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We combined mapping-mode mid-infrared Spitzer spectra with complementary infrared imaging to perform a spatially resolved study of polycyclic aromatic hydrocarbons (PAHs) emission from the central regions of 66 nearby galaxies, roughly…

Astrophysics of Galaxies · Physics 2022-12-13 Lulu Zhang , Luis C. Ho , Aigen Li

The molecular species hydrogen peroxide, HOOH, is likely to be a key ingredient in the oxygen and water chemistry in the interstellar medium. Our aim with this investigation is to determine how abundant HOOH is in the cloud core {\rho} Oph…

Astrophysics of Galaxies · Physics 2011-06-02 P. Bergman , B. Parise , R. Liseau , B. Larsson , H. Olofsson , K. M. Menten , R. Güsten

We have developed a new massively-parallel radiation-hydrodynamics code (Cosmos) for Newtonian and relativistic astrophysical problems that also includes radiative cooling, self-gravity, and non-equilibrium, multi-species chemistry. Several…

Astrophysics · Physics 2009-11-07 Peter Anninos , P. Chris Fragile , Stephen D. Murray

Observations of diffuse clouds showed that they contain a number of simple hydrocarbons (e.g. CH, C$_2$H, (l- and c-)C$_3$H$_2$, and C$_4$H) in abundances that may be difficult to understand on the basis of conventional gas-phase chemical…

Astrophysics of Galaxies · Physics 2022-02-02 Zainab Awad , Serena Viti

Using the molecular dynamics method, dynamics of hydrogen bond (HB) networks emerging on the surface of a graphene sheet during its functionalization with hydroxyl groups OH are simulated. It is demonstrated that two OH groups form an…

Mesoscale and Nanoscale Physics · Physics 2020-12-30 Alexander V. Savin

Water is the main component of interstellar ice mantles, is abundant in the solar system and is a crucial ingredient for life. The formation of this molecule in the interstellar medium cannot be explained by gas-phase chemistry only and its…

Solar and Stellar Astrophysics · Physics 2017-08-23 S. Ioppolo , H. M. Cuppen , C. Romanzin , E. F. van Dishoeck , H. Linnartz

The reaction between atomic oxygen and molecular hydrogen is an important one in astrochemistry as it regulates the abundance of the hydroxyl radical and serves to open the chemistry of oxygen in diverse astronomical environments. However,…

Astrophysics of Galaxies · Physics 2021-04-21 A. Veselinova , M. Agundez , J. R. Goicoechea , M. Menendez , A. Zanchet , E. Verdasco , P. G. Jambrina , F. J. Aoiz

It is very important to identify carrier molecules of astronomical interstellar infrared spectrum (IR) to understand chemical evolution step of polycyclic aromatic hydrocarbon (PAH) in the universe. In our previous study, it was suggested…

Astrophysics of Galaxies · Physics 2018-01-22 Norio Ota

CONTEXT: The attachment of free electrons to polycondensed aromatic ring molecules (PAHs) is studied for the variety of these molecules with different numbers of condensed rings and over a broad range of electron temperatures, using a…

Astrophysics of Galaxies · Physics 2015-06-05 F. Carelli , T. Grassi , F. A. Gianturco

Polycyclic aromatic hydrocarbons (PAHs) are believed to be ubiquitous in the interstellar medium. Yet, to date no specific PAH molecule has been identified. In this paper, a new observational avenue is suggested to detect individual PAHs,…

Astrophysics of Galaxies · Physics 2015-08-21 Yacine Ali-Haïmoud

Void induced coronene C23H12++ was suggested to be a possible carrier of the astronomically observed polycyclic aromatic hydrocarbon (PAH), which shows unique molecular structure with carbon two pentagons connected with five hexagons. Well…

Chemical Physics · Physics 2015-02-14 Norio Ota

The signatures of polycyclic aromatic hydrocarbons (PAHs) have been observed in protoplanetary discs, and their emission features obtained from spectral energy distributions (SED) have been used in the literature to characterise their size…

Earth and Planetary Astrophysics · Physics 2023-11-22 K. Lange , C. Dominik , A. G. G. M. Tielens

We performed mid-infrared spectroscopic observations of 18 local dusty elliptical galaxies by using the Infrared Spectrograph (IRS) on board Spitzer. We have significantly detected polycyclic aromatic hydrocarbon (PAH) features from 14 out…

Astrophysics · Physics 2009-11-13 H. Kaneda , T. Onaka , I. Sakon , T. Kitayama , Y. Okada , T. Suzuki

Molecules with an excess number of hydrogen-bonding partners play a crucial role in fundamental chemical processes, ranging from the anomalous diffusion in supercooled water to the transport of aqueous proton defects and the ordering of…

In this work, we study the photodissociation processes of small PAH clusters (e.g., pyrene clusters). The experiments are carried out using a quadrupole ion trap in combination with time-of-flight (QIT-TOF) mass spectrometry. The results…

Instrumentation and Methods for Astrophysics · Physics 2018-09-27 Junfeng Zhen , Tao Chen , Alexander G. G. M. Tielens

Recent experimental results about the formation of molecular hydrogen on astrophysically relevant surfaces under conditions close to those encountered in the interstellar medium are analyzed using rate equations. The parameters of the rate…

Astrophysics · Physics 2009-10-31 N. Katz , I. Furman , O. Biham , V. Pirronello , G. Vidali

The couplings $g_{\rho HH}$ of the $\rho$ meson with any hadron H are calculated in a holographic dual of QCD where the Regge trajectories for mesons are manifest. The resulting couplings grow linearly with the exciting number of H, thus…

High Energy Physics - Phenomenology · Physics 2008-11-26 Tao Huang , Fen Zuo

When hydrogen molecules collide with a surface, they can either scatter away from the surface or stick to the surface through a dissociation reaction which leaves two H atoms adsorbed on the surface. The relative probabilities of these two…

Chemical Physics · Physics 2024-10-03 H. Chadwick , G. Zhang , C. J. Baker , P. L. Smith , G. Alexandrowicz

Hydrogen recombination is one of the most important atomic processes in many astrophysical objects such as Type II supernova (SN~II) atmospheres, the high redshift universe during the cosmological recombination era, and H II regions in the…

Solar and Stellar Astrophysics · Physics 2015-05-18 Soma De , E. Baron , Peter H. Hauschildt

The paper presents evidence of a rather strong correlation of odd electrons in the singlet state of graphene. Due to the correlation, the chemical modification of graphene can be considered following a certain algorithmic computational…

Materials Science · Physics 2012-01-10 E. F. Sheka , N. A. Popova