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From first principles, the author gathers a few general rules that need to be abided by in the calculation of the internal partition functions (IPFs) of individual molecules. These rules are violated in many schemes in the literature where…

Plasma Physics · Physics 2015-06-11 Mofreh R. Zaghloul

Particle splitting methods are considered for the estimation of rare events. The probability of interest is that a Markov process first enters a set $B$ before another set $A$, and it is assumed that this probability satisfies a large…

Probability · Mathematics 2007-11-14 Thomas Dean , Paul Dupuis

The number partition problem is a well-known problem, which is one of 21 Karp's NP-complete problems \cite{karp}. The partition function is a boolean function that is equivalent to the number partition problem with number range restricted.…

Computational Complexity · Computer Science 2022-12-25 Chuyu Xiong

Recently, we developed and implemented the bond propagation algorithm for calculating the partition function and correlation functions of random bond Ising models in two dimensions. The algorithm is the fastest available for calculating…

Statistical Mechanics · Physics 2009-11-13 Y. L. Loh , E. W. Carlson , M. Y. J. Tan

Modeling spectral line profiles taking frequency redistribution effects into account is a notoriously challenging problem from the computational point of view, especially when polarization phenomena (atomic polarization and polarized…

Solar and Stellar Astrophysics · Physics 2021-01-04 A. Paganini , B. Hashemi , E. Alsina Ballester , L. Belluzzi

The partition function of the random energy model at inverse temperature $\beta$ is a sum of random exponentials $Z_N(\beta)=\sum_{k=1}^N \exp(\beta \sqrt{n} X_k)$, where $X_1,X_2,...$ are independent real standard normal random variables…

Probability · Mathematics 2014-02-11 Zakhar Kabluchko , Anton Klimovsky

Aims. In this work we rigorously show the shortcomings of various simplifications that are used to calculate the total internal partition function. These shortcomings can lead to errors of up to 40 percent or more in the estimated partition…

Chemical Physics · Physics 2016-11-16 Andrius Popovas , Uffe G. Jørgensen

Partition functions for non-interacting particles are known to be symmetric functions. It is shown that powerful group-theoretical techniques can be used not only to derive these relationships, but also to significantly simplify calculation…

Statistical Mechanics · Physics 2009-11-07 A. B. Balantekin

We study the partition function from random matrix theory using a well known connection to orthogonal polynomials, and a recently developed Riemann-Hilbert approach to the computation of detailed asymptotics for these orthogonal…

Mathematical Physics · Physics 2007-05-23 N. M. Ercolani , K. D. T-R McLaughlin

We present a numerical method to evaluate partition functions and associated correlation functions of inhomogeneous 2--D classical spin systems and 1--D quantum spin systems. The method is scalable and has a controlled error. We illustrate…

Other Condensed Matter · Physics 2009-11-11 V. Murg , F. Verstraete , J. I. Cirac

Partition functions of certain classes of "spin glass" models in statistical physics show strong connections to combinatorial graph invariants. Also known as homomorphism functions they allow for the representation of many such invariants,…

Computational Complexity · Computer Science 2010-04-08 Marc Thurley

We introduce a general technique to compute finite temperature electronic properties by a novel covariant formulation of the electronic partition function. By using a rigorous variational upper bound to the free energy we are led to the…

Strongly Correlated Electrons · Physics 2013-06-19 Guglielmo Mazzola , Andrea Zen , Sandro Sorella

The simulated tempering (ST) is an important method to deal with systems whose phase spaces are hard to sample ergodically. However, it uses accepting probabilities weights which often demand involving and time consuming calculations. Here…

Statistical Mechanics · Physics 2015-05-20 Carlos E. Fiore , M. G. E. da Luz

Probabilistic graphical models are a key tool in machine learning applications. Computing the partition function, i.e., normalizing constant, is a fundamental task of statistical inference but it is generally computationally intractable,…

Machine Learning · Statistics 2020-01-29 Sungsoo Ahn , Michael Chertkov , Adrian Weller , Jinwoo Shin

We study approximations of the partition function of dense graphical models. Partition functions of graphical models play a fundamental role is statistical physics, in statistics and in machine learning. Two of the main methods for…

Machine Learning · Computer Science 2018-02-21 Vishesh Jain , Frederic Koehler , Elchanan Mossel

The key problem of statistical physics standing over one hundred years is how to exactly calculate the partition function (or free energy) of many-body interaction systems, which severely hinders application of the theory for realistic…

Statistical Mechanics · Physics 2019-04-26 Bo-Yuan Ning , Le-Cheng Gong , Tsu-Chien Weng , Xi-Jing Ning

Partitioning a set of elements into an unknown number of mutually exclusive subsets is essential in many machine learning problems. However, assigning elements, such as samples in a dataset or neurons in a network layer, to an unknown and…

Machine Learning · Computer Science 2023-11-10 Thomas M. Sutter , Alain Ryser , Joram Liebeskind , Julia E. Vogt

Probabilistic inference is a fundamental task in modern machine learning. Recent advances in tensor network (TN) contraction algorithms have enabled the development of better exact inference methods. However, many common inference tasks in…

Machine Learning · Computer Science 2024-09-10 Martin Roa-Villescas , Xuanzhao Gao , Sander Stuijk , Henk Corporaal , Jin-Guo Liu

We study the problem of approximating the Ising model partition function with complex parameters on bounded degree graphs. We establish a deterministic polynomial-time approximation scheme for the partition function when the interactions…

Quantum Physics · Physics 2019-07-12 Ryan L. Mann , Michael J. Bremner

We present a method for evaluating the partition function in a varying external field. Specifically, we look at the case of a non-interacting, charged, massive scalar field at finite temperature with an associated chemical potential in the…

High Energy Physics - Theory · Physics 2009-11-10 J. J. Mckenzie-Smith , Wade Naylor