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Singlet fission, in which the optical spin-singlet exciton dissociates into two low energy triplet excitons, has been proposed as a viable approach to enhance the quantum efficiency of organic solar cells. We show that even when singlet…

Strongly Correlated Electrons · Physics 2013-03-15 K. Aryanpour , J. A. Muñoz , S. Mazumdar

The formation of bound electron-hole pairs, also called charge-transfer (CT) states, in organic-based photovoltaic devices is one of the dominant loss mechanisms hindering performance. While CT state dynamics following electron transfer…

Modeling the charge-generation process is highly important to understand device physics and optimize power conversion efficiency of bulk-heterojunction (BHJ) organic solar cells (OSCs). Free carriers are generated by both ultrafast exciton…

Mesoscale and Nanoscale Physics · Physics 2016-12-06 Zi Shuai Wang , Wei E. I. Sha , Wallace C. H. Choy

We approach the biexciton Schr\"{o}dinger equation not through the free-carrier basis as usually done, but through the free-exciton basis, exciton-exciton interactions being treated according to the recently developed composite boson…

Strongly Correlated Electrons · Physics 2016-12-16 Shiue-Yuan Shiau , Monique Combescot , Yia-Chung Chang

The common model to describe exciton-plasmon interaction phenomenologically is the coupled oscillator model. Originally developed for atomic systems rather than solid-state matter, this model treats both excitons and plasmons as single…

Mesoscale and Nanoscale Physics · Physics 2024-10-23 Lara Greten , Robert Salzwedel , Diana Schutsch , Andreas Knorr

We investigate the viability of highly efficient organic solar cells (OSCs) based on non-fullerene acceptors (NFA) by taking into consideration efficiency loss channels and stability issues caused by triplet excitons (TE) formation. OSCs…

We solve the Schr\"{o}dinger equation for two electrons plus one hole by writing it in the electron-exciton basis. The main advantage of this basis is to eliminate the exciton contribution from the trion energy in a natural way. The…

Strongly Correlated Electrons · Physics 2015-03-20 Shiue-Yuan Shiau , Monique Combescot , Yia-Chung Chang

Photoabsorption in the low-energy region for C$_{60}$ and PTCDA molecular complexes is studied within linear response TDDFT. For the PBE, B3LYP and HSE exchange-correlation (xc) functionals the dependence of the accuracy of the exciton…

Mesoscale and Nanoscale Physics · Physics 2026-04-16 N. L. Matsko , Mahmoud A. Salem

This paper presents a possible explanation for the enhanced singlet exciton yield in light emitting polymers. We propose a theory of electron-hole recombination via inter-molecular inter-conversion from inter-molecular weakly bound polaron…

Chemical Physics · Physics 2009-11-10 William Barford

Control of the band-edge offsets at heterojunctions between organic semiconductors allows efficient operation of either photovoltaic or light-emitting diodes. We investigate systems where the exciton is marginally stable against charge…

Soft Condensed Matter · Physics 2013-09-27 Arne C. Morteani , Paiboon Sreearunothai , Laura M. Herz , Richard H. Friend , Carlos Silva

We demonstrate sub-wavelength imaging of excitons confined to single CdTe quantum dots. By combining slit-confocal microscopy with a hemispherical solid immersion lens we simultaneously map the emission of thousands of single quantum dots…

Other Condensed Matter · Physics 2009-11-10 K. P. Hewaparakrama , S. Mackowski , H. E. Jackson , L. M. Smith , G. Karczewski , J. Kossut

We use a local model to study the formation and the structure of the low energy charge transfer excitations in the insulating Cu-O$_2$ plane. The elementary excitation is a bound exciton of spin singlet, consisting of a Cu$^+$ and a…

Strongly Correlated Electrons · Physics 2007-05-23 Fu Chun Zhang , Kwai-Kong Ng

In order to discuss the exciton fine-structure of transition-metal dichalcogenides mono-layers, excitons are first defined in the subspace of electron- and hole states, including the lowest conduction band (LCB) and the uppermost valence…

Mesoscale and Nanoscale Physics · Physics 2019-06-25 Pierre Gilliot , Mathieu Gallart , Bernd Hönerlage

Exciton many-body interaction bear great implication for application in advanced photonic devices and quantum science and technology such as quantum computing, but the fundamental understanding about exciton many-body interaction is very…

Materials Science · Physics 2020-09-17 Yiling Yu , Guoqing Li , Linyou Cao

Understanding charge transfer (CT) between two chemical entities and subsequent change in their charge densities is essential not only for molecular species but also for various low-dimensional materials. Because of their extremely high…

Materials Science · Physics 2021-08-04 Haneul Kang , Kwanghee Park , Sunmin Ryu

Excitons and their constituent charge carriers play the central role in electroluminescence mechanisms determining the ultimate performance of organic optoelectronic devices. The involved processes and their dynamics are often studied with…

Mesoscale and Nanoscale Physics · Physics 2018-06-05 Anna Rosławska , Pablo Merino , Christoph Große , Christopher C. Leon , Olle Gunnarsson , Markus Etzkorn , Klaus Kuhnke , Klaus Kern

The optical spectra of CdSe nanocrystals up to 55 A in diameter are analyzed in a wide range of energies from the fine structure of the low-energy excitations to the so-called high-energy transitions. We apply a symmetry-based method in two…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 J. Perez-Conde , A. K. Bhattacharjee

In organic semiconductors working under ambient circumstance, there are remarkable quantum effects lack of comprehensive understanding, and an exotic composite particle named charge transfer (CT) exciton is normally regarded as the key…

Mesoscale and Nanoscale Physics · Physics 2021-12-07 Yao Yao

Charge Transfer (CT) has enjoyed continuous interest due to increasing experimental control over molecular structure leading to applications in, for example, photovoltaics and hydrogen production. In this paper, we investigate the effect of…

Chemical Physics · Physics 2022-06-29 Marìck Manrho , Thomas L. C. Jansen , Jasper Knoester

We develop a theory of polarized photoluminescence of interface excitons localized at lateral heterojunctions between transition metal dichalcogenide monolayers. We show that the circular selection rules governing interband optical…

Mesoscale and Nanoscale Physics · Physics 2026-03-26 M. V. Durnev , D. S. Smirnov