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Our main objective in this paper is to develop a second-order stochastic numerical method which generalizes the well-known deterministic TR-BDF2 scheme. Since most stochastic techniques used for approximating the solution of a stochastic…

Numerical Analysis · Mathematics 2026-02-12 Tomás Caraballo , Macarena Gómez-Mármol , Ignacio Roldán

A method based on separated integration to estimate anharmonic corrections to energy and vibration of molecules in a second-order diagrammatic vibrational many-body Green's function formalism has already been presented. A severe bottleneck…

Chemical Physics · Physics 2019-09-17 Prashant Rai , Khachik Sargsyan , Habib Najm , So Hirata

Parameters of differential equations are essential to characterize intrinsic behaviors of dynamic systems. Numerous methods for estimating parameters in dynamic systems are computationally and/or statistically inadequate, especially for…

Methodology · Statistics 2026-01-27 Jianbin Tan , Guoyu Zhang , Xueqin Wang , Hui Huang , Fang Yao

A stochastic resolution of identity approach (sRI) is applied to the second-order coupled cluster singles and doubles (CC2) model to calculate the ground-state energy. Utilizing a set of stochastic orbitals to optimize the expensive tensor…

Chemical Physics · Physics 2022-10-25 Chongxiao Zhao , Wenjie Dou

Recent results obtained by applying the method of self-consistent Green's functions to nuclei and nuclear matter are reviewed. Particular attention is given to the description of experimental data obtained from the (e,e'p) and (e,e'2N)…

Nuclear Theory · Physics 2009-11-10 W. H. Dickhoff , C. Barbieri

An approach is presented which allows a self-consistent description of the fragmentation of single-particle strength for nucleons in finite nuclei employing the Greens function formalism. The self-energy to be considered in the Dyson…

Nuclear Theory · Physics 2009-10-22 H. Müther , L. D. Skouras

The self-consistent theory of the correlation effects in Highly Correlated Systems(HCS) is presented. The novel Irreducible Green's Functions(IGF) method is discused in detail for the Hubbard model and random Hubbard model. The…

Strongly Correlated Electrons · Physics 2008-02-03 A. L. Kuzemsky

The convergence property of a stochastic algorithm for the self-consistent field (SCF) calculations of electron structures is studied. The algorithm is formulated by rewriting the electron charges as a trace/diagonal of a matrix function,…

Numerical Analysis · Mathematics 2023-04-20 Taehee Ko , Xiantao Li

By using recent developments for the Langevin dynamics of spatially asymmetric systems, we routinely generalize the Onsager-Machlup fluctuation theory of the second order in time. In this form, it becomes applicable to fluctuating…

Statistical Mechanics · Physics 2016-12-28 Roman Belousov , E. G. D. Cohen

We present a scalable single-particle framework to treat electronic correlation in molecules and materials motivated by Green's function theory. We derive a size-extensive Brillouin-Wigner perturbation theory from the single-particle…

Chemical Physics · Physics 2023-09-12 Christopher J. N. Coveney , David P. Tew

We present a self-consistent approach for computing the correlated quasiparticle spectrum of charged excitations in iterative $\mathcal{O}[N^5]$ computational time. This is based on the auxiliary second-order Green's function approach [O.…

Chemical Physics · Physics 2020-10-05 Oliver J. Backhouse , George H. Booth

We present an approach for GW calculations of quasiparticle energies with quasi-quadratic scaling by approximating high-energy contributions to the Green's function in its Lehmann representation with effective stochastic vectors. The method…

Materials Science · Physics 2023-12-07 Aaron R. Altman , Sudipta Kundu , Felipe H. da Jornada

We develop a time dependent second order Green's function theory (GF2) for calculating neutral excited states in molecules. The equation of motion for the lesser Green's function (GF) is derived within the adiabatic approximation to the…

Chemical Physics · Physics 2022-01-19 Wenjie Dou , Joonho Lee , David R. Reichman , Roi Baer , Eran Rabani

This article presents an overview on recent progress in the theory of nonequilibrium Green functions (NEGF). NEGF, presently, are the only \textit{ab-initio} quantum approach that is able to study the dynamics of correlations for long times…

Strongly Correlated Electrons · Physics 2019-12-20 N. Schluenzen , S. Hermanns , M. Scharnke , M. Bonitz

The self-energy method for quantum impurity models expresses the correlation part of the self-energy in terms of the ratio of two Green's functions and allows for a more accurate calculation of equilibrium spectral functions than is…

Strongly Correlated Electrons · Physics 2021-11-24 H. T. M. Nghiem , T. A. Costi

With a super-high-efficient numerical algorithm, we are able to self-consistently calculate the Green's function in the renormalized-ring-diagram approximation for a two-dimensional electron system with long-range Coulomb interactions. The…

Strongly Correlated Electrons · Physics 2011-11-09 Xin-Zhong Yan , C. S. Ting

Quantum chemical methods dealing with challenging systems while retaining low computational costs have attracted attention. In particular, many efforts have been devoted to developing new methods based on the second-order perturbation that…

Chemical Physics · Physics 2023-10-30 Nhan Tri Tran , Hoang Thanh Nguyen , Lan Nguyen Tran

We demonstrate in the present study that self-consistent calculations based on the self-energy functional theory (SFT) are possible for the electronic structure of realistic systems in the context of quantum chemistry. We describe the…

Materials Science · Physics 2018-06-14 Taichi Kosugi , Hirofumi Nishi , Yoritaka Furukawa , Yu-ichiro Matsushita

Long-range correlations, which are partially responsible for the observed fragmentation and depletion of low-lying single-particle strength, are studied in the Green's function formalism. The self-energy is expanded up to second order in…

Nuclear Theory · Physics 2009-10-30 Y. Dewulf , D. Van Neck , L. Van Daele , M. Waroquier

We present a rigorous framework that combines single-particle Green's function theory with density functional theory based on a separation of electron-electron interactions into short-range and long-range components. Short-range…

Chemical Physics · Physics 2018-06-07 Alexei A. Kananenka , Dominika Zgid