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Two path integral representations for the $T$-matrix in nonrelativistic potential scattering are derived and proved to produce the complete Born series when expanded to all orders. They are obtained with the help of "phantom" degrees of…

Nuclear Theory · Physics 2009-07-28 R. Rosenfelder

A new approach to the modeling of nonfree particle diffusion is presented. The approach uses a general setup based on geometric graphs (networks of curves), which means that particle diffusion in anything from arrays of barriers and pore…

Statistical Mechanics · Physics 2018-04-05 Niels Buhl

We introduce a quasiclassical Green function approach describing the unitary yet irreversible dynamics of quantum systems effectively acting as their own environment. Combining a variety of concepts of quantum many-body theory, notably the…

Mesoscale and Nanoscale Physics · Physics 2025-09-09 Alexander Altland , Kun Woo Kim , Tobias Micklitz

This paper presents an extended version of the article [Franz, S., Kopteva, N.: J. Differential Equations, 252 (2012)]. The main improvement compared to the latter is in that here we additionally estimate the mixed second-order derivative…

Analysis of PDEs · Mathematics 2022-12-23 Sebastian Franz , Natalia Kopteva

We propose a general theoretical description of chemical reactions occurring on a catalytic surface with heterogeneous reactivity. The propagator of a diffusion-reaction process with eventual absorption on the heterogeneous partially…

Chemical Physics · Physics 2019-11-05 Denis S. Grebenkov

We revisit the analysis of sharp infinite potentials within the path integral formalism using the image method [1]. We show that the use of a complete set of energy eigenstates that satisfy the boundary conditions of an infinite wall…

Quantum Physics · Physics 2011-12-19 Phillip Dluhy , Asim Gangopadhyaya

A theory of flame propagation in curved channels is developed within the framework of the on-shell description of premixed flames. Employing the Green function appropriate to the given channel geometry, an implicit integral representation…

Fluid Dynamics · Physics 2009-10-13 Hazem El-Rabii , Guy Joulin , Kirill A. Kazakov

We present the path integral formulation of a broad class of generalized diffusion processes. Employing the path integral we derive exact expressions for the path probability densities and joint probability distributions for the class of…

Statistical Mechanics · Physics 2011-10-27 Rudolf Friedrich , Stephan Eule

We expand on a previous study of fronts in finite particle number reaction-diffusion systems in the presence of a reaction rate gradient in the direction of the front motion. We study the system via reaction-diffusion equations, using the…

Statistical Mechanics · Physics 2009-11-11 Elisheva Cohen , David A. Kessler , Herbert Levine

We construct path integrals for stochastic hybrid reaction-diffusion (RD) processes, in which the reaction terms depend on the discrete state of a randomly switching environment. We proceed by spatially discretizing a given RD system and…

Statistical Mechanics · Physics 2021-10-15 Paul C. Bressloff

Path-integral methods can be used to derive a `path-decomposition expansion' for the temperature Green function of a magnetized free-electron gas confined by a hard wall. With the help of this expansion the asymptotic behaviour of the…

Statistical Mechanics · Physics 2009-10-31 M. M. Kettenis , L. G. Suttorp

We develop an encounter-based approach for describing restricted diffusion with a gradient drift towards a partially reactive boundary. For this purpose, we introduce an extension of the Dirichlet-to-Neumann operator and use its eigenbasis…

Chemical Physics · Physics 2022-10-10 Denis S. Grebenkov

We consider subdiffusion in a system which consists of two media separated by a thin membrane. The subdiffusion parameters may be different in each of the medium. Using the new method presented in this paper we derive the probabilities (the…

Statistical Mechanics · Physics 2016-11-30 Tadeusz Kosztołowicz

An integro differential equation which is able to describe the evolution of a large class of dissipative models, is considered. By means of an equivalence, the focus shifts to the perturbed sine- Gordon equation that in superconductivity…

Mathematical Physics · Physics 2025-03-04 Monica De Angelis

We propose an analytical method for understanding the problem of multi-channel electron transfer reaction in solution, modeled by a particle undergoing diffusive motion under the influence of one donor and several acceptor potentials. The…

Quantum Physics · Physics 2015-06-30 Aniruddha Chakraborty

For distinguishable particles it is well known that Brownian motion and a Feynman-Kac functional can be used to calculate the path integral (for imaginary times) for a general class of scalar potentials. In order to treat identical…

Condensed Matter · Physics 2009-10-28 L. F. Lemmens , F. Brosens , J. T. Devreese

The relativistic Green's function of a free spin-1/2 fermion is derived using the Feynman path integral formalism in spherical coordinates. The Green's function is reduced to an exactly solvable path integral by an appropriate coordinate…

Atomic Physics · Physics 2023-09-26 Sreya Banerjee , Zoltán Harman

Many chemical reactions can be formulated in terms of particle diffusion in a complex energy landscape. Transition path theory (TPT) is a theoretical framework for describing the direct (reaction) pathways from reactant to product states…

Statistical Mechanics · Physics 2023-10-03 Paul C Bressloff

We investigate reversible diffusion-influenced reactions of an isolated pair in two dimensions. To this end, we employ convolution relations that permit deriving the survival probability of the reversible reaction directly in terms of the…

Quantitative Methods · Quantitative Biology 2015-06-16 Thorsten Prüstel , M. Tachiya

This chapter aims at emphasizing the crucial role of partial reactivity of a catalytic surface or a target molecule in diffusion-controlled reactions. We discuss various microscopic mechanisms that lead to imperfect reactions, the Robin…

Chemical Physics · Physics 2019-11-05 Denis S. Grebenkov