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We consider optical spectroscopy of molecular junctions from the quantum transport perspective when radiation field is quantized and optical response of the system is simulated as photon flux. Using exact expressions for photon and…

Mesoscale and Nanoscale Physics · Physics 2016-05-09 Yi Gao , Michael Galperin

Development of experimental techniques at nanoscale resulted in ability to perform spectroscopic measurements on single-molecule current carrying junctions. These experiments are natural meeting point for research fields of optical…

Mesoscale and Nanoscale Physics · Physics 2025-02-20 Haoran Sun , Upendra Harbola , Shaul Mukamel , Michael Galperin

Nonlinear optical signals from an assembly of N noninteracting particles consist of an incoherent and a coherent component, whose magnitudes scale \sim N and \sim N(N-1), respectively. A unified microscopic description of both types of…

Quantum Physics · Physics 2009-11-13 Christoph A. Marx , Upendra Harbola , Shaul Mukamel

Progress of experimental techniques at nanoscale in the last decade made optical measurements in current-carrying nanojunctions a reality thus indicating emergence of a new field of research coined as optoelectronics. Optical spectroscopy…

Mesoscale and Nanoscale Physics · Physics 2018-03-26 Michael Galperin

Two-dimensional spectroscopy is discussed for open quantum systems with multiple simultaneously measurable fluxes. In particular, we discuss a junction where optical measurements of photon flux are complemented with simultaneous transport…

Mesoscale and Nanoscale Physics · Physics 2025-02-28 Haoran Sun , Upendra Harbola , Shaul Mukamel , Michael Galperin

We compare theoretical techniques utilized for description of optical response in molecular junctions, and their application to simulate Raman spectroscopy in such systems. Strong and weak sides of the Hilbert vs. Liouville space, as well…

Mesoscale and Nanoscale Physics · Physics 2015-04-09 Michael Galperin , Mark A. Ratner , Abraham Nitzan

Sub-wavelength arrays of quantum emitters offer an efficient free-space approach to coherent light-matter interfacing, using ultracold atoms or two-dimensional solid-state quantum materials. The combination of collectively suppressed…

Quantum Gases · Physics 2024-12-16 Simon Panyella Pedersen , Georg M. Bruun , Thomas Pohl

We introduce diagrammatic technique for Hubbard nonequilibrium Green functions (NEGF). The formulation is an extension of equilibrium considerations for strongly correlated lattice models to description of current carrying molecular…

Mesoscale and Nanoscale Physics · Physics 2016-11-04 Feng Chen , Maicol A. Ochoa , Michael Galperin

The interaction of optical fields sculpted on the nano-scale with matter may not be described by the dipole approximation since the fields vary appreciably across the molecular length scale. Rather than incrementally adding higher…

Quantum Physics · Physics 2015-10-28 Vladimir Y. Chernyak , Prasoon Saurabh , Shaul Mukamel

Closed expressions are derived for resonant multidimensional X-ray spectroscopy using the quasiparticle nonlinear exciton representation of optical response. This formalism is applied to predict coherent four wave mixing signals which probe…

Strongly Correlated Electrons · Physics 2015-05-13 U. Harbola , S. Mukamel

We propose a scheme for calculation of linear optical response of current-carrying molecular junctions for the case when electronic tunneling through the junction is much faster than characteristic time of external laser field. We discuss…

Mesoscale and Nanoscale Physics · Physics 2008-04-07 Michael Galperin , Sergei Tretiak

Based on a formalism that describes atom-light interactions in terms of the classical electromagnetic Green's function, we study the optical response of atoms and other quantum emitters coupled to one-dimensional photonic structures, such…

Quantum Physics · Physics 2017-03-22 A. Asenjo-Garcia , J. D. Hood , D. E. Chang , H. J. Kimble

A polaron model proposed as a possible mechanism for nonlinear conductance [Galperin M, Ratner M A, and Nitzan A 2005 Nano Lett. 5 125-30] is revisited with focus on the differences between the weak and strong molecule-lead coupling cases.…

Mesoscale and Nanoscale Physics · Physics 2008-08-26 Michael Galperin , Abraham Nitzan , Mark A. Ratner

We present a theoretical approach to optical spectroscopy of open nonequilibrium systems, which generalizes traditional nonlinear optical spectroscopy tools by imposing charge and energy conservation at all levels of approximation. Both…

Mesoscale and Nanoscale Physics · Physics 2019-12-19 Shaul Mukamel , Michael Galperin

I discuss the relation between the nuclear response and the Green function describing the propagation of a nucleon in the nuclear medium. Within this formalism, the widely used expressions in terms of spectral functions can be derived in a…

Nuclear Theory · Physics 2008-11-26 Omar Benhar

We investigate the linear and nonlinear optical responses of dilute anisotropic networks using the Green's-function formalism (GFF)[Gu Y et al. 1999 Phys. Rev. B 59 12847]. For the different applied fields, numerical calculations indicate…

Soft Condensed Matter · Physics 2007-05-23 Y. Gu , K. W. Yu

We present a brief pedagogical review of theoretical Green's function methods applicable to open quantum systems out of equilibrium in general, and single molecule junctions in particular. We briefly describe experimental advances in…

Mesoscale and Nanoscale Physics · Physics 2020-03-10 Guy Cohen , Michael Galperin

A generalized Green's function theory is developed to simulate the inelastic electron tunneling spectroscopy (IETS) of molecular junctions. It has been applied to a realistic molecular junction with an octanedithiolate embedded between two…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Jun Jiang , Mathias Kula , Wei Lu , Yi Luo

We present linear response theories in the continuum capable of describing photoionization spectra and dynamic polarizabilities of finite systems with no spatial symmetry. Our formulations are based on the time-dependent local density…

Chemical Physics · Physics 2016-09-08 Takashi Nakatsukasa , Kazuhiro Yabana

The resonant interaction between x-ray photons and nuclei is one of the most exciting subjects of the burgeoning field of x-ray quantum optics. A resourceful platform used so far are thin-film x-ray cavities with embedded layers or…

Quantum Physics · Physics 2020-10-02 Xiangjin Kong , Darrick E. Chang , Adriana Pálffy
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