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Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble, whereas canonical ones fail in the most interesting, mostly inhomogeneous, situations like phase separations or away from the thermodynamic…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

A simple and effective approach to thermodynamics is suggested, which solves the major difficulties in the traditional presentation of the subject. The internal energy is introduced from the behavior of deformable bodies, whereas the…

General Physics · Physics 2012-03-13 Rodrigo de Abreu , Vasco Guerra

The classical thermodynamic laws fail to capture the behavior of systems with energy Hamiltonian which is an explicit function of the temperature. Such Hamiltonian arises, for example, in modeling information processing systems, like…

Statistical Mechanics · Physics 2009-11-13 Ori Shental , Ido Kanter

The first part of this paper is a condensed synthesis of the matter presented in several previous ones. It begins with an argumentation showing that the first and second laws of thermodynamics are incompatible with one another if they are…

General Physics · Physics 2010-02-21 Jean-Louis Tane

A generalization of the thermodynamic uncertainty relations is proposed. It is done by introducing of an additional term proportional to the interior energy into the standard thermodynamic uncertainty relation that leads to existence of the…

General Relativity and Quantum Cosmology · Physics 2007-05-23 A. E. Shalyt-Margolin , A. Ya. Tregubovich

The second law of thermodynamics constitutes a fundamental principle of physics, precluding the existence of perpetual motion machines and providing a natural definition of the arrow of time. Its scope extends across virtually all areas of…

General Relativity and Quantum Cosmology · Physics 2025-10-21 Alejandro Corichi , Omar Gallegos

Second law of thermodynamics can be apparently violated for systems whose dynamics depends on acquired information by measurement. However, when one consider measurement and erasure process together along with the system it saves the second…

Statistical Mechanics · Physics 2016-11-08 Shubhashis Rana , A. M. Jayannavar

In this note, we present two general classes of integral inequalities motivated by their applications to infinite dimensional systems. The inequalities possess general structures in terms of weight functions and lower quadratic bounds. Many…

Optimization and Control · Mathematics 2019-09-17 Qian Feng , Sing Kiong Nguang

Validity of local equilibrium has been questioned for non-equilibrium systems which are characterized by delayed response. In particular, for systems with non-zero thermodynamic inertia, the assumption of local equilibrium leads to negative…

Statistical Mechanics · Physics 2015-07-29 K. S. Glavatskiy

Claims of exceptions to the second law of thermodynamics are generally met with extreme skepticism that is quite reasonable given the great confidence placed in the second law. But what specifically is the basis for that confidence? The…

Statistical Mechanics · Physics 2009-11-07 Todd L. Duncan

The unification of relativity and thermodynamics has been a subject of considerable debate over the last 100 years. The reasons for this are twofold: (i) Thermodynamic variables are nonlocal quantities and, thus, single out a preferred…

Statistical Mechanics · Physics 2009-12-18 Jörn Dunkel , Peter Hänggi , Stefan Hilbert

In classical phenomenological thermodynamics the first and second laws can be regarded as independent statements. Statistical mechanics provides a microscopic substratum that explains thermodynamics in probabilistic terms via a microstate…

Statistical Mechanics · Physics 2007-05-23 A. Plastino , E. M. F. Curado

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

Statistical Mechanics · Physics 2015-03-09 J-P. Badiali , A. El Kaabouchi

A multiscale theory of interacting continuum mechanics and thermodynamics of mixtures of fluids, electrodynamics, polarization and magnetization is proposed. The mechanical (reversible) part of the theory is constructed in a purely…

Classical Physics · Physics 2020-08-26 Petr Vagner , Michal Pavelka , Ogul Esen

We analyze, from the thermodynamical point of view, mechanical systems in which there is production of mechanical energy due to an internal source of energy, and compare that analysis with the similar one for the "symmetric" motion which…

Classical Physics · Physics 2014-03-17 Julio Güémez , Manuel Fiolhais

The second law of thermodynamics is a fundamental law of Nature. It is almost universally associated with the Clausius inequality that lower bounds a change in entropy by the ratio of supplied heat and temperature. However, this result…

Quantum Gases · Physics 2020-05-11 Daniel Mayer , Eric Lutz , Artur Widera

We consider thermodynamic properties, e.g. specific heat, magnetic susceptibility, of alternating Heisenberg spin chains. Due to a hidden Ising symmetry these chains can be decomposed into a set of finite chain fragments. The problem of…

Strongly Correlated Electrons · Physics 2009-10-30 H. Niggemann , G. Uimin , J. Zittartz

In textbooks on statistical mechanics, one finds often arguments based on classical mechanics, phase space and ergodicity in order to justify the second law of thermodynamics. However, the basic equations of motion of classical mechanics…

Statistical Mechanics · Physics 2014-08-28 Barbara Drossel

Jensen's Inequality (JIEQ) has proved to be a major tool to prove the consistency of various fluctuation theorems with the second law in microscopic thermodynamics. We show that the situation is far from clear and the reliance on the JIE…

Statistical Mechanics · Physics 2020-08-26 P. D. Gujrati

We obtain generalizations of the Kelvin-Planck, Clausius, and Carnot statements of the second law of thermodynamics, for situations involving information processing. To this end, we consider an information reservoir (representing, e.g. a…

Statistical Mechanics · Physics 2013-10-21 Sebastian Deffner , Christopher Jarzynski
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