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For complex molecules, nuclear degrees of freedom can act as an environment for the electronic `system' variables, allowing the theory and concepts of open quantum systems to be applied. However, when molecular system-environment…

Quantum Physics · Physics 2021-01-05 Angus J. Dunnett , Alex W. Chin

Real-time time-dependent density functional theory (TDDFT) is widely considered to be the most accurate available method for calculating electronic stopping powers from first principles, but there have been relatively few assessments of the…

Computational Physics · Physics 2024-01-18 Alina Kononov , Alexander J. White , Katarina A. Nichols , S. X. Hu , Andrew D. Baczewski

We illustrate the scope of Time Dependent Density Functional Theory (TDDFT) for strongly correlated (lattice) models out of equilibrium. Using the exact many body time evolution, we reverse engineer the exact exchange correlation (xc)…

Mesoscale and Nanoscale Physics · Physics 2008-08-12 Claudio Verdozzi

Cavity quantum electrodynamics (QED) generalizations of time-dependent (TD) density functional theory (DFT) and equation-of-motion (EOM) coupled-cluster (CC) theory are used to model small molecules strongly coupled to optical cavity modes.…

Chemical Physics · Physics 2023-07-19 Marcus D. Liebenthal , Nam Vu , A. Eugene DePrince

We propose a nonadiabatic time-dependent spin-density functional theory (TDSDFT) approach for studying the single-electron excited states and the ultrafast response of systems with strong electron correlations. The correlations are…

Strongly Correlated Electrons · Physics 2013-11-27 Volodymyr Turkowski , Talat S. Rahman

In this contribution, we extend our framework for analyzing and visualizing correlated many-electron dynamics to non-variational, highly scalable electronic structure method. Specifically, an explicitly time-dependent electronic wave packet…

Chemical Physics · Physics 2017-04-27 Gunter Hermann , Vincent Pohl , Jean Christophe Tremblay

In 2D topological insulators (TIs) based on semiconductor quantum wells such as HgTe/CdTe or InAs/GaSb/AlSb, spin polarized edge states have been predicted with a massless Dirac like dispersion. In a hard wall treatment based on the 4 x 4…

Mesoscale and Nanoscale Physics · Physics 2021-11-17 P. C. Klipstein

We propose a novel method to describe realistically ionization processes with absorbing boundary conditions in basis expansion within the formalism of the so-called Non-Adiabatic Quantum Molecular Dynamics. This theory couples…

Quantum Physics · Physics 2015-06-26 Mathias Uhlmann , Thomas Kunert , Ruediger Schmidt

We study the effects of a finite cubic volume with twisted boundary conditions on pseudoscalar mesons. We first apply chiral perturbation theory in the p-regime and calculate the corrections for masses, decay constants, pseudoscalar…

High Energy Physics - Lattice · Physics 2016-08-24 Gilberto Colangelo , Alessio Vaghi

The logical structure and the basic theorems of time-dependent current density functional theory (TDCDFT) are analyzed and reconsidered from the point of view of recently proposed time-dependent deformation functional theory (TDDefFT). It…

Strongly Correlated Electrons · Physics 2019-03-27 I. V. Tokatly

Time-dependent density functional theory continues to draw a large number of users in a wide range of fields exploring myriad applications involving electronic spectra and dynamics. Although in principle exact, the predictivity of the…

Chemical Physics · Physics 2023-08-14 Lionel Lacombe , Neepa T. Maitra

We present a formulation of spin-conserving and spin-flip, hybrid time-dependent density functional theory (TDDFT), including the calculation of analytical forces, which allows for efficient calculations of excited state properties of…

Materials Science · Physics 2023-12-05 Yu Jin , Victor Wen-zhe Yu , Marco Govoni , Andrew C Xu , Giulia Galli

We model the dynamics of a closed quantum system brought out of mechanical equilibrium, undergoing a non-driven, spontaneous, thermodynamic transformation. In particular, we consider a quantum particle in a box with a moving and insulating…

Quantum Physics · Physics 2024-02-21 Sofia Sgroi , Mauro Paternostro

Explaining quantum many-body dynamics is a long-held goal of physics. A rigorous operator algebraic theory of dynamics in locally interacting systems in any dimension is provided here in terms of time-dependent equilibrium (Gibbs)…

Statistical Mechanics · Physics 2023-08-08 Berislav Buča

For a wide class of noninteracting tight-binding models in one dimension we present an analytical solution for all scattering and edge states on a half-infinite system. Without assuming any symmetry constraints we consider models with…

Mesoscale and Nanoscale Physics · Physics 2020-04-14 Mikhail Pletyukhov , Dante M. Kennes , Jelena Klinovaja , Daniel Loss , Herbert Schoeller

In this paper a new formulation of quantum dynamics of totally constrained systems is developed, in which physical quantities representing time are included as observables. In this formulation the hamiltonian constraints are imposed on a…

General Relativity and Quantum Cosmology · Physics 2010-11-19 Hideo Kodama

Density Functional Theory (DFT) is widely used for atomistic simulations. However, its reach stays limited due to several limitations such as lack of accurate exchange-correlation functional, requirement of costly O(N 3) diagonalization…

Quantum Physics · Physics 2026-05-18 Namrata Manglani , Samrit Kumar Maity , Shashank Sharma , Soham Phulare , Sanjay Wandhekar

We provide a new formulation of Time-Dependent Density Functional Theory (TDDFT) based on the geometric structure of the set of states constrained to have a fixed density. Orbital-free TDDFT is formulated using a hydrodynamics equation…

Critical systems are described by conformal field theories, whose dynamics can be exactly solved in two dimensions. In the presence of a boundary, with the so-called method of images it is possible to study the surface critical behaviour of…

High Energy Physics - Theory · Physics 2007-05-23 Valentina Riva

In lattice quantum field theories with topological sectors, simulations at fine lattice spacings --- with typical algorithms --- tend to freeze topologically. In such cases, specific topological finite size effects have to be taken into…

High Energy Physics - Lattice · Physics 2015-10-30 Arthur Dromard , Wolfgang Bietenholz , Urs Gerber , Héctor Mejía-Díaz , Marc Wagner
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