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We studied the recombination dynamics of charge carriers in organic bulk heterojunction solar cells made of the blend system poly(2,5-bis(3-dodecyl thiophen-2-yl) thieno[2,3-b]thiophene) (pBTCT-C12):[6,6]-phenyl-C61-butyric acid methyl…

Charge separation properties, that is the ability of a chromophore, or a chromophore/semiconductor interface, to separate charges upon light absorption, are crucial characteristics for an efficient photovoltaic device. Starting from this…

Chemical Physics · Physics 2019-12-05 Thibaud Etienne , Mariachiara Pastore

The ability to spatially resolve the carrier mobility profile along the cross section of micrometer-thin solar cells is vital both for fundamental studies in photovoltaics and as a quality control for reproducibly obtaining high conversion…

Applied Physics · Physics 2024-01-15 Noah B. Stocek , Miguel J. Young , Reg Bauld , Tianhao Ouyang , Giovanni Fanchini

Drift-diffusion model is an indispensable modeling tool to understand the carrier dynamics (transport, recombination, and collection) and simulate practical-efficiency of solar cells (SCs) through taking into account various carrier…

Mesoscale and Nanoscale Physics · Physics 2017-04-20 Xingang Ren , Zishuai Wang , Wei E. I. Sha , Wallace C. H. Choy

Surface recombination affects both light-to-electricity and electricity-to-light conversion in solar cells (SCs). Therefore, quantitative analysis and reduction of surface recombination is an important direction in SC research. In this…

Several kinds of models have already been proposed for explaining the photoemission process. The exact photoemission theory of semiconductor photocathode was not well established after decades of research. In this paper an integral equation…

Accelerator Physics · Physics 2015-05-30 Xudong Li , Qiang Gu , Meng Zhang , Minghua Zhao

In polymer:fullerene solar cells, the origin of the losses in the field-dependent photocurrent is still controversially debated. We contribute to the ongoing discussion by performing photo-induced charge extraction measurements on…

Materials Science · Physics 2009-12-03 C. Deibel

We propose a new concept for the design of high-efficiency photocells based on ultra-thin (submicron) semiconductor films of controlled thickness. Using a microscopic model of a thin dielectric layer interacting with incident…

Materials Science · Physics 2009-11-13 D. Mozyrsky , I. Martin

In perovskite solar cells, photovoltaic action is created by charge transport layers (CTLs) either side of the light-absorbing metal halide perovskite semiconductor. Hence, the rates for desirable charge extraction and unwanted interfacial…

Absorbed sunlight in a solar cell produces electrons and holes. But, at the open circuit condition, the carriers have no place to go. They build up in density and, ideally, they emit external fluorescence that exactly balances the incoming…

Optics · Physics 2013-08-02 Owen D. Miller , Eli Yablonovitch , Sarah R. Kurtz

Recently, significant progress in the development of III-V/Si dual-junction solar cells has been achieved. This not only boosts the efficiency of Si-based photovoltaic solar cells, but also offers the possibility of highly efficient green…

Electron energy-loss spectroscopy (EELS) is a powerful tool for imaging chemical variations at the nanoscale. Here, we investigate a polymer/organic small molecule-blend used as absorber layer in an organic solar cell and employ EELS for…

Solid-state quantum light sources are being intensively investigated for applications in quantum technology. A key challenge is to extract light from host materials with high refractive index, where efficiency is limited by refraction and…

Optics · Physics 2023-10-11 S G Bishop , J K Cannon , H B Yagci , R N Clark , J P Hadden , W Langbein , A J Bennett

A combination of transient photovoltage (TPV), voltage dependent charge extraction (CE) and time delayed collection field (TDCF) measurements is applied to poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl]…

Applied Physics · Physics 2021-06-21 A. Foertig , J. Kniepert , M. Gluecker , T. Brenner , V. Dyakonov , D. Neher , C. Deibel

The power conversion efficiency of organic solar cells based on donor--acceptor blends is governed by an interplay of polaron pair dissociation and bimolecular polaron recombination. Both processes are strongly dependent on the charge…

Materials Science · Physics 2010-05-26 C. Deibel , A. Wagenpfahl , V. Dyakonov

In this paper, an optoelectronic device simulation framework valid for arbitrary spatial variation of electronic potentials and optical modes, and for transport regimes ranging from ballistic to diffusive, is used to study non-local photon…

Mesoscale and Nanoscale Physics · Physics 2014-11-17 Urs Aeberhard

Electroluminescence (EL) imaging is a powerful and established technique for assessing the quality of photovoltaic (PV) modules, which consist of many electrically connected solar cells arranged in a grid. The analysis of imperfect…

Computer Vision and Pattern Recognition · Computer Science 2020-09-01 Evgenii Sovetkin , Ansgar Steland

We investigate nongeminate recombination in organic solar cells based on copper phthalocyanine (CuPc) and C$_{60}$. Two device architectures, the planar heterojunction (PHJ) and the bulk heterojunction (BHJ), are directly compared in view…

Applied Physics · Physics 2021-06-21 A. Foertig , A. Wagenpfahl , T. Gerbich , D. Cheyns , V. Dyakonov , C. Deibel

The increased complexity and reduced size of (opto-)electronic devices demands for quantitative descriptions of excess carrier transport and recombination via various mechanisms. In addition, experimental methods capable of resolving…

Mesoscale and Nanoscale Physics · Physics 2026-02-17 Tobias Meyer , Christoph Flathmann , David A. Ehrlich , Patrick Paap-Peretzki , Jonas Lindner , Christian Jooß , Michael Seibt

Selenium is an elemental semiconductor with a wide bandgap suitable for a range of optoelectronic and solar energy conversion technologies. However, developing such applications requires an in-depth understanding of the fundamental material…