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Electron Transfer (ET) reactions are modeled by the dynamics of a quantum two-level system (representing the electronic state) coupled to a thermalized bath of classical harmonic oscillators (representing the nuclei degrees of freedom).…

Chemical Physics · Physics 2014-11-24 Serge Aubry

Entropy and the fluctuation-dissipation theorem are at the heart of statistical mechanics near equilibrium. Driving a system beyond the linear response regime leads to (i) the breakdown of the fluctuation-dissipation theorem and (ii) a…

Statistical Mechanics · Physics 2010-09-10 Thomas Speck

We develop the kinetic theory of the flux-carrying Brownian motion recently introduced in the context of open quantum systems. This model constitutes an effective description of two-dimensional dissipative particles violating both…

Statistical Mechanics · Physics 2022-07-27 Antonio A. Valido

Despite the seminal connection between classical multiply-periodic motion and Heisenberg matrix mechanics and the massive amount of work done on the associated problem of semiclassical (EBK) quantization of bound states, we show that there…

chem-ph · Physics 2009-10-28 Wm. R. Greenberg , Abraham Klein , Ivalyo Zlatev , C. T. Li

It is noted that the Schrodinger equation with any self-adjoint Hamiltonian is unitary equivalent to a set of non-interacting classical harmonic oscillators and in this sense any quantum dynamics is completely integrable. Higher order…

Mathematical Physics · Physics 2019-11-06 Igor V. Volovich

The thermodynamic behavior of Markovian open quantum systems can be described at the level of fluctuations by using continuous monitoring approaches. However, practical applications require assessing imperfect detection schemes, where the…

Understanding the non-equilibrium dynamics of quantum many-body systems remains one of the grand challenges of modern physics. In particular, increasing attention has been devoted to the emergence of non-equilibrium universality classes…

Quantum Physics · Physics 2025-12-22 Wenbo Zhou , Yuke Zhang , Pengfei Zhang

In this paper we study the semiclassical limit of the Schr\"odinger equation. Under mild regularity assumptions on the potential $U$ which include Born-Oppenheimer potential energy surfaces in molecular dynamics, we establish asymptotic…

Analysis of PDEs · Mathematics 2010-06-29 Luigi Ambrosio , Alessio Figalli , Gero Friesecke , Johannes Giannoulis , Thierry Paul

The dynamics of Brownian motion has widespread applications extending from transport in designed micro-channels up to its prominent role for inducing transport in molecular motors and Brownian motors. Here, Brownian transport is studied in…

Statistical Mechanics · Physics 2008-07-18 P. S. Burada , G. Schmid , P. Talkner , P. Hänggi , D. Reguera , J. M. Rubí

We first recall that the system of fluid mechanics equations (Euler and continuity) that describes a fluid in irrotational motion subjected to a generalized quantum potential (in which the constant is no longer reduced to the standard…

General Physics · Physics 2010-09-17 Laurent Nottale

We study the quantum transport through entropic barriers induced by hardwall constrictions of hyperboloidal shape in two and three spatial dimensions. Using the separability of the Schrodinger equation and the classical equations of motion…

Chaotic Dynamics · Physics 2015-05-13 R. Hales , H. Waalkens

We consider a general class of nonlinear diffusive models with bulk dissipation and boundary driving, and derive its hydrodynamic description in the large size limit. Both the average macroscopic behavior and the fluctuating properties of…

Statistical Mechanics · Physics 2013-10-29 A. Prados , A. Lasanta , Pablo I. Hurtado

Entanglement fluctuations associated with Schr\"{o}dinger evolution of wavefunctions offer a unique perspective on various fundamental issues ranging from quantum thermalization to state preparation in quantum devices. Very recently, a…

Quantum Physics · Physics 2024-11-25 Cunzhong Lou , Chushun Tian , Zhixing Zou , Tao Shi , Lih-King Lim

A generalisation of Takens' delay-coordinate embedding theorem to stochastic systems, the Stochastic Embedding Sufficiency Theorem, is an inverse methodology enabling non-parametric recovery of both drift and diffusion fields from scalar…

Statistical Mechanics · Physics 2026-05-12 Carolina Garcia , Lucía Perea Durán , Agnese Venezia , Alex Conradie

We use the recently introduced theory for the kinetics of systems of classical particles to investigate systems driven by Smoluchowski dynamics. We investigate the existence of ergodic-nonergodic (ENE) transitions near the liquid-glass…

Soft Condensed Matter · Physics 2011-04-29 Gene F. Mazenko

Stochastic thermodynamics and the associated fluctuation relations provide the means to extend the fundamental laws of thermodynamics to small scales and systems out of equilibrium. The fluctuating thermodynamic variables are usually…

Statistical Mechanics · Physics 2015-05-29 Aki Kutvonen , Tapio Ala-Nissilä , Jukka P. Pekola

We investigate the previously unexplored quantum dynamics of non-relativistic, spinless particles propagating in curved spaces with torsion. Our findings demonstrate that while torsion has been predominantly associated with spin, it can…

General Relativity and Quantum Cosmology · Physics 2025-11-19 Tomoi Koide , Armin van de Venn

We formulate a dynamical fluctuation theory for stationary non equilibrium states (SNS) which is tested explicitly in stochastic models of interacting particles. In our theory a crucial role is played by the time reversed dynamics. Within…

Statistical Mechanics · Physics 2015-12-18 L. Bertini , A. De Sole , D. Gabrielli , G. Jona-Lasinio , C. Landim

Non-equilibrium stochastic dynamics of several active Brownian systems are modeled in terms of non-linear velocity dependent force. In general, this force may consist of both even and odd functions of velocity. We derive the expression for…

Statistical Mechanics · Physics 2016-09-14 Debasish Chaudhuri

Biased diffusive transport of Brownian particles through irregularly shaped, narrow confining quasi-one-dimensional structures is investigated. The complexity of the higher dimensional diffusive dynamics is reduced by means of the so-called…

Statistical Mechanics · Physics 2009-09-22 P. Sekhar Burada , Gerhard Schmid , Peter Hänggi
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