Superconductivity · Physics 2009-10-31 Ekkehard Krüger

We develop a nonadiabatic theory of phonon magnetic moments applicable to both insulators and metals. By relating the phonon magnetic moment to the force-velocity response of ions in a magnetic field, we derive a gauge-invariant expression…

Mesoscale and Nanoscale Physics · Physics 2026-05-11 Haoran Chen , Wenqin Chen , Kaijie Yang , Ting Cao , Di Xiao