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In the works on Statistical Mechanics and Statistical Physics, when deriving the distribution of particles of ideal gases, one uses the method of Lagrange multipliers in a formal way. In this paper we treat rigorously this problem for…
The paper analyzes the entropy of a system composed by non-interacting and indistinguishable particles whose quantum state numbers are modelled as independent and identically distributed classical random variables. The crucial observation…
We formulate a geometric framework in which physical laws emerge from restricted access to microscopic information. Measurement constraints are modeled as a gauge symmetry acting on density operators, inducing a gauge-reduced space of…
Finite thermostats are studied in the context of nonequilibrium statistical mechanics. Entropy production rate has been identified with the mechanical quantity expressed by the phase space contraction rate and the currents have been linked…
To explain black hole thermodynamics in quantum gravity, one must introduce constraints to ensure that a black hole is actually present. I show that for a large class of black holes, such ``horizon constraints'' allow the use of conformal…
Observational entropy provides a general notion of quantum entropy that appropriately interpolates between Boltzmann's and Gibbs' entropies, and has recently been argued to provide a useful measure of out-of-equilibrium thermodynamic…
In effective field theory, the positivity bounds of higher derivative operators are derived from analyticity, causality, and unitarity. We show that the positivity bounds on some operators of the effective field theory, e.g.,…
We study a spatial diffusion process generated by velocity fluctuations of intermittent nature. We note that intermittence reduces the entropy production rate while enhancing the diffusion strength. We study a case of space-dependent…
The Bekenstein-Hawking entropy suggests that thermodynamics is an intrinsic ingredient of gravity. Here, we explore the idea that requirements of thermodynamic consistency could determine the gravitational entropy in other set-ups. We…
Experimental and theoretical results about entropy limits for macroscopic and single-particle systems are reviewed. It is clarified when it is possible to speak about a quantum of entropy, given by the Boltzmann constant k, and about a…
Based on a cocycle structure, we identify a new derivation of the Boltzmann distribution for finite energy-level systems from the maximal entropy principle (MEP). Our approach does not rely on the method of the Lagrange multiplier, and it…
The phase space contraction and the entropy production rates of Hamiltonian systems in an external field, thermostatted to obtain a stationary state are considered. While for stationary states with a constant kinetic energy the two rates…
The expressions for entropy production, free energy, and entropy extraction rates are derived for a Brownian particle that walks in an underdamped medium. Our analysis indicates that as long as the system is driven out of equilibrium, it…
A derivation of the Boltzmann equation from the Liouville equation by the use of the Grad limiting procedure in a finite volume is proposed. We introduce two scales of space-time: macro- and microscale and use the BBGKY hierarchy and the…
We introduce a constructive framework for assigning thermodynamic structure to an arbitrary data system from its measured microstates. Starting from an empirical distribution over configurations, we first infer a data-driven energy function…
Entropy in nonequilibrium statistical mechanics is investigated theoretically so as to extend the well-established equilibrium framework to open nonequilibrium systems. We first derive a microscopic expression of nonequilibrium entropy for…
Since the early nineties, it has been observed that the Schroedinger bridge problem can be formulated as a stochastic control problem with atypical boundary constraints. This in turn has a fluid dynamic counterpart where the flow of…
Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…
Statistical entropies of a general relativistic ideal gas obeying Maxwell-Boltzmann, Bose-Einstein and Fermi-Dirac statistics are calculated in a general axisymmetry space-time of arbitrary dimension. This general formation can be used to…
We consider optimization of the average entropy production in inhomogeneous temperature environments within the framework of stochastic thermodynamics. For systems modeled by Langevin equations (e.g. a colloidal particle in a heat bath) it…