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Descriptions of molecular systems usually refer to two distinct theoretical frameworks. On the one hand the quantum pure state, i.e. the wavefunction, of an isolated system which is determined to calculate molecular properties and to…

Statistical Mechanics · Physics 2011-03-17 Barbara Fresch , Giorgio J. Moro

It is generally believed that, in the thermodynamic limit, the microcanonical description as a function of energy coincides with the canonical description as a function of temperature. However, various examples of systems for which the…

Statistical Mechanics · Physics 2016-01-13 Tiziano Squartini , Joey de Mol , Frank den Hollander , Diego Garlaschelli

For the case of reduction onto the non-zero momentum level, in the problem of the path integral quantization of a scalar particle motion on a smooth compact Riemannian manifold with the given free isometric action of the compact semisimle…

Mathematical Physics · Physics 2009-12-18 S. N. Storchak

We study the heat statistics of a quantum Brownian motion described by the Caldeira-Leggett model. By using the path integral approach, we introduce a novel concept of the quantum heat functional along every pair of Feynman paths. This…

Statistical Mechanics · Physics 2018-07-18 Ken Funo , H. T. Quan

For studying the thermodynamic properties of systems using statistical mechanics we propose an ensemble that lies in between the familiar canonical and microcanonical ensembles. From a comparative study of these ensembles we conclude that…

Statistical Mechanics · Physics 2007-05-23 R. P. Venkataraman

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble, whereas canonical ones fail in the most interesting, mostly inhomogeneous, situations like phase separations or away from the thermodynamic…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

The microcanonical ensemble has long been a starting point for the development of thermodynamics from statistical mechanics. However, this approach presents two problems. First, it predicts that the entropy is only defined on a discrete set…

Statistical Mechanics · Physics 2017-06-07 William Griffin , Michael Matty , Robert H. Swendsen

Recent progress in manipulating atomic and condensed matter systems has instigated a surge of interest in non-equilibrium physics, including many-body dynamics of trapped ultracold atoms and ions, near-field radiative heat transfer, and…

Quantum Physics · Physics 2016-09-05 F. Intravaia , R. O. Behunin , C. Henkel , K. Busch , D. A. R. Dalvit

Gauge fixing procedure in the path integral for the microcanonical statistical sum in quantum cosmology is considered in a special class of gauge conditions free from residual gauge ambiguities. Relevant functional determinants, path…

High Energy Physics - Theory · Physics 2015-01-16 Dmitry Nesterov , Andrei Barvinsky

Quantum criticality provides an important route to revealing universal non-equilibrium behaviour. A canonical example of a quantum critical point is the Bose-Hubbard model, which we study under the application of an electric field. A…

Strongly Correlated Electrons · Physics 2015-06-18 A. M. Berridge , A. G. Green

Nonequilibrium thermodynamics has shown its applicability in a wide variety of different situations pertaining to fields such as physics, chemistry, biology, and engineering. As successful as it is, however, its current formulation…

Condensed Matter · Physics 2009-11-07 J. M. G. Vilar , J. M. Rubi

For classical nonequilibrium systems, the separation of the total entropy production into the adiabatic and nonadiabatic contributions is useful for understanding irreversibility in nonequilibrium thermodynamics. In this article, we…

Statistical Mechanics · Physics 2015-06-16 Jordan M. Horowitz , Juan M. R. Parrondo

A quantum microcanonical postulate is proposed as a basis for the equilibrium properties of small quantum systems. Expressions for the corresponding density of states are derived, and are used to establish the existence of phase transitions…

Quantum Physics · Physics 2007-06-13 Dorje C. Brody , Daniel W. Hook , Lane P. Hughston

We investigate the correspondence between a non-equilibrium ensemble defined via the distribution of phase-space paths of a Hamiltonian system, and a system driven into a steady-state by non-equilibrium boundary conditions. To discover…

Statistical Mechanics · Physics 2014-01-27 Milos Knezevic , R. M. L. Evans

A local interpretation of quantum mechanics is presented. Its main ingredients are: first, a label attached to one of the virtual paths in the path integral formalism, determining the output for measurement of position or momentum; second,…

Quantum Physics · Physics 2015-09-03 Carlos Lopez

A new microcanonical equilibrium state is introduced for quantum systems with finite-dimensional state spaces. Equilibrium is characterised by a uniform distribution on a level surface of the expectation value of the Hamiltonian. The…

Quantum Physics · Physics 2007-10-25 Dorje C. Brody , Daniel W. Hook , Lane P. Hughston

A path integral method, combined with atomistic spin dynamics simulations, has been developed to calculate thermal quantum expectation values using a classical approach. In this study, we show how to treat Hamiltonians with non-linear…

Quantum Physics · Physics 2024-08-12 Thomas Nussle , Pascal Thibaudeau , Stam Nicolis

In this Thesis by publication, we cover both phenomenological and theoretical approaches to the study of inflation: from model-independent parametrizations to modifications of gravity. In a review style, we provide a short introduction to…

General Relativity and Quantum Cosmology · Physics 2019-06-25 Héctor Ramírez

Non-equilibrium thermodynamics can provide strong advantages when compared to more standard equilibrium situations. Here, we present a general framework to study its application to concrete problems, which is valid also beyond the…

Quantum Physics · Physics 2023-03-16 Qiongyuan Wu , Matteo Carlesso

It has recently been shown, by application of statistical mechanical methods to determine the canonical ensemble governing the equilibrium distribution of operator initial values, that complex quantum field theory can emerge as a…

High Energy Physics - Theory · Physics 2009-10-30 Stephen L. Adler , L. P. Horwitz