Related papers: Up-Hill Diffusion Creating Density Gradient - What…
The Hamiltonian evolution of an isolated classical system is reversible, yet the second law of thermodynamics states that its entropy can only increase. This has confounded attempts to identify a `Microscopic Dynamical Entropy' (MDE), by…
In our derivation of the second law of thermodynamics from the relation of adiabatic accessibility of equilibrium states we stressed the importance of being able to scale a system's size without changing its intrinsic properties. This…
We generalize Gaspard's method for computing the \epsilon-entropy production rate in Hamiltonian systems to dissipative systems with attractors considered earlier by T\'el, Vollmer, and Breymann. This approach leads to a natural definition…
Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…
The entropy production is one of the most essential features for systems operating out of equilibrium. The formulation for discrete-state systems goes back to the celebrated Schnakenberg's work and hitherto can be carried out when for each…
We propose a thermodynamically motivated measure of gravitational entropy based on the Bel-Robinson tensor, which has a natural interpretation as the effective super-energy-momentum tensor of free gravitational fields. The specific form of…
In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…
The Second Law of Thermodynamics asserts that the physical entropy of an adiabatic system is an increasing function in time. In this paper we will study a more stringent version of this law, according to which the entropy should not only…
Usually, in a non-equilibrium setting, a current brings mass from the highest density regions to the lowest density ones. Although rare, the opposite phenomenon (known as "uphill diffusion") has also been observed in multicomponent systems,…
For a dynamical system far from equilibrium, one has to deal with empirical probabilities defined through time-averages, and the main problem is then how to formulate an appropriate statistical thermodynamics. The common answer is that the…
Statistical mechanics relies on the complete though probabilistic description of a system in terms of all the microscopic variables. Its object is to derive therefrom static and dynamic properties involving some reduced set of variables.…
We consider an isolated system in an arbitrary state and provide a general formulation using first principles for an additive and non-negative statistical quantity that is shown to reproduce the equilibrium thermodynamic entropy of the…
Entropy rate is a real valued functional on the space of discrete random sources which lacks a closed formula even for subclasses of sources which have intuitive parameterizations. A good way to overcome this problem is to examine its…
We show that the concept of entropy and the dynamics of gravitation provide the linchpin in a unified scheme to understand the physics of black hole computers, space-time foam, dark energy, dark matter and the phenomenon of turbulence. We…
The present paper studies a large class of temperature dependent probability distributions and shows that entropy and energy can be defined in such a way that these probability distributions are the equilibrium states of a generalized…
For a colloidal particle driven by a constant force across a periodic potential, we investigate the distribution of entropy production both experimentally and theoretically. For short trajectories, the fluctuation theorem holds…
Approximations to the exact density functional for the exchange-correlation energy of a many-electron ground state can be constructed by satisfying constraints that are universal, i.e., valid for all electron densities. Gedanken densities…
An internal energy function of the mass density, the volumetric entropy and their gradients at n-order generates the representation of multi-gradient fluids. Thanks to Hamilton's principle, we obtain a thermodynamical form of the equation…
The classical thermostatics of equilibrium processes is shown to possess a quantum-mechanical dual theory with a finite-dimensional Hilbert space of quantum states. Specifically, the kernel of a certain Hamiltonian operator becomes the…
In statistical physics, useful notions of entropy are defined with respect to some coarse graining procedure over a microscopic model. Here we consider some special problems that arise when the microscopic model is taken to be relativistic…