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We ascertain the anisotropic thermal conductivity of alumina passivated black phosphorus (BP), a reactive 2D nanomaterial with strong in-plane anisotropy. We measure the room temperature thermal conductivity by time-domain thermoreflectance…

Materials Science · Physics 2015-10-02 Hyejin Jang , Joshua D. Wood , Christopher R. Ryder , Mark C. Hersam , David G. Cahill

With a semiconducting band gap and high charge carrier mobility, two-dimensional (2D) black phosphorus (BP), often referred to as phosphorene, holds significant promise for next generation electronics and optoelectronics. However, as a 2D…

Materials Science · Physics 2015-02-10 Xiaolong Liu , Joshua D. Wood , Kan-Sheng Chen , EunKyung Cho , Mark C. Hersam

We demonstrate the large scale exfoliation of bulk black phosphorus into few-layers black phosphorus. We use wet-jet mill (WJM) as an industrially scalable exfoliation technique. In order to avoid the degradation by oxidation of the…

Solution-processed two-dimensional (2D) materials hold promise for their scalable applications. However, the random, fragmented nature of the solution-processed nanoflakes and the poor percolative conduction through their discrete networks…

Although a considerable number of solvent based methodologies have been developed for exfoliating black phosphorus, so far there are no reports on controlled organization of these exfoliated nanosheets on substrates. Here, for the first…

The exceptional interest in improving the limitations of data storage, molecular electronics, and optoelectronics has promoted the development of an ever increasing number of techniques used to pattern polymers at micro and nanoscale. Most…

Atomically-thin films of phosphorene (also known as black phosphorus) are a low dimensional optical material with direct exciton emission, whose wavelength is tunable by controlling the number of layers. In addition to this excitonic…

Mesoscale and Nanoscale Physics · Physics 2017-07-03 Shahriar Aghaeimeibodi , Je-Hyung Kim , Edo Waks

Mid-infrared saturable absorber mirror is successfully fabricated by transferring the mechanically exfoliated black phosphorus onto the gold-coated mirror. With the as-prepared black phosphorus saturable absorber mirror, a continuous-wave…

Optics · Physics 2015-09-23 Zhipeng Qin , Guoqiang Xie , Chujun Zhao , Shuangchun Wen , Peng Yuan , Liejia Qian

As a new two-dimensional layered material, black phosphorus (BP) is a promising material for nanoelectronics and nano-optoelectronics. We use Raman spectroscopy and first-principles theory to report our findings related to low-frequency…

Black phosphorus (BP) stands out from other 2D materials by the wide amplitude of the band-gap energy (Delta(Eg)) that sweeps an optical window from Visible (VIS) to Infrared (IR) wavelengths, depending on the layer thickness. This…

Screening in reduced dimensions has strong consequences on the electronic properties in van der Waals semiconductors, impacting the quasiparticle band gap and exciton binding energy. Screening in these materials is typically treated…

We review the Raman shift method as a non-destructive optical tool to investigate the thermal conductivity and demonstrate the possibility to map this quantity with a micrometer resolution by studying thin film and bulk materials for…

Materials Science · Physics 2015-06-22 B. Stoib , S. Filser , J. Stötzel , A. Greppmair , N. Petermann , H. Wiggers , G. Schierning , M. Stutzmann , M. S. Brandt

Phosphorene is a promising two dimensional (2D) material with a direct band gap, high carrier mobility, and anisotropic electronic properties. Phosphorene-based electronic devices, however, are found to degrade upon exposure to air. In this…

Materials Science · Physics 2016-04-14 Gaoxue Wang , William J. Slough , Ravindra Pandey , Shashi P. Karna

We report the observation in the direct space of the transport of a few thousand charges submitted to a tunable electric field along the surface of a silicon oxide layer. Charges are both deposited and observed using the same Electrostatic…

Condensed Matter · Physics 2007-05-23 J. S. Lambert , G. De Loubens , C. Guthmann , M. Saint-Jean , T. Melin

Hydrogen fuel cells offer a clean and sustainable energy conversion solution. The bipolar separator plate, a critical component in fuel cells, plays a vital role in preventing reactant gas cross-contamination and facilitating efficient ion…

Materials Science · Physics 2023-08-31 Taemin Ahn , Tae-Hwan Kim

We report on our results for the characterization of Si:P delta-layers grown by low temperature molecular beam epitaxy. Our data shows that the effective thickness of a delta-layer can be obtained through a weak localization analysis of…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 D. F. Sullivan , B. E. Kane , P. E. Thompson

Two-dimensional (2D) materials, such as graphene and transition metal dichalcogenides have attracted great attention because of the rich physics and potential applications in next-generation nano-sized electronic devices. Recently,…

Materials Science · Physics 2015-05-25 Xiaolong Chen , Yingying Wu , Zefei Wu , Shuigang Xu , Lin Wang , Yu Han , Weiguang Ye , Tianyi Han , Yuheng He , Yuan Cai , Ning Wang

Black phosphorus (BP) is an emerging two-dimensional semiconducting material with great potential for nanoelectronic and nanophotonic applications, especially owing to its unique anisotropic electrical and optical properties. Many…

We report a scalable approach to synthesize a large-area (up to 4 mm) thin black phosphorus (BP) film on a flexible substrate. We first deposited a red phosphorus (RP) thin-film on a flexible polyester substrate, followed by its conversion…

The possibility of hybridizing collective electronic motion with mid-infrared (mid-IR) light to form surface polaritons has made van der Waals layered materials a versatile platform for extreme light confinement and tailored nanophotonics.…

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