Related papers: Molecular Dynamics at Electrical- and Optical-Driv…
Understanding and controlling the electronic as well as ro-vibrational motion and, thus, the entire chemical dynamics in molecules is the ultimate goal of ultrafast laser and imaging science. In photochemistry, laser-induced dissociation…
Light-matter interaction dynamics is governed by the strength of local coupling constants, tailored by surrounding electromagnetic structures. Characteristic decay times in dipole-allowed fluorescent transitions are much faster than…
In conventional optical Stark-shift spectroscopy, molecules are exposed to spatially homogeneous static electric fields that shift the energies of their spectral lines. These shifts are attributed to the molecular electronic properties,…
The photoexcited state in superconducting metals and alloys was studied via pump-probe spectroscopy. A pulsed Ti:sapphire laser was used to create the non-equilibrium state and the far-infrared pulses of a synchrotron storage ring, to which…
Molecular absorption and photo-electron spectra can be efficiently predicted with real-time time-dependent density-functional theory (TDDFT). We show here how these techniques can be easily extended to study time-resolved pump-probe…
Molecular iodine was photoexcited by a strong 800 nm laser, driving several channels of multiphoton excitation. The motion following photoexcitation was probed using time-resolved X-ray scattering, which produces a scattering map…
Fourier-transform spectroscopy (FTS) has been widely used as a standard analytical technique over the past half-century. FTS is a simple and robust autocorrelation-based technique that is compatible with both temporally coherent and…
We study thorium-doped CaF$_2$ crystals as a possible platform for optical spectroscopy of the Th-229 nuclear isomer transition. We anticipate two major sources of background signal that might cover the nuclear spectroscopy signal:…
The ultrafast dynamics of charge carriers in organic donor-acceptor interfaces are of primary importance to understanding the fundamental properties of these systems. In this work, we focus on a charge-transfer complex formed by…
Phase transitions (liquid-solid, solid-solid) triggered by temperature changes are studied in free nanosized clusters of TeF_6 (SF_6) with different negative charges assigned to the fluorine atoms. Molecular dynamics simulations at constant…
The conformational change of biological macromolecule is investigated from the point of quantum transition. A quantum theory on protein folding is proposed. Compared with other dynamical variables such as mobile electrons, chemical bonds…
We report on an original and simple formulation of the phase shift in N-light-pulse atom interferometers. We consider atomic interferometers based on two-photon transitions (Raman transitions or Bragg pulses). Starting from the exact…
The work presents the electronic structure, spin state and optical properties of TM-dinuclear molecules (TM = Cr, Mn, Fe, Co, and Ni) which was modelled according to the recently reported Pt$^{II}$-dinuclear complex…
In this work, we combine conventional linear response time-domain THz spectroscopy with non-linear THz-pump THz-probe techniques to study metallic strained thin films of $\mathrm{Ca}_2\mathrm{RuO}_4$, which undergo a transition into a…
Technology moves towards ever faster switching between different electronic and magnetic states of matter. Manipulating properties at terahertz rates requires accessing the intrinsic timescales of electrons (femtoseconds) and associated…
Time integrated spectroscopic measurements are carried out to characterize transient plasma stream produced in a coaxial pulsed plasma accelerator. This method allows the estimation of different plasma parameters and its evolution with…
All optical switches offer advanced control over the properties of light at ultrafast timescales using optical pulses as both the signal and the control. Limited only by material response times, these switches can operate at terahertz…
We present a theory of vibrational modulation of two-dimensional coherent Fourier transformed electronic spectra. Based on an expansion of the system's energy gap correlation function in terms of Huang-Rhys factors, we explain the…
We calculate the shift, due to interatomic interactions, of an optical transition in an atomic Fermi gas trapped in an optical lattice, as in recent experiments of Campbell {\it et al.}, Science {\bf 324}, 360 (2009). Using a pseudospin…
Strongly correlated materials that exhibit an insulator-metal transition are key candidates in the search for new computing platforms. Understanding the pathways and timescales underlying the electrically-driven insulator-metal transition…