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We present a matrix-product state (MPS)-based quadratically convergent density-matrix renormalization group self-consistent-field (DMRG-SCF) approach. Following a proposal by Werner and Knowles (JCP 82, 5053, (1985)), our DMRG-SCF algorithm…

Chemical Physics · Physics 2017-08-14 Yingjin Ma , Stefan Knecht , Sebastian Keller , Markus Reiher

This work introduces various approaches to include connected three-body terms in unitary many-body theories, focusing a representative example on the driven similarity renormalization group (DSRG). Starting from the least approximate method…

Chemical Physics · Physics 2020-07-15 Chenyang Li , Francesco A. Evangelista

Shared-memory parallelization (SMP) strategies for density matrix renormalization group (DMRG) algorithms enable the treatment of complex systems in solid state physics. We present two different approaches by which parallelization of the…

Strongly Correlated Electrons · Physics 2009-11-10 G. Hager , E. Jeckelmann , H. Fehske , G. Wellein

We develop SOS-RILT-MP2, an efficient Gaussian-based periodic scaled opposite-spin second-order M{\o}ller-Plesset perturbation theory (SOS-MP2) algorithm that utilizes the resolution-of-the-identity approximation (RI) combined with the…

Chemical Physics · Physics 2025-03-27 Idan Haritan , Xiao Wang , Tamar Goldzak

We describe an approximation to the in-medium similarity renormalization group (IMSRG) method in which we include the effects of intermediate three-body operators arising within nested commutators. As an initial step, we present the…

Nuclear Theory · Physics 2025-01-09 B. C. He , S. R. Stroberg

The Density Matrix Renormalization Group (DMRG) algorithm is a powerful tool for solving eigenvalue problems to model quantum systems. DMRG relies on tensor contractions and dense linear algebra to compute properties of condensed matter…

Distributed, Parallel, and Cluster Computing · Computer Science 2021-01-26 Ryan Levy , Edgar Solomonik , Bryan K. Clark

A modified density matrix renormalization group (DMRG) algorithm is applied to the zigzag spin-1/2 chain with frustrated antiferromagnetic exchange $J_1$, $J_2$ between first and second neighbors. The modified algorithm yields accurate…

Strongly Correlated Electrons · Physics 2015-05-18 Manoranjan Kumar , Zoltan G. Soos , Diptiman Sen , S. Ramasesha

We employ the density matrix renormalization group (DMRG) and the wave function factorization method for the numerical solution of large scale nuclear structure problems. The DMRG exhibits an improved convergence for problems with realistic…

Nuclear Theory · Physics 2007-05-23 T. Papenbrock , D. J. Dean

Embedding techniques allow the efficient description of correlations within localized fragments of large molecular systems, while accounting for their environment at a lower level of theory. We introduce FragPT2: a novel embedding framework…

Chemical Physics · Physics 2025-01-15 Emiel Koridon , Souloke Sen , Lucas Visscher , Stefano Polla

We adapt White's density matrix renormalisation group (DMRG) to the direct study of critical phenomena. We use the DMRG to generate transformations in the space of coupling constants. We postulate that a study of density matrix eigenvalues…

Condensed Matter · Physics 2007-05-23 R. J. Bursill , F. Gode

A new density matrix renormalisation group (DMRG) approach is presented for quantum systems of two spatial dimensions. In particular, it is shown that it is possible to create a multi-chain-type 2D DMRG approach which utilises previously…

Strongly Correlated Electrons · Physics 2009-11-10 Damian J. J. Farnell

We present an algorithm and implementation of integral-direct, density-fitted Hartree-Fock (HF) and second-order M{\o}ller-Plesset perturbation theory (MP2) for periodic systems. The new code eliminates the formerly prohibitive storage…

Chemical Physics · Physics 2022-10-11 Sylvia J. Bintrim , Timothy C. Berkelbach , Hong-Zhou Ye

In this paper, we analyze the numerical aspects of the inherently multi-reference density matrix renormalization group (DMRG) calculations on top of the periodic Kohn-Sham density functional theory (DFT) using the complete active space…

Strongly Correlated Electrons · Physics 2020-06-09 Gergely Barcza , Viktor Ivády , Tibor Szilvási , Márton Vörös , Libor Veis , Ádám Gali , Örs Legeza

We present a generalized adaptive time-dependent density matrix renormalization group (DMRG) scheme, called the {\it double time window targeting} (DTWT) technique, which gives accurate results with nominal computational resources, within…

Strongly Correlated Electrons · Physics 2015-03-13 Tirthankar Dutta , S. Ramasesha

The functional-renormalization-group aided density-functional theory (FRG-DFT) is applied to the two-dimensional homogeneous electron gas (2DHEG). The correlation energy of the 2DHEG is derived as a function of the Wigner-Seitz radius $…

Strongly Correlated Electrons · Physics 2019-03-13 Takeru Yokota , Tomoya Naito

Second-order Moller-Plesset perturbation theory (MP2) provides accurate correlation energies for periodic systems but suffers from finite-size errors (FSEs) that have inverse volume scaling due to the Coulomb kernel singularity in…

Computational Physics · Physics 2026-05-14 Stephen Jon Quiton , Juan D. F. Pottecher , Martin Head-Gordon , Lin Lin

The density matrix renormalization group (DMRG) method introduced by White for the study of strongly interacting electron systems is reviewed; the method is variational and considers a system of localized electrons as the union of two…

Strongly Correlated Electrons · Physics 2009-10-31 G. Fano , F. Ortolani , L. Ziosi

We present an efficient stochastic algorithm for the recently introduced perturbative density matrix renormalization group (p-DMRG) method for large active spaces. The stochastic implementation bypasses the computational bottleneck involved…

Chemical Physics · Physics 2018-08-01 Sheng Guo , Zhendong Li , Garnet Kin-Lic Chan

In the Density Matrix Renormalization Group (DMRG) algorithm, Hamiltonian symmetries play an important role. Using symmetries, the matrix representation of the Hamiltonian can be blocked. Diagonalizing each matrix block is more efficient…

Strongly Correlated Electrons · Physics 2012-06-29 G. Alvarez

We develop a variant of the density matrix renormalization group (DMRG) algorithm for two-dimensional cylinders that uses a real space representation along the cylinder and a momentum space representation in the perpendicular direction. The…

Strongly Correlated Electrons · Physics 2016-04-25 Johannes Motruk , Michael P. Zaletel , Roger S. K. Mong , Frank Pollmann