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Pyroelectric current and magnetoelectric coupling measurements on polycrystalline samples of the quadruple perovskite (LaMn$_{3}$)Mn$_{4}$O$_{12}$ give evidence of ferroelectricity driven by the antiferromagnetic ordering of the $B$-site…

Ferroelectric (FE) metals have been attracting attention as they possess both metallicity and ferroelectricity, the two seemingly incompatible physical properties. An important problem for both fundamental research and potential…

Materials Science · Physics 2022-03-22 Sheng Xu , Yanni Gu , Chuanbo Zheng , Xiao Shen

2D Ferroelectricity with switchable electric polarization has drawn widespread attention in condensed matter physics due to its crucial applications in non-volatile memory and ferroelectric spin devices. Despite recent progress in 2D…

Materials Science · Physics 2024-01-17 Jiajun Zhu , Botao Fu , Heyun Zhao , Wanbiao Hu

Single crystal synthesis, structure, electric polarization and heat capacity measurements on hexagonal InMnO3 show that this small R ion in the RMnO3 series is ferroelectric (space group P63cm). Structural analysis of this system reveals a…

Materials Science · Physics 2015-06-15 T. Yu , P. Gao , T. Wu , T. A. Tyson , R. Lalancette

We present a detailed study of the structural, electronic, magnetic and ferroelectric properties of prototypical \textit{proper} and \textit{improper} multiferroic (MF) systems such as BiFeO$_{3}$ and orthorhombic HoMnO$_{3}$, respectively,…

Materials Science · Physics 2017-03-15 A. Stroppa , S. Picozzi

The combination of antiferroelectricity (AFE) and ferromagnetism (FM) in one structure would allow the development of new type of multiferroic candidates, which be applicable not only in magnetoelectric memories but also in novel energy…

Materials Science · Physics 2022-10-05 Cong-Cong Duan , Guo-Long Tan

Realization of ferromagnetic ferroelectricity, combining two ferroic orders in a single phase, is the longstanding problem of great practical importance. One of the difficulties is that ferromagnetism alone cannot break inversion symmetry…

Materials Science · Physics 2026-04-22 I. V. Solovyev

First-principles calculations were performed to investigate the ferroelectric properties of barium titanate and bismuth ferrite, as well as phonon dispersion of BaTiO3, using density functional theory and density functional perturbation…

Materials Science · Physics 2014-12-08 Hong-Jian Feng

Magnetic random access memory schemes employing magnetoelectric coupling to write binary information promise outstanding energy efficiency. We propose and demonstrate a purely antiferromagnetic magnetoelectric random access memory…

The coexistence of metallicity and ferroelectricity in ferroelectric (FE) metals defies conventional wisdom and enables novel functionalities in electronic and optoelectronic systems. However, intrinsic FE metals remain extremely rare and…

Materials Science · Physics 2025-07-11 Guangrong Tan , Jinyu Zou , Gang Xu

We use a combination of symmetry arguments and first-principles calculations to explore the connection between structural distortions and ferroelectricity in the perovskite family of materials. We explain the role of octahedral rotations in…

Materials Science · Physics 2013-08-01 Nicole A. Benedek , Craig J. Fennie

The strategic design of ferroelectric materials exhibiting robust and reversible spontaneous polarization remains a pivotal challenge in functional materials research. Here, A-site cation disorder engineering is employed in the n = 2…

Metamaterials are artificial periodic structures which represent effective homogeneous medium for electromagnetic fields. Here I show that there exists an important class of such composite systems, metaferroelectrics. They are properly…

Other Condensed Matter · Physics 2008-06-09 Lasha Tkeshelashvili

Emergent functionalities of structural and topological defects in ferroelectric materials underpin an extremely broad spectrum of applications ranging from domain wall electronics to high dielectric and electromechanical responses. Many of…

All known proper ferroelectrics are unable to polarize normal to a surface or interface if the resulting depolarization field is unscreened, but there is no fundamental principle that enforces this behavior. In this work, we introduce…

Materials Science · Physics 2014-04-01 Kevin F. Garrity , Karin M. Rabe , David Vanderbilt

Ferroelectric domain walls are attracting broad attention as atomic-scale switches, diodes and mobile wires for next-generation nanoelectronics. Charged domain walls in improper ferroelectrics are particularly interesting as they offer…

We have studied the structural phase transition of multiferroic YMnO$_3$ from first principles. Using group-theoretical analysis and first-principles density functional calculations of the total energy and phonons, we perform a systematic…

Materials Science · Physics 2009-11-11 Craig J. Fennie , Karin M. Rabe

Ferroelasticity describes a phenomenon in which a material exhibits two or more equally stable orientation variants and can be switched from one form to another under an applied stress. Recent works have demonstrated that two-dimensional…

Materials Science · Physics 2024-09-11 Devesh R. Kripalani , Qiye Guan , Hejin Yan , Yongqing Cai , Kun Zhou

Originating from a broken spatial inversion symmetry, ferroelectricity is a functionality of materials with an electric dipole that can be switched by external electric fields. Spontaneous polarization is a crucial ferroelectric property,…

Materials Science · Physics 2017-08-03 Yubo Zhang , Jianwei Sun , John P. Perdew , Xifan Wu

We report the development of a combined machine-learning and high-throughput density functional theory (DFT) framework to accelerate the search for new ferroelectric materials. The framework can predict potential ferroelectric compounds…