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We propose a dynamical theory of low-temperature shear deformation in amorphous solids. Our analysis is based on molecular-dynamics simulations of a two-dimensional, two-component noncrystalline system. These numerical simulations reveal…

Statistical Mechanics · Physics 2009-10-30 M. L. Falk , J. S. Langer

We report here a study of reversible pressure-induced structural transformation between two amorphous forms of SO$_2$: molecular at pressures below 26 GPa and polymeric above this pressure, at temperatures of 77 - 300 K. The transformation…

We study the structural, dynamical and electronic properties of amorphous Si\sub{1-x}Ge\sub{x}:H alloys using first principles local basis molecular dynamics simulation. The network topology and defects in the amorphous network have been…

Materials Science · Physics 2007-05-23 T. A. Abtew , D. A. Drabold

High pressure in-situ synchrotron X-ray diffraction experiments were performed on Ag2Te up to 42.6 GPa at room temperature and four phases were identified. Phase I ({\beta}-Ag2Te) transformed into phase II at 2.4 GPa, and phase III and…

Materials Science · Physics 2015-05-01 Zhao Zhao , Shibing Wang , Haijun Zhang , Wendy L. Mao

The local electronic and magnetic properties of superconducting FeSe have been investigated by K$\beta$ x-ray emission (XES) and simultaneous x-ray absorption spectroscopy (XAS) at the Fe K-edge at high pressure and low temperature. Our…

Superconductivity · Physics 2018-05-09 B. W. Lebert , V. Balédent , P. Toulemonde , J. M. Ablett , J. -P. Rueff

We report high pressure X-ray diffraction and a detailed systematic Raman measurements on $ReS_2$ sample, which is mechanically exfoliated from a single crystal. A few new Bragg peaks are observed to emerge above 6 GPa indicating a…

Materials Science · Physics 2020-05-20 Pinku Saha , Bishnupada Ghosh , Aritra Mazumder , Konstantin Glazyrin , Goutam Dev Mukherjee

The persistent problem posed by the glass transition is to develop a general atomic level description of a solidification process that is not associated with any change in the symmetry of the atomic structure. The answer proposed in this…

Soft Condensed Matter · Physics 2022-07-20 Gang Sun , Peter Harrowell

We simulate the compression of a two-component Lennard-Jones liquid at a variety of constant temperatures using a molecular dynamics algorithm in an isobaric-isothermal ensemble. The viscosity of the liquid increases with pressure,…

chem-ph · Physics 2009-10-22 Shelly L. Shumway , Andrew S. Clarke , Hannes Jónsson

Investigating electronic structure and excitations under extreme conditions gives access to a rich variety of phenomena. High pressure typically induces behavior such as magnetic collapse and the insulator-metal transition in 3d transition…

Strongly Correlated Electrons · Physics 2017-09-27 Jean-Pascal Rueff , Abhay Shukla

A superstructure can elicit versatile new properties of materials by breaking their original geometrical symmetries. It is an important topic in the layered graphene-like two-dimensional transition-metal dichalcogenides (TMDs), but its…

Because of the negative inclination of the solid-liquid phase separation line in water, ice Ih melts on compression. On further increase in pressure the liquid water transforms into a high density metastable glassy state, characterized by a…

Soft Condensed Matter · Physics 2021-04-22 Saumyak Mukherjee , Biman Bagchi

As-deposited and unencapsulated GeSe$_{1-x}$Te$_x$ ($x = 0, 0.25$) 3-$\mu$m-thick amorphous films on Si(001) were obtained via the co-evaporation technique to study the effect of selenium (Se) substitution for tellurium (Te) on the GeSe…

Materials Science · Physics 2025-01-22 P. Armand , R. Escalier , G. Silly , J. Lizion , A. Piarristeguy

Amorphous silica density at ambient pressure is known to depend on thermal history (through the quenching rate) but also, at room temperature, on the maximum pressure applied in the past. Here we show that beyond density, a mechanical…

Other Condensed Matter · Physics 2009-05-15 Cindy Linn Rountree , Damien Vandembroucq , Mehdi Talamali , Elisabeth Bouchaud , Stéphane Roux

Short range order and topology of Ge$_x$S$_{100-x}$ glasses over a broad composition range (20 $\le$ x $\le$ 42 in at%) was investigated by neutron diffraction, X-ray diffraction, and Ge K-edge extended X-ray absorption fine structure…

We report results of ab initio constant-pressure molecular dynamics simulations of sulfur compression leading to structural transition and pressure-induced amorphization. Starting from the orthorhombic S-I phase composed of S$_8$ ring…

Disordered Systems and Neural Networks · Physics 2015-06-19 Dušan Plašienka , Roman Martoňák

The metal to insulator transition in the charge transfer NiS{2-x}Se{x} compound has been investigated through infrared reflectivity. Measurements performed by applying pressure to pure NiS2 (lattice contraction) and by Se-alloying (lattice…

Recent studies (J. Alloys Compd. 695 (2017) 2661) of the electronic structure and properties of $(TiZrNbCu)_{1-x}$$Ni_{x}$ (x$\leq$0.25) amorphous high entropy alloys (a-HEA) have been extended to x=0.5 in order to compare behaviours of…

The role of porous structure and glass density in response to compressive deformation of amorphous materials is investigated via molecular dynamics simulations. The disordered, porous structures were prepared by quenching a high-temperature…

Soft Condensed Matter · Physics 2018-09-18 Nikolai V. Priezjev , Maxim A. Makeev

To experimentally clarify the changes in structural and dynamic heterogeneities in a metallic glass (MG), Gd65Co35, by rejuvenation with a temperature cycling (cryogenic rejuvenation), high-energy x-ray diffraction (HEXRD), anomalous x-ray…

Fourier transform infrared (FTIR) spectra and X-ray photoelectron spectra (XPS) of Nd doped phosphate glasses have been studied before and after gamma irradiation in order to find the behavior of chemical bonds, which decide the structural…

Materials Science · Physics 2014-06-19 V. N. Rai , B. N. Raja Sekhar , D. M. Phase , S. K. Deb