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The reactions of the low-lying metastable states of atomic phosphorus, P($^2$D) and P($^2$P), with H$_{2}$O and H$_{2}$ were studied by the pulsed laser photolysis at 248 nm of PCl$_{3}$ , combined with laser induced fluorescence detection…

Solar and Stellar Astrophysics · Physics 2022-06-29 Kevin M. Douglas , David Gobrecht , John M. C. Plane

(Abridged) Sulfur chemistry is poorly understood in the process of low-mass star and planet formation, where the main carriers of sulfur are still unknown. Despite the fact that simple S-bearing molecules are usually detected toward…

Solar and Stellar Astrophysics · Physics 2023-10-18 E. Artur de la Villarmois , V. V. Guzman , Y. -L. Yang , Y. Zhang , N. Sakai

The interstellar medium is known to be chemically complex. Organic molecules with up to 11 atoms have been detected in the interstellar medium, and are believed to be formed on the ices around dust grains. The ices can be released into the…

Cold cores in interstellar molecular clouds represent the very first phase in star formation. The physical conditions of these objects are studied in order to understand how molecular clouds evolve and how stellar masses are determined. The…

Astrophysics · Physics 2009-11-13 J. Harju , M. Juvela , S. Schlemmer , L. K. Haikala , K. Lehtinen , K. Mattila

The central stars of planetary nebulae (PNe) are natural targets for FUSE due to their UV brightness. The FUSE spectra of many PNe show absorption features due to circumstellar material in species ranging from H_2 and neutrals in the…

Astrophysics · Physics 2007-05-23 Harriet L. Dinerstein , N. C. Sterling , Charles W. Bowers

Sulfur-bearing molecules are central to interstellar chemistry, yet their observed abundances in the gas phase remain far below cosmic expectations in dense interstellar regions. Mixed N-S-O species such as thionylimide (HNSO) are…

Astrophysics of Galaxies · Physics 2025-12-01 Valerio Lattanzi , Miguel Sanz-Novo , Víctor M. Rivilla , Izaskun Jiménez-Serra , Paola Caselli

Starless cores represent the initial stage of evolution toward (proto)star formation, and a subset of them, known as prestellar cores, with high density (~ 10^6 cm^-3 or higher) and being centrally concentrated are expected to be embryos of…

We discuss the interstellar absorption from many atomic and molecular species seen in high-resolution $HST$/STIS UV and high-S/N optical spectra of the moderately reddened B3-5~V star HD~62542. This remarkable sight line exhibits both very…

Astrophysics of Galaxies · Physics 2020-07-08 Daniel E. Welty , Paule Sonnentrucker , Theodore P. Snow , Donald G. York

The carrier of the 21 ${\mu}$m emission feature discovered in a handful of protoplanetary nebulae (PPNe) is one of the most intriguing enigmas in circumstellar chemistry. Investigating the gas-phase molecules in PPNe could yield important…

Elemental phosphorus exhibits fascinating structural varieties and versatile properties. The unique nature of phosphorus bonds can lead to the formation of extremely complex structures, and detailed structural information on some phosphorus…

The phosphorus abundance distribution in field stars as a function of metallicity reveals a complex pattern. The LTE data for [P/Fe] in the low-metallicity range are sparse and scattered around [P/Fe]~ 0 dex. Near [Fe/H]~ -2 dex, the…

Solar and Stellar Astrophysics · Physics 2026-03-17 S. M. Andrievsky , S. A. Korotin

We have recently completed an observing program with the Australia Telescope Compact Array towards massive star formation regions traced by 6.7 GHz methanol maser emission. We found the molecular cores could be separated into groups based…

Astrophysics · Physics 2007-11-29 S. N. Longmore , M. G. Burton , C. R. Purcell , P. Barnes , J. Ott

Observations are presented of emission lines from organic molecules at frequencies 32 - 50 GHz in the vicinity of Chamaeleon MMS1. This chemically-rich dense cloud core habours an extremely young, very low-luminosity protostellar object and…

Astrophysics of Galaxies · Physics 2015-05-30 Martin A. Cordiner , Steven B. Charnley , Eva S. Wirström , Robert G. Smith

We present 1.3mm continuum and spectral line images of two massive molecular clumps P1 and P2 in the G28.34+0.06 region with the Submillimeter Array. While the two clumps contain masses of 1000 and 880 \msun, respectively, P1 has a…

Astrophysics of Galaxies · Physics 2011-02-11 Qizhou Zhang , Yang Wang , Thushara Pillai , Jill Rathborne

We have measured the deuterium fractionation (through the column density ratio N(N2D+)/N(N2H+)) and the CO depletion factor (ratio between expected and observed CO abundance) in a sample of 10 high-mass protostellar candidates, in order to…

Astrophysics · Physics 2009-11-11 F. Fontani , P. Caselli , A. Crapsi , R. Cesaroni , S. Molinari , L. Testi , J. Brand

We studied sulfur chemistry of massive star-forming regions through single-dish submillimeter spectroscopy. OCS, O13CS, 13CS, H2S and SO transitions were observed toward a sample of massive star-forming regions with embedded UCH II or CH II…

Solar and Stellar Astrophysics · Physics 2015-06-23 Juan Li , Junzhi Wang , Qingfeng Zhu , Jiangshui Zhang , Di Li

Thermochemical equilibrium and kinetic calculations are used to model sulfur and phosphorus chemistry in giant planets, brown dwarfs, and extrasolar giant planets (EGPs). The chemical behavior of individual S- and P-bearing gases and…

Astrophysics · Physics 2008-11-26 Channon Visscher , Katharina Lodders , Bruce Fegley

We investigated the chemistry of nitrogen--containing species, principally isotopomers of CN, HCN, and HNC, in a sample of pre-protostellar cores. We used the IRAM 30 m telescope to measure the emission in rotational and hyperfine…

Solar and Stellar Astrophysics · Physics 2015-05-18 Pierre Hily-Blant , Malcolm Walmsley , G. Pineau Des forêts , David Flower

Cold ($\sim$10 K) and dense ($\sim$10$^{5}$ cm$^{-3}$) cores of gas and dust within molecular clouds, known as starless and dynamically evolved prestellar cores, are the birthplaces of low-mass ($M$ $\leq$ few M$_\odot$) stars. As…

Astrophysics of Galaxies · Physics 2024-08-22 Samantha Scibelli , Yancy Shirley , Andrés Megías , Izaskun Jiménez-Serra

First protostellar cores are young stellar objects in the earliest evolutionary stage. They are hydrostatic objects formed soon after the central portions of star-forming cores become optically thick to dust emission. We consider their…

Astrophysics · Physics 2015-05-13 K. Omukai
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