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Two new carbon allotropes (H-carbon and S-carbon) are proposed, as possible candidates for the intermediate superhard phases between graphite and diamond obtained in the process of cold compressing graphite, based on the results of…

Materials Science · Physics 2012-06-12 Chaoyu He , L. Z. Sun , C. X. Zhang , K. W. Zhang , Xiangyang Peng , Jianxin Zhong

Using evolutionary algorithm for crystal structure prediction, we present a new stable two-dimensional (2D) carbon allotrope composed of polymerized as-indacenes (PAI) in a zigzag pattern, namely PAI-graphene whose energy is lower than most…

Materials Science · Physics 2020-09-11 Xin Chen , Adrien Bouhon , Linyang Li , François M. Peeters , Biplab Sanyal

Organic-inorganic halide perovskite solar cells have recently attracted much attention due to their low-cost fabrication, flexibility, and high-power conversion efficiency. The reduction from three- to two-dimension (2D) promises an…

Materials Science · Physics 2018-07-24 Rahul Singh , Prashant Singh , Ganesh Balasubramanian

Stacking two-dimensional (2D) materials into multi-layers or heterostructures, known as van der Waals (vdW) epitaxy, is an essential degree of freedom for tuning their properties on demand. Few-layer black phosphorus (FLBP), a material with…

Materials Science · Physics 2016-02-17 Zhi-Xin Hu , Xianghua Kong , Jingsi Qiao , Bruce Normand , Wei Ji

Black phosphorus (BP), a layered van der Waals (vdW) crystal, has unique in-plane band anisotropy and many resulting anisotropy properties such as the effective mass, electron mobility, optical absorption, thermal conductivity and plasmonic…

Materials Science · Physics 2020-08-14 Zhimin Liu , Ye Yang , Yueshao Zheng , Qinjun Chen , Yexin Feng

We propose two novel two-dimensional topological Dirac materials, planar PtN4C2 and Pt2N8C6, which exhibit graphene-like electronic structures with linearly dispersive Dirac-cone states exactly at the Fermi level. Moreover, the Dirac cone…

Materials Science · Physics 2022-07-20 Jingping Dong , Chuhan Wang , Xinlei Zhao , Miao Gao , Xun-Wang Yan , Fengjie Ma , Zhong-Yi Lu

Three two-dimensional phosphorus nitride (PN) monolayer sheets (named as $\alpha$-, $\beta$-, and $\gamma$-PN, respectively) with fantastic structures and properties are predicted based on first-principles calculations. The $\alpha$-PN and…

Materials Science · Physics 2015-10-02 ShuangYing Ma , Chaoyu He , L. Z. Sun , Haiping Lin , Youyong Li , K. W. Zhang

Because of its novel physical properties, two-dimensional materials have attracted great attention. From first-principle calculations and vibration frequenceis analysis, we predict a new family of two-dimensional materials based on the idea…

Materials Science · Physics 2015-07-24 Jason Lee , Wen-Chuan Tian , Wei-Liang Wang , Dao-Xin Yao

A key challenge for computational discovery of electrocatalytic materials is the reliable prediction of thermodynamic stability in aqueous environment and under different electrochemical conditions. In this work, we first evaluate the…

Materials Science · Physics 2025-06-10 Stefano Americo , Ivano E. Castelli , Kristian S. Thygesen

Two-dimensional (2D) materials have attracted considerable attention due to their unique physicochemical properties and significant potential in energy-related applications. Polymeric carbon nitrides (PCNs) with 2D stacked architecture show…

Isolated oxygen impurities and fully oxidized structures of four stable two-dimensional (2D) SiS structures are investigated by {\em ab initio} density functional calculations. Binding energies of oxygen impurities for all the four 2D SiS…

Materials Science · Physics 2019-04-23 Zhengnan Li , Shuai Dong , Jie Guan

A single atomic layer of black phosphorus, phosphorene, was experimentally realized in 2014. It has a puckered honeycomb lattice structure and a semiconducting electronic structure. In the first part of this paper, we use a simple LCAO…

Mesoscale and Nanoscale Physics · Physics 2015-10-22 Shuhei Fukuoka , Toshihiro Taen , Toshihito Osada

Organic semiconductors tend to self-assemble into highly ordered and oriented morphologies with anisotropic optical properties. Studying these optical anisotropies provides insight into processing-dependent structural properties and informs…

Materials Science · Physics 2016-11-03 Steven J. Brown , Ruth A. Schlitz , Michael L. Chabinyc , Jon A. Schuller

We measured and calculated transmission spectra of two-dimensional quasiperiodic photonic crystals (PCs) based on a 5-fold (Penrose) or 8-fold (octagonal) symmetric quasiperiodic pattern. The photonic crystal consisted of dielectric…

Chalcogenide phase-change materials (PCMs) are regarded as the leading candidate for storage-class non-volatile memory and neuro-inspired computing. Recently, using the $TiTe_2$/$Sb_2Te_3$ material combination, a new framework -…

Materials Science · Physics 2021-07-20 Xudong Wang , Yue Wu , Yuxing Zhou , Volker L. Deringer , Wei Zhang

Low-dimensional multiferroicity, though highly scarce in nature, has attracted great attention due to both fundamental and technological interests. Using first-principles density functional theory, we show that ferromagnetism and…

Materials Science · Physics 2018-07-26 Jingshan Qi , Hua Wang , Xiaofang Chen , Xiaofeng Qian

Atomically thin black phosphorus (BP) is a promising two-dimensional material for fabricating electronic and optoelectronic nano-devices with high mobility and tunable bandgap structures. However, the charge-carrier mobility in few-layer…

Exfoliated black phosphorus has recently emerged as a new two-dimensional crystal that, due to its peculiar and anisotropic crystalline and electronic band structures, may have potentially important applications in electronics,…

A sp2-sp3 hybrid carbon allotrope named HSH-carbon is proposed by the first-principles calculations. The structure of HSH-carbon can be regarded as a template polymerization of [1.1.1]propellane molecules in a hexagonal lattice, as well as,…

Materials Science · Physics 2022-07-26 Jia-Qi Liu , Qian Gao , Zhen-Peng Hu

We substitute individual Pt atoms into monolayer MoS$_2$ and study the resulting atomic structures with single-sideband (SSB) ptychography supported by ab initio simulations. We demonstrate that while high-angle annular dark-field (HAADF)…

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