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Related papers: Current issues in finite-$T$ density-functional th…

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Density functional theory is the workhorse of modern electronic structure calculations, with wide-ranging applications in chemistry, physics, materials science, and machine learning. At its heart lies the exchange-correlation functional, a…

Chemical Physics · Physics 2026-02-20 Fabien Tran , Susi Lehtola , Stefano Pittalis , Miguel A. L. Marques

The density linear response function for an inhomogeneous system of electrons in equilibrium with an array of fixed ions is considered. Two routes to its evaluation for extreme conditions (e.g., warm dense matter) are considered. The first…

Statistical Mechanics · Physics 2018-09-12 James Dufty , Kai Luo , S. B. Trickey

In Cerium-based heavy electron materials, the 4f electron's magnetic moments bind to the itinerant quasiparticles to form composite heavy quasiparticles at low temperature. The volume of the Fermi surfacein the Brillouin zone incorporates…

Strongly Correlated Electrons · Physics 2013-09-03 Hong Chul Choi , B. I. Min , J. H. Shim , K. Haule , G. Kotliar

The controversy with respect to the role of electron-electron collisions in the dynamic conductivity of dense plasmas is resolved. In particular, the dc conductivity is analyzed in the low-density, non-degenerate limit where the Spitzer…

Plasma Physics · Physics 2015-01-27 H. Reinholz , G. Röpke , S. Rosmej , R. Redmer

The dynamic electron-ion collisions play an important rolein determining the static and transport properties of warmdense matter (WDM). Electron force field (eFF) method is applied to study the ionic transport properties of warm…

Computational Physics · Physics 2021-01-15 Yunpeng Yao , Qiyu Zeng , Ke Chen , Dongdong Kang , Yong Hou , Qian Ma , Jiayu Dai

It has long been postulated that within density-functional theory (DFT) the total energy of a finite electronic system is convex with respect to electron count, so that 2 E_v[N_0] <= E_v[N_0 - 1] + E_v[N_0 + 1]. Using the…

Chemical Physics · Physics 2023-12-25 Andrew C. Burgess , Edward Linscott , David D. O'Regan

We explore the production of thermal dark matter (DM) candidates (WIMPs, SIMPs, ELDERs and Cannibals) during cosmic reheating. Assuming a general parametrization for the scaling of the inflaton energy density and the standard model (SM)…

High Energy Physics - Phenomenology · Physics 2024-08-28 Nicolás Bernal , Kuldeep Deka , Marta Losada

Density functional theory (DFT) has greatly expanded our ability to affordably compute and understand electronic ground states, by replacing intractable {\em ab initio} calculations by models based on paradigmatic physics from high- and…

Chemical Physics · Physics 2023-03-29 Tim Gould , Derk P. Kooi , Paola Gori-Giorgi , Stefano Pittalis

We present the extension of Frozen Density Embedding (FDE) theory to real-time Time Dependent Density Functional Theory (rt-TDDFT). FDE a is DFT-in-DFT embedding method that allows to partition a larger Kohn-Sham system into a set of…

Chemical Physics · Physics 2015-06-23 Alisa Krishtal , Davide Ceresoli , Michele Pavanello

The celebrated Wiedemann-Franz (WF) law is believed to be robust in metals as long as interactions between electrons preserve their fermion-quasiparticle character. We study thermal transport and the fate of the WF law close to a continuous…

Strongly Correlated Electrons · Physics 2017-10-11 P. Haldar , M. S. Laad , S. R. Hassan

One of the greatest challenges when designing new technologies that make use of non-trivial quantum materials is the difficulty associated with predicting material-specific properties, such as critical temperature, gap parameter, etc. There…

Superconductivity · Physics 2025-03-24 Adrian D. Scheppe , Michael V. Pak

Many-electron systems at substantial finite temperatures and densities present a major challenge to density functional theory. Very little is known about the free-energy behavior over the temperature range of interest, for example, in the…

Materials Science · Physics 2012-01-25 Travis Sjostrom , Frank E. Harris , S. B. Trickey

The energy band structures caused by self-energy shifting that results in bound energy levels broadening and merging in warm dense aluminum and beryllium are observed. An energy band theory for warm dense matter (WDM) is proposed and a new…

Plasma Physics · Physics 2018-12-21 Chang Gao , Shen Zhang , X. T. He , Wei Kang , Ping Zhang , Mohan Chen , Cong Wang

A novel method to determine the density and temperature of a system based on quantum Fermionic fluctuations is generalized to the limit where the reached temperature T is large compared to the Fermi energy {\epsilon}f . Quadrupole and…

Nuclear Theory · Physics 2015-06-03 Hua Zheng , Aldo Bonasera

We assess the performance of nonempirical, truly nonlocal and semi-local functionals with regard to structural and thermal properties of $3d$, $4d$, and $5d$ non-magnetic transition metals. We focus on constraint-based functionals and…

Materials Science · Physics 2021-01-14 Leili Gharaee , Paul Erhart , Per Hyldgaard

There is growing interest in warm dense matter (WDM) -- an exotic state on the border between condensed matter and plasmas. Due to the simultaneous importance of quantum and correlation effects WDM is complicated to treat theoretically. A…

Computational Physics · Physics 2020-10-07 Paul Hamann , Tobias Dornheim , Jan Vorberger , Zhandos A. Moldabekov , Michael Bonitz

We present a new model of electron transport in warm and hot dense plasmas which combines the quantum Landau-Fokker-Planck equation with the concept of mean-force scattering. We obtain electrical and thermal conductivities across several…

Plasma Physics · Physics 2020-05-27 Nathaniel R. Shaffer , Charles E. Starrett

We present an accurate and efficient real-space formulation of the Hellmann-Feynman stress tensor for $\mathcal{O}(N)$ Kohn-Sham density functional theory (DFT). While applicable at any temperature, the formulation is most efficient at high…

Computational Physics · Physics 2020-08-26 Abhiraj Sharma , Sebastien Hamel , Mandy Bethkenhagen , John E. Pask , Phanish Suryanarayana

Million-atom quantum simulations are in principle feasible with Orbital-Free Density Functional Theory (OF-DFT) because the algorithms only require simple functional minimizations with respect to the electron density function. In this…

Materials Science · Physics 2019-07-17 Wenhui Mi , Michele Pavanello

The formalism of density functional theory (DFT) can be easily extended to the time dependent case (TDDFT). However, while in the static case the theory is well established and is expected to be, at least in principle, an exact approach for…

Condensed Matter · Physics 2007-05-23 Sandro Stringari