English
Related papers

Related papers: Many-electron integrals over gaussian basis functi…

200 papers

Many multi-loop calculations make use of integration by parts relations to reduce the large number of complicated Feynman integrals that arise in such calculations to a simpler basis of master integrals. Recently, Gluza, Kajda, and Kosower…

High Energy Physics - Phenomenology · Physics 2015-06-03 Robert M. Schabinger

In the context of high-energy particle physics, a reliable theory-experiment confrontation requires precise theoretical predictions. This translates into accessing higher-perturbative orders, and when we pursue this objective, we inevitably…

High Energy Physics - Phenomenology · Physics 2024-09-12 German Sborlini

This study presents the derivation of a recursive formula for integrals of products of $N$ Hermite polynomials, establishing a numerically stable scheme for their accurate evaluation in computer codes. The derivation is notably simple and…

Quantum Physics · Physics 2026-02-25 Tran Duong Anh-Tai , Phan Quang Son , Le Minh Khang , Nguyen Duy Vy , Vinh N. T. Pham

Evaluation of basic integrals over Gaussian functions, traditionally utilized for electronic structure computations on molecules and solids, is discussed in a pedagogical form.

Quantum Physics · Physics 2020-07-24 Justin T. Fermann , Edward F. Valeev

In this paper, we develop algorithms for computing the recurrence coefficients corresponding to multiple orthogonal polynomials on the step-line. We reformulate the problem as an inverse eigenvalue problem, which can be solved using…

Numerical Analysis · Mathematics 2026-03-05 Amin Faghih , Michele Rinelli , Marc Van Barel , Raf Vandebril , Robbe Vermeiren

We present algorithms for computing weakly singular and near-singular integrals arising when solving the 3D Helmholtz equation with curved boundary elements. These are based on the computation of the preimage of the singularity in the…

Numerical Analysis · Mathematics 2022-06-28 Hadrien Montanelli , Matthieu Aussal , Houssem Haddar

We present the Electronic Tensor Reconstruction Algorithm (ELECTRA) - an equivariant model for predicting electronic charge densities using floating orbitals. Floating orbitals are a long-standing concept in the quantum chemistry community…

Machine Learning · Computer Science 2026-01-27 Jonas Elsborg , Luca Thiede , Alán Aspuru-Guzik , Tejs Vegge , Arghya Bhowmik

A simple scheme is described for introducing the correct cusps at nuclei into orbitals obtained from Gaussian basis set electronic structure calculations. The scheme is tested with all-electron variational quantum Monte Carlo (VMC) and…

Computational Physics · Physics 2008-01-18 A. Ma , M. D. Towler , N. D. Drummond , R. J. Needs

We present a system of canonical differential equations satisfied by the three-loop banana integrals with four distinct non-zero masses in $D = 2-2\eps$ dimensions. Together with the initial condition in the small-mass limit, this provides…

High Energy Physics - Theory · Physics 2025-12-09 Claude Duhr , Sara Maggio , Franziska Porkert , Cathrin Semper , Sven F. Stawinski

All-electron calculations play an important role in density functional theory, in which improving computational efficiency is one of the most needed and challenging tasks. In the model formulations, both nonlinear eigenvalue problem and…

Computational Physics · Physics 2020-07-29 Bin Gao , Guanghui Hu , Yang Kuang , Xin Liu

The proposal for quantum computing with rare-earth-ion qubits in inorganic crystals makes use of the inhomogeneous broadening of optical transitions in the ions to associate individual qubits with ions responding to radiation in selected…

Quantum Physics · Physics 2009-11-10 Ingela Roos , Klaus Molmer

In the present letter, it is demonstrated how full configuration interaction (FCI) results in extended basis sets may be obtained to within sub-kJ/mol accuracy by decomposing the energy in terms of many-body expansions in the virtual…

Chemical Physics · Physics 2017-09-15 Janus J. Eriksen , Filippo Lipparini , Jürgen Gauss

We report a method for the evaluation of the one-loop self-energy, to all orders in the external binding field, using a Gaussian basis set expansion. This choice of basis is motivated by its widespread use in molecular calculations. For a…

Quantum Physics · Physics 2025-04-14 Dávid Ferenc , Maen Salman , Trond Saue

We consider functions $f$ of two real variables, given as trigonometric functions over a finite set $F$ of frequencies. This set is assumed to be closed under rotations in the frequency plane of angle $\frac{2k\pi}{M}$ for some integer $M$.…

Numerical Analysis · Mathematics 2016-12-02 Jean-Paul Gauthier , Dario Prandi

In this article we present an algorithm to efficiently evaluate the exchange matrix in periodic systems when Gaussian basis set with pseudopotentials are used. The usual algorithm for evaluating exchange matrix scales cubically with the…

Strongly Correlated Electrons · Physics 2022-11-11 Sandeep Sharma , Alec F. White , Gregory Beylkin

This paper presents a high-order accurate numerical quadrature algorithm for evaluating integrals over curved surfaces and regions defined implicitly via a level set of a given function restricted to a hyperrectangle. The domain is divided…

Numerical Analysis · Mathematics 2025-06-17 Zibo Zhao

We present analytical formulas for the calculation of the two-center two-electron integrals in the basis of Slater geminals and products of Slater orbitals. Our derivation starts with establishing a inhomogeneous fourth-order ordinary…

Quantum Physics · Physics 2012-12-07 Michał Lesiuk , Robert Moszynski

In this paper, we consider the Dirac-Coulomb equation for many-particles, to describe the interaction between electrons in the system having many electrons. The four-component wave function will expanding into a finite basis-set, using…

Quantum Physics · Physics 2019-12-10 Bilal K. Jasim , Ayad A. Al-Ani , Saad N. Abood

Perturbation theory (PT) is often used to model statistical observables capturing the translation and rotation-invariant information in cosmological density fields. PT produces higher-order corrections by integration over linear statistics…

Cosmology and Nongalactic Astrophysics · Physics 2018-12-07 Zachary Slepian

Standard integration-by-parts (IBP) reduction methods typically yield Feynman integral bases where the reduction of some integrals gives rise to coefficients singular as the dimensional regulator $\epsilon\rightarrow 0$. These singular…

High Energy Physics - Theory · Physics 2025-08-07 Stefano De Angelis , David A. Kosower , Rourou Ma , Zihao Wu , Yang Zhang