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The accurate quantum chemical calculation of excited states is a challenging task, often requiring computationally demanding methods. When entire ground and excited potential energy surfaces (PESs) are desired, e.g., to predict the…

Chemical Physics · Physics 2025-03-26 Zeno Schätzle , P. Bernát Szabó , Alice Cuzzocrea , Frank Noé

We present a nucleon structure analysis including local isovector charges as well as twist-2 operator insertions. Computations are performed on CLS ensembles with $N_f=2+1$ Wilson fermions, covering four values of the lattice spacing and…

High Energy Physics - Lattice · Physics 2018-11-27 Konstantin Ottnad , Tim Harris , Harvey Meyer , Georg von Hippel , Jonas Wilhelm , Hartmut Wittig

We introduce the multistate iterative qubit coupled cluster (MS-iQCC) method, a quantum-inspired algorithm that runs efficiently on classical hardware and is designed to predict both ground and excited electronic states of molecules.…

Chemical Physics · Physics 2026-01-05 Robert A. Lang , Shashank G. Mehendale , Ilya G. Ryabinkin , Artur F. Izmaylov

We present results from a lattice QCD study of nucleon matrix elements at vanishing momentum transfer for local and twist-2 isovector operator insertions. Computations are performed on gauge ensembles with non-perturbatively improved…

We present an update of our analysis of statistical and systematic errors in the calculation of iso-vector scalar, axial and tensor charges of the nucleon. The calculations are done using $N_f=2+1+1$ flavor HISQ ensembles generated by the…

High Energy Physics - Lattice · Physics 2016-01-11 Rajan Gupta , Tanmoy Bhattacharya , Vincenzo Cirigliano , Huey-Wen Lin , Boram Yoon

We present a new approach to calculate excited states with the full configuration interaction quantum Monte Carlo (FCIQMC) method. The approach uses a Gram-Schmidt procedure, instantaneously applied to the stochastically evolving…

Computational Physics · Physics 2015-10-28 N. S. Blunt , Simon D. Smart , George H. Booth , Ali Alavi

The authors present a technique using variational Monte Carlo to solve for excited states of electronic systems. The technique is based on enforcing orthogonality to lower energy states, which results in a simple variational principle for…

Chemical Physics · Physics 2021-10-15 Shivesh Pathak , Brian Busemeyer , João N. B. Rodrigues , Lucas K. Wagner

We combine recent advances in excited state variational principles, fast multi-Slater Jastrow methods, and selective configuration interaction to create multi-Slater Jastrow wave function approximations that are optimized for individual…

Strongly Correlated Electrons · Physics 2019-06-19 Sergio D. Pineda Flores , Eric Neuscamman

The essence of atomic structure theory, quantum chemistry, and computational materials science is solving the multi-electron stationary Schr\"odinger equation. The Quantum Monte Carlo-based neural network wave function method has surpassed…

Atomic Physics · Physics 2023-12-27 JinDe Liu , Chenglong Qin , Xi He , Gang Jiang

Determining quantum excited states is crucial across physics and chemistry but presents significant challenges for variational methods, primarily due to the need to enforce orthogonality to lower-energy states, often requiring…

Quantum Physics · Physics 2025-05-01 Shi-Xin Zhang , Lei Wang

The calculation of excited state energies of electronic structure Hamiltonians has many important applications, such as the calculation of optical spectra and reaction rates. While low-depth quantum algorithms, such as the variational…

Quantum Physics · Physics 2019-07-03 Oscar Higgott , Daochen Wang , Stephen Brierley

This work presents a series of highly-accurate excited-state properties obtained using high-order coupled-cluster (CC) calculations performed with a series of diffuse containing basis sets, as well as extensive comparisons with experimental…

Chemical Physics · Physics 2021-06-14 Amara Chrayteh , Aymeric Blondel , Pierre-François Loos , Denis Jacquemin

The excitation spectra in the deformed nucleus 158Gd have been studied with high energy resolution by means of the (p,t) reaction using the Q3D spectrograph facility at the Munich Tandem accelerator. The angular distributions of tritons…

The RQCD collaboration proposed a projection method to remove the excited state contamination in lattice OCD calculations of nuclear form factors. The effectiveness of this method in removing the two-particle nucleon-pion-state…

High Energy Physics - Lattice · Physics 2020-02-28 Oliver Bar

We discuss a robust projection method for the extraction of excited-state masses of the nucleon from a matrix of correlation functions. To illustrate the algorithm in practice, we present results for the positive parity excited states of…

High Energy Physics - Lattice · Physics 2010-04-28 M. S. Mahbub , Alan Ò Cais , Waseem Kamleh , B. G. Lasscock , Derek B. Leinweber , Anthony G. Williams

Obtaining accurate ground and low-lying excited states of electronic systems is crucial in a multitude of important applications. One ab initio method for solving the Schr\"odinger equation that scales favorably for large systems is…

Chemical Physics · Physics 2023-01-19 Mike Entwistle , Zeno Schätzle , Paolo A. Erdman , Jan Hermann , Frank Noé

Monte Carlo techniques have been widely employed in statistical physics as well as in quantum theory in the Lagrangian formulation. However, in the conventional approach, it is extremely difficult to compute the excited states. Here we…

Quantum Physics · Physics 2009-11-07 X. Q. Luo , H. Jirari , H. Kroger , K. Moriarty

Two state-of-the-art computational approaches: quantum Monte Carlo (QMC), based on accurate total energies, and GW with exciton effects (GW-BSE), based on perturbation theory are employed to calculate ionization potentials, electron…

Materials Science · Physics 2009-10-31 Jeffrey C. Grossman , Michael Rohlfing , Lubos Mitas , Steven G. Louie , Marvin L. Cohen

We discuss the quantum mechanics of coalescence of quark-antiquark pairs into mesons using a non-relativistic quark model. We derive the coalescence probabilities assuming a harmonic oscillator potential and generic Gaussian wave packet…

High Energy Physics - Phenomenology · Physics 2025-12-30 R. J. Fries , P. Virupapuram , J. Purcell , H. Anconetani , W. Lippincott , S. Robicheaux , M. Kordell , C. M. Ko

The description of excited state dynamics in multichromophoric systems constitutes both a theoretical and experimental challenge in modern physical chemistry. An experimental protocol which can systematically characterize both coherent and…

Quantum Physics · Physics 2011-10-31 Joel Yuen-Zhou , Jacob J. Krich , Masoud Mohseni , Alán Aspuru-Guzik