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Recent experiments on electron scattering through molecular films have shown that chiral molecules can be efficient sources of polarized electrons even in the absence of heavy nuclei as source of a strong spin-orbit interaction. We show…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Ernesto Medina , Floralba López , Mark Ratner , Vladimiro Mujica

Topological photonics provides an important platform for the development of photonic devices with robust disorder-immune light transport and controllable helicity. Mixing photons with excitons (or polaritons) gives rise to nontrivial…

Sensing and discriminating between enantiomers of chiral molecules remains a significant challenge in the design of sensor platforms. In the case of chemoresistive sensors, where detection relies on changes in electrical response upon…

Quantum gases of doubly-polar molecules represent appealing frameworks for a variety of cross-disciplinary applications, encompassing quantum simulation and computation, controlled quantum chemistry and precision measurements. Through a…

We apply a time-dependent perturbation theory based on unitary transformations combined with averaging techniques, on molecular orientation dynamics by ultrashort pulses. We test the validity and the accuracy of this approach on LiCl…

Quantum Physics · Physics 2007-05-23 D. Sugny , A. Keller , O. Atabek , D. Daems , S. Guérin , H. R. Jauslin

This review is based on the talk in the conference of "Spectroscopic Studies on Molecular Chirality" held on Dec 20-21 2013. The objects of the present paper are to (1) derive the energy difference between Laevorotatory, or left-handed,…

High Energy Physics - Phenomenology · Physics 2014-04-02 Takeshi Fukuyama

The radiation of optically active (chiral) molecule placed near chiral nanoparticle is investigated. The optimal conditions for engineering of radiation of optically active (chiral) molecules with the help of chiral nanoparticles are…

Optics · Physics 2015-05-30 Vasily V. Klimov , Dmitry V. Guzatov , Martial Ducloy

We present two methods for efficient detection of chiral molecules based on sequences of single pulses and Raman pulse pairs. The chiral molecules are modelled by a closed-loop three-state system with different signs in one of the couplings…

Quantum Physics · Physics 2020-11-18 Boyan T. Torosov , Michael Drewsen , Nikolay V. Vitanov

A theoretical study of the rotational dynamics of a linear polar molecule in a two-color non-resonant cw laser field is presented. By systematically considering the interactions of this field with the electric dipole moment, polarizability…

Quantum Physics · Physics 2020-08-26 David Mellado-Alcedo , Niurka R. Quintero , Rosario González-Férez

Recently, there is growing interest in integrating alkali vapors with nanoscale photonic structures, such as nano-waveguides, resonators and nanoantennas. Nanoscale confinement of electromagnetic fields may introduce a longitudinal electric…

Optics · Physics 2021-02-10 Roy Zektzer , Eliran Talker , Yefim Barash , Noa Mazurski , Uriel Levy

Photoelectron angular distributions (PADs) of oriented polar molecules in response to different polarized lasers are systematically investigated. It is found that the PADs of polar CO molecules show three distinct styles excited by…

Chemical Physics · Physics 2013-03-05 Xiaosong Zhu , Qingbin Zhang , Weiyi Hong , Peixiang Lu , Zhizhan Xu

Precision searches for time-reversal symmetry violating interactions in polar molecules are extremely sensitive probes of high energy physics beyond the Standard Model. To extend the reach of these probes into the PeV regime, long coherence…

Atomic Physics · Physics 2017-10-03 Ivan Kozyryev , Nicholas R. Hutzler

We propose an alternative scenario for the generation of entanglement between rotational quantum states of two polar molecules. This entanglement arises from dipole-dipole interaction, and is controlled by a sequence of laser pulses…

Quantum Physics · Physics 2016-08-16 Eric Charron , Pérola Milman , Arne Keller , Osman Atabek

Detection of chiral molecules requires amplification of chirality to measurable levels. Typically, amplification mechanisms are considered at the microscopic scales of individual molecules and their aggregates. Here we demonstrate chirality…

Soft Condensed Matter · Physics 2015-07-28 Chenhui Peng , Oleg D. Lavrentovich

The second-order nonlinear optical coefficients associated with chirality differ in sign for the two mirror-image forms (enantiomers) of a chiral material. Structures comprised of alternating stacks of the enantiomers can therefore be used…

Chemical Physics · Physics 2019-05-16 Bertrand Busson , Martti Kauranen , Colin Nuckolls , Thomas Katz , André Persoons

We present a rigorous finite element method to calculate circular dichroism (CD) in various systems consisting of nanostructures and oriented chiral molecules with electric quadrupole transitions. The interaction between oriented molecule…

Optics · Physics 2017-12-27 Weixuan Zhang , Tong Wu , Rongyao Wang , Xiangdong Zhang

We optically trap freestanding single metallic chiral nanoparticles using a standing-wave optical tweezer. We also incorporate within the trap a polarimetric setup that allows to perform in situ chiral recognition of single enantiomers.…

Parity-violating differences in rotational constants of a chiral 5d transition metal complex, that was previously experimentally well-characterised by broad-band microwave spectroscopy, are predicted with a recently established efficient…

Chemical Physics · Physics 2023-05-09 Nityananda Sahu , Konstantin Gaul , Anke Wilm , Melanie Schnell , Robert Berger

Nanophotonic platforms in theory uniquely enable < femtomoles of chiral biological and pharmaceutical molecules to be detected, through the highly localised changes in the chiral asymmetries of the near-fields that they induce. However,…

Single fluorescent molecules, behaving as ideal electric dipole emitters, are powerful nanoscopic probes of complex optical fields. Here, this property is exploited to precisely map the polarization and vectorial structure of tightly…

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