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We study the asymptotic long-range behavior of the time-dependent correlation function of the surface charge density induced on the interface between two media of distinct dielectric functions which are in thermal equilibrium with one…

Statistical Mechanics · Physics 2016-10-26 Ladislav Samaj

The interaction between an electric field and the electric charges in a material is described by electrostatic screening, which in metallic systems is commonly thought to be confined within a distance of the order of the Thomas-Fermi…

Mesoscale and Nanoscale Physics · Physics 2018-10-29 Erik Piatti , Davide Romanin , Renato S. Gonnelli , Dario Daghero

We consider equilibrium statistical mechanics of a simplified model for the ideal conductor electrode in an interface contact with a classical semi-infinite electrolyte, modeled by the two-dimensional Coulomb gas of pointlike $\pm$ unit…

Statistical Mechanics · Physics 2009-11-11 L. Samaj , Z. Bajnok

Several statistical mechanical theories predict that colloidal suspensions of highly charged macroions and monovalent microions can exhibit unusual thermodynamic phase behavior when strongly deionized. Density-functional, extended…

Soft Condensed Matter · Physics 2009-11-11 A. R. Denton

Near-critical binary mixtures containing ions and confined between two charged and selective surfaces are studied within a Landau-Ginzburg theory extended to include electrostatic interactions. Charge density profiles and the effective…

Soft Condensed Matter · Physics 2012-02-28 Faezeh Pousaneh , Alina Ciach , Anna Maciolek

In this dissertation we analyzed the double-layer force interaction between two dielectric charged colloidal spheres of different radii immersed in a solution of ions in water and in thermal equilibrium. In the limit of low electrostatic…

Soft Condensed Matter · Physics 2016-03-01 Daniel Martínez Tibaduiza

We study the interaction between two charge regulating spherical macroions with dielectric interior and dissociable surface groups immersed in a monovalent electrolyte solution. The charge dissociation is modelled via the…

Soft Condensed Matter · Physics 2023-12-11 Hu Ruixuan , Arghya Majee , Jure Dobnikar , Rudolf Podgornik

We show how, with the use of quantum interference, we can violate, in some sense, the rule that charges of equal sign always repel each other. By considering two electrons that propagate parallel to each other in a Mach-Zehnder…

Quantum Physics · Physics 2019-08-05 Marina F. B. Cenni , Raul Corrêa , Pablo L. Saldanha

We explore the effect of steric interaction on the ionic density distribution near a charged hard wall. For weakly charged walls, small particles, and monovalent ions the mean-field Poisson-Boltzmann equation provides an excellent…

Soft Condensed Matter · Physics 2015-06-05 Derek Frydel , Yan Levin

Mobile charge in an electrolytic solution can in principle be represented as the divergence of ionic polarization. After adding explicit solvent polarization a finite volume of electrolyte can then be treated as a composite non-uniform…

Soft Condensed Matter · Physics 2021-03-03 Michiel Sprik

We consider the electrostatic interaction between two rigid membranes, with different surface charge densities of opposite sign, across an aqueous solution without added salt. Exact solutions to the nonlinear Poisson-Boltzmann equation are…

Soft Condensed Matter · Physics 2016-08-31 A. W. C. Lau , P. Pincus

Effect of ionic solute on a near-critical binary aqueous mixture confined between charged walls with different adsorption preferences is considered within a simple density functional theory. For the near-critical system containing small…

Soft Condensed Matter · Physics 2015-05-28 F. Pousaneh , A. Ciach

A unified electrodynamic approach to the guided-wave excitation theory is generalized to the waveguiding structures containing a hypothetical space-dispersive medium with drifting charge carriers possessing simultaneously elastic,…

Classical Physics · Physics 2009-10-31 A. A. Barybin

In this chapter we review the electrostatic properties of charged membranes in aqueous solutions, with or without added salt, employing simple physical models. The equilibrium ionic profiles close to the membrane are governed by the…

Soft Condensed Matter · Physics 2023-01-05 Tomer Markovich , David Andelman , Rudi Podgornik

Electrostatic interactions make a large contribution to solvation free energy in ionic fluids such as electrolytes and colloidal dispersions. The electrostatic contribution to solvation free energy has been ascribed to the self-energy of a…

Statistical Mechanics · Physics 2020-02-19 Hiroshi Frusawa

Recent measurements of microsphere interactions in diverse media suggest that the standard dielectric-continuum models of solution-phase interactions are fundamentally incomplete. Experiments indicate that the interactions of charged…

Soft Condensed Matter · Physics 2026-05-12 Ali Behjatian , Madhavi Krishnan

Using Poisson-Boltzmann equation and linear response theory, we derive an effective interaction potential due to a fixed charge distribution in a solution containing polyelectrolytes and point salt. We obtain an expression for the effective…

Soft Condensed Matter · Physics 2016-01-08 Sandipan Dutta , and Y. S. Jho

Like-charge attraction, driven by ionic correlations, challenges our understanding of electrostatics both in soft and hard matter. For two charged planar surfaces confining counterions and water, we prove that even at relatively low…

Soft Condensed Matter · Physics 2023-03-15 Ivan Palaia , Abhay Goyal , Emanuela del Gado , Ladislav Šamaj , Emmanuel Trizac

We show that hydrophilic ions present in a confined, near-critical aqueous mixture can lead to an attraction between like charge surfaces with opposing preferential adsorption of the two species of the mixture, even though the corresponding…

Soft Condensed Matter · Physics 2016-03-27 Faezeh Pousaneh , Alina Ciach , Anna Maciołek

We consider fluids where the attractive interaction at distances slightly larger than the particle size is dominated at larger distances by a repulsive contribution. A previous investigation of the effects of the competition between…

Soft Condensed Matter · Physics 2009-11-11 D. Pini , A. Parola , L. Reatto