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The question of optical bandgap anisotropy in the monoclinic semiconductor $\beta$-Ga2O3 was revisited by combining accurate optical absorption measurements with theoretical analysis, performed using different advanced computation methods.…

The low energy electronic structure of LaFeAsO1-xHx (0.0 < x < 0.60), the system which exhibits two superconducting domes in its phase diagram, is investigated by utilizing the laser photoemission spectroscopy. From the precise…

Superconductivity · Physics 2017-02-08 A. Nakamura , T. Shimojima , T. Sonobe , K. Ishizaka , W. Malaeb , S. Shin , S. Iimura , S. Matsuishi , H. Hosono

Epitaxial thin films of SrTiO$_3$(100) doped with 6% and 12% Ni are studied with resonant angle-resolved photoelectron spectroscopy (ARPES) at the Ti and Ni L2,3-edges. We find that the Ni doping shifts the valence band (VB) of pristine…

Structural and Optical properties of the (Na0.5 K0.5)y Li 1-y NbO3 (y = 0.934 & 0.936) ceramics have been explored in terms of the X-Ray diffraction patters, Rietveld analysis, UV-Vis spectroscopy, and Kubelka-Munk functions. Rietveld…

Materials Science · Physics 2015-06-17 S. K. Mishra , R. K. Mishra , Kumar Brajesh , Rajyavardhan Ray , A. K. Himanshu , N. K. Singh

A theoretical study of Al(1-x)Ga(x)N, based on full-potential linearized augmented plane wave method, is used to investigate the variations in the bandgap, optical properties and non-linear behavior of the compound with the variation of Ga…

Materials Science · Physics 2015-03-17 B. Amin , Iftikhar Ahmad , M. Maqbool , S. Goumri-Said , R. Ahmad

A large number of published experimental works suggest that when the Fe ions in orthorhombic LaFeO3 are substituted, band gap reduction is expected. However, recent experimental works observe band gap enhancement with increasing Ti ions…

Materials Science · Physics 2024-01-23 Jesaya Situmeang , Djoko Triyono , Muhammad Aziz Majidi

In this report, the optical properties of Ta doped SrTiO3 (STO) due to its potential in transparent conducting oxides (TCOs) is explored by a combination of theoretical studies based on density functional theory and spectroscopic…

Materials Science · Physics 2024-11-25 Shammi Kumar , Raja Sen , Mamta Arya , Sankar Dhar , Priya Johari

Hexagonal LuFeO$_3$ films have been studied using x-ray absorption and optical spectroscopy. The crystal splittings of Fe$^{3+}$ are extracted as $E_{e'}-E_{e"}$=0.7 eV and $E_{a_1'}-E_{e'}$=0.9 eV and a 2.0 eV optical band gap is…

Angle resolved photoemission spectroscopy of Ba(Fe1-xCox)2As2 (x = 0.06, 0.14, and 0.24) shows that the width of the Fe 3d yz/zx hole band depends on the doping level. In contrast, the Fe 3d x^2-y^2 and 3z^2-r^2 bands are rigid and shifted…

Epitaxial thin films of Fe doped SrTiO3 have been studied by the use of resonant photoemission. This technique allowed to identify contributions of the Fe and Ti originating electronic states to the valence band. Two valence states of iron…

Materials Science · Physics 2015-09-29 J. Szade , D. Kajewski , J. Kubacki , K. Szot , A. Koehl , Ch. Lenser , R. Dittmann

The role of doping Fe on the structural, magnetic and dielectric properties of frustrated antiferromagnet YMn1-xFexO3 (x less than or equal to 0.5) has been investigated. The neutron diffraction analysis shows that the structure of these…

Materials Science · Physics 2014-05-28 Neetika Sharma , A. Das , S. K. Mishra , C. L. Prajapat , M. R. Singh , S. S. Meena

Using a first-principles band-structure method and a special quasirandom structure (SQS) approach, we systematically calculate the band gap bowing parameters and \emph{p}-type doping properties of (Zn, Mg, Be)O related random ternary and…

Materials Science · Physics 2009-12-01 Hongliang Shi , Yifeng Duan

Herein, we present a detailed study of the structural, optical, and electrochemical responses of Gd$_2$O$_3$ doped with nickel zinc ferrite nanoparticles. Doping of Ni$_{0.5}$Zn$_{0.5}$Fe$_2$O$_4$ nanoparticles to Gd$_2$O$_3$ powder was…

Materials Science · Physics 2023-05-09 M. Azeem , Q. Abbas , M. A. Abdelkareem , A. G. Olabi

The electronic structure and the band gap behavior of CH$_3$NH$_3$Pb(I$_{1-x}$Br$_x$)$_3$ for $x$=0.25, 0.33, 0.50, 0.67, 0.75, 1.00 were studied using the full-relativistic density-functional-theory calculations. A combination of the…

Materials Science · Physics 2024-09-26 Sergei M. Butorin

We measured the in-plane optical conductivity of a nearly optimally doped (Ba,K)Fe2As2 single crystal with Tc = 39.1 K. Upon entering the superconducting state the optical conductivity below ~20 meV vanishes, strongly suggesting a fully…

Superconductivity · Physics 2015-01-09 Y. M. Dai , B. Xu , B. Shen , H. H. Wen , X. G. Qiu , R. P. S. M. Lobo

We report on the evidenced orbital mediated electron phonon coupling and band gap tuning in HoFe1-xCrxO3 compounds. From the room temperature Raman scattering, it is apparent that the electron-phonon coupling is sensitive to the presence of…

Materials Science · Physics 2016-06-15 Ganesh Kotnana , S. Narayana Jammalamadaka

La-doped ASnO3 (A = Ba, Sr) have great potential as advanced transparent oxide semiconductors due to their large optical bandgap and relatively high electron mobility. The bandgap of Ba1-xSrxSnO3 solid solution increases from 3.2 eV…

Materials Science · Physics 2020-05-05 Hai Jun Cho , Koichi Sato , Mian Wei , Gowoon Kim , Hiromichi Ohta

Advanced theoretical investigations are crucial for understanding the structural growth mechanisms, optoelectronic properties, and photocatalytic activity of photoelectrodes for efficient photoelectrochemical water splitting. In this work,…

Materials Science · Physics 2025-03-24 Abdul Ahad Mamun , Muhammad Anisuzzaman Talukder

A first-principles study has been performed to evaluate the electronic and optical properties of wurtzite Zn1-xCdxO up to x=0.25. We have employed the Perdew-Burke-Ernzerhof (PBE) form of generalized gradient approximation within the…

Materials Science · Physics 2012-10-02 X. D. Zhang , M. L. Guo , W. X. Li , C. L. Liu

To investigate the scope of ferroelectric behavior in La-substituted BiFeO3 films, LaxBi1-xFeO3 epitaxial films were synthesized using off-axis co-sputtering on SrTiO3(001) and DyScO3(110) substrates with a SrRuO3 bottom electrode layer. A…