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We study the dynamics of ionic liquids in a thin slit pore geometry. Beginning with the classical and dynamic density functional theories for systems of charged hard spheres, an asymptotic procedure leads to a simplified model which…

Soft Condensed Matter · Physics 2021-10-15 Ruben J. Tomlin , Tribeni Roy , Toby L. Kirk , Monica Marinescu , Dirk Gillespie

The well-known two-capacitor problem, in which exactly half the stored energy disappears when a charged capacitor is connected to an identical capacitor is discussed based on the mechanical harmonic oscillator model approach. In the…

Classical Physics · Physics 2012-10-17 Keeyung Lee

The so-called negative electron compressibility refers to the lowering of the chemical potential of a metallic system when the carrier density increases. This effect has often been invoked in the past to explain the enhancement of the…

Mesoscale and Nanoscale Physics · Physics 2019-06-19 Javier Junquera , Pablo García-Fernández , Massimiliano Stengel

We discuss various measures of net charge (conserved quantities) fluctuations proposed for the identification of critical phenomena in heavy ion collisions. We show the dynamical component of fluctuations of the net charge can be expressed…

Nuclear Experiment · Physics 2009-11-07 C. Pruneau , S. Gavin , S. Voloshin

Near-critical binary mixtures containing ions and confined between two charged and selective surfaces are studied within a Landau-Ginzburg theory extended to include electrostatic interactions. Charge density profiles and the effective…

Soft Condensed Matter · Physics 2012-02-28 Faezeh Pousaneh , Alina Ciach , Anna Maciolek

We calculate the counting statistics of electron transfer through an open quantum dot with charging interaction. A dot that is connected to leads by two single-channel quantum point contacts in an in-plane magnetic field is described by a…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Markus Kindermann , Bjoern Trauzettel

An understanding of density fluctuations in bulk water has made significant contributions to our understanding of the hydration and interactions of idealized, purely repulsive hydrophobic solutes. To similarly inform the hydration of…

Chemical Physics · Physics 2015-02-19 Richard C. Remsing , Amish J. Patel

In aqueous solutions, dissolved ions interact strongly with the surrounding water, thereby modifying the solution properties in an ion-specific manner. These ion-hydration interactions can be accounted for theoretically on a mean-field…

Soft Condensed Matter · Physics 2014-04-22 Dan Ben-Yaakov , David Andelman , Rudi Podgornik , Daniel Harries

Understanding the force between charged surfaces immersed in an electrolyte solution is a classic problem in soft matter and liquid-state theory. Recent experiments showed that the force decays exponentially but the characteristic decay…

Soft Condensed Matter · Physics 2018-09-26 Alpha A. Lee , Jean-Pierre Hansen , Olivier Bernard , Benjamin Rotenberg

Computer simulations are used to investigate the response of a charged colloid and its surrounding microion cloud to an external electric field. Both static fields (DC) and alternating fields (AC) are considered. A mesoscopic simulation…

Soft Condensed Matter · Physics 2013-07-19 Jiajia Zhou , Roman Schmitz , Burkard Duenweg , Friederike Schmid

A generalization of the mean-field approach will be derived that will take into account the ion-ion as well as ion-surface non-electrostatic effects on an equal footing, being based on the bulk and surface equations of state in the absence…

Soft Condensed Matter · Physics 2018-06-20 Rudolf Podgornik

A self-consistent mode coupling theory (MCT) with microscopic inputs of equilibrium pair correlation functions is developed to analyze electrolyte dynamics. We apply the theory to calculate concentration dependence of (i) time dependent ion…

Statistical Mechanics · Physics 2015-01-09 Susmita Roy , Subramanian Yashonath , Biman Bagchi

In this letter we perform an experimental study of ionic transport and current fluctuations inside individual Carbon Nanotubes (CNT). The conductance exhibits a power law behavior at low salinity, with an exponent close to 1/3 versus the…

Soft Condensed Matter · Physics 2016-04-20 E. Secchi , A. Nigues , L. Jubin , A. Siria , L. Bocquet

The dynamical characteristics of a single frequency low pressure capacitively coupled plasma (CCP) device under varying applied RF voltages and driving frequencies are studied using particle-in-cell/Monte Carlo collision simulations. An…

Plasma Physics · Physics 2018-08-29 Sarveshwar Sharma , Abhijit Sen , N. Sirse , M. M. Turner , A. R. Ellingboe

The dependence of the actual/effective ionic concentration on the nominal salt concentration is experimentally investigated for aqueous solutions of NaCl and KCl. The actual ionic bulk density is determined by means of the impedance…

Chemical Physics · Physics 2022-04-04 G. Barbero , N. G. Fytas , I. Lelidis , J. V. da Silva Andrade , F. C. M. Freire , A. J. Santana

We revisit the role of the local solvent structure on the activity coefficient of electrolytes with a general non-local dielectric function approach. We treat the concentrated electrolyte as a dielectric medium and suggest an interpolated…

Chemical Physics · Physics 2020-01-08 Amir Levy , Martin Z. Bazant , Alexei A. Kornyshev

Molecular dynamics simulations for aqueous sodium chloride solutions were carried out at various concentrations. Supplementary to the Debye-H\"uckel theory, reversible transient nucleation of ions was observed even in dilute solutions. The…

Soft Condensed Matter · Physics 2014-11-26 Gan Ren , Yanting Wang

Within the Poisson-Boltzmann (PB) approach electrolytes in contact with planar, spherical, and cylindrical electrodes are analyzed systematically. The dependences of their capacitance $C$ on the surface charge density $\sigma$ and the ionic…

Soft Condensed Matter · Physics 2017-04-24 Andreas Reindl , Markus Bier , S. Dietrich

We investigate self-organized criticality in a two-dimensional electron gas (2DEG) by introducing a lattice-based model that incorporates electron-electron interactions through the concept of coherence length. Our numerical simulations…

Statistical Mechanics · Physics 2025-09-17 Maryam Pirgholi , Morteza Nattagh Najafi , Vadood Adami

We address the role of fluctuations in strongly interacting matter during the dense stages of a heavy-ion collision through its electromagnetic emission. Fluctuations of isospin charge are considered in a thermal system at rest as well as…

High Energy Physics - Phenomenology · Physics 2009-11-07 M. Prakash , R. Rapp , J. Wambach , I. Zahed