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We present the novel method for generation of periodic surfaces based on the simple Landau-Ginzburg model of microemulsion. We test the method on four minimal surfaces (P,D,G, and I-WP), find two new surfaces of cubic symmetry, show how to…

Condensed Matter · Physics 2015-12-29 W. T. Gozdz , R. Holyst

The polymer systems are discussed in the framework of the Landau-Ginzburg model. The model is derived from the mesoscopic Edwards hamiltonian via the conditional partition function. We discuss flexible, semiflexible and rigid polymers. The…

Condensed Matter · Physics 2007-05-23 Robert Holyst , T. A. Vilgis

In this paper we collect some new observations about periodic critical points and local minimizers of a nonlocal isoperimetric problem, arising in the modeling of diblock copolymers. In the main result, by means of a purely variational…

Analysis of PDEs · Mathematics 2017-11-21 Riccardo Cristoferi

We consider a non local isoperimetric problem arising as the sharp interface limit of the Ohta-Kawasaki free energy introduced to model microphase separation of diblock copolymers. We perform a second order variational analysis that allows…

Analysis of PDEs · Mathematics 2013-07-24 Vesa Julin , Giovanni Pisante

We devise a method for designing materials that will have some desired structural characteristics. We apply it to multiblock copolymers that have two different types of monomers, A and B. We show how to determine what sequence of A's and…

Condensed Matter · Physics 2009-10-28 Tanya Kurosky , J. M. Deutsch

Nanocomposite materials made of block copolymer and nanoparticles display properties which can be different from the purely polymeric matrix. The resulting material is a crossover of the original properties of the block copolymer and the…

Soft Condensed Matter · Physics 2019-11-04 Javier Diaz , Marco Pinna , Andrei V. Zvelindovsky , Ignacio Pagonabarraga

We discuss the local minimality of certain configurations for a nonlocal isoperimetric problem used to model microphase separation in diblock copolymer melts. We show that critical configurations with positive second variation are local…

Analysis of PDEs · Mathematics 2015-06-12 Emilio Acerbi , Nicola Fusco , Massimiliano Morini

We study a variational model for a diblock-copolymer/homopolymer blend. The energy functional is a sharp-interface limit of a generalisation of the Ohta-Kawasaki energy. In one dimension, on the real line and on the torus, we prove…

Mathematical Physics · Physics 2007-10-30 Yves van Gennip , Mark A. Peletier

We consider the problem of minimizing a convex, separable, nonsmooth function subject to linear constraints. The numerical method we propose is a block-coordinate extension of the Chambolle-Pock primal-dual algorithm. We prove convergence…

Optimization and Control · Mathematics 2020-03-26 D. Russell Luke , Yura Malitsky

Polymers consisting of more than one type of monomer, known as copolymers, are vital to both living and synthetic systems. Copolymerisation has been studied theoretically in a number of contexts, often by considering a Markov process in…

The adsorption of a single multi-block $AB$-copolymer on a solid planar substrate is investigated by means of computer simulations and scaling analysis. It is shown that the problem can be mapped onto an effective homopolymer adsorption…

Soft Condensed Matter · Physics 2008-06-27 Swati Bhattacharya , Hsiao-Ping Hsu , Andrey Milchev , Vakhtang G. Rostiashvili , Thomas A. Vilgis

In this paper we study a new model for patterns in two dimensions, inspired by diblock copolymer melts with a dominant phase. The model is simple enough to be amenable not only to numerics but also to analysis, yet sophisticated enough to…

Analysis of PDEs · Mathematics 2013-12-06 D. P. Bourne , M. A. Peletier , S. M. Roper

Using the delta correction to the standard free energy \cite{bc} in the elastic setting with a quadratic foundation term and some parameters, we introduce a one dimension only model for strong segregation in diblock copolymers, whose sharp…

General Mathematics · Mathematics 2009-05-28 Adam Chmaj

We study random copolymers consisted of two kinds of monomers with attraction between similar kinds. The mean field analysis of this system indicates a continuous phase transition into a phase with periodic microdomain structure. It is…

Condensed Matter · Physics 2009-10-22 A. M. Gutin , C. D. Sfatos , E. I. Shakhnovich

We use a standard bead-spring model and molecular dynamics simulations to study the static properties of symmetric linear multiblock copolymer chains and their blocks under poor solvent conditions in a dilute solution from the regime close…

Soft Condensed Matter · Physics 2012-03-05 Panagiotis E. Theodorakis , Nikolaos G. Fytas

In the first part of this work a summary is provided of some recent experiments and theoretical results which are relevant in the research of systems of polymer rings in nontrivial topological conformations. Next, some advances in modeling…

Soft Condensed Matter · Physics 2014-02-04 Yani Zhao , Franco Ferrari

Block copolymers play an important role in materials sciences and have found widespread use in many applications. From a mathematical perspective, they are governed by a nonlinear fourth-order partial differential equation which is a…

Dynamical Systems · Mathematics 2022-08-30 Peter Rizzi , Evelyn Sander , Thomas Wanner

Smoluchowski's coagulation equations can be used as elementary mathematical models for the formation of polymers. We review here some recent contributions on a variation of this model in which the number of aggregations for each atom is a…

Probability · Mathematics 2012-02-24 Jean Bertoin

Coupled-mode systems are used in physical literature to simplify the nonlinear Maxwell and Gross-Pitaevskii equations with a small periodic potential and to approximate localized solutions called gap solitons by analytical expressions…

Analysis of PDEs · Mathematics 2009-11-13 Dmitry Pelinovsky , Guido Schneider

The thermal properties of coarse grained knotted polymers containing two kinds of monomers $A$ and $B$ fluctuating in a solution are investigated on a simple cubic lattice using the Wang-Landau MC algorithm. These knots have a more complex…

Soft Condensed Matter · Physics 2022-09-07 Neda Abbasi Taklimi , Franco Ferrari , Marcin Radosław Piątek , Luca Tubiana
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