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Recently developed instrumentation at the University of Washington has allowed for nonresonant x-ray emission spectra (XES) to be measured in a laboratory-setting with an inexpensive, easily operated system. We present a critical evaluation…

Materials Science · Physics 2016-06-22 Devon R. Mortensen , Gerald T. Seidler , Alexander S. Ditter , Pieter Glatzel

We present a method for computing optical absorption spectra by means of a Bethe-Salpeter equation approach, which is based on a conserving linear response calculation for electron-hole coherences in the presence of an external…

Materials Science · Physics 2010-12-21 George Pal , Yaroslav Pavlyukh , Wolfgang Hübner , Hans Christian Schneider

Recent studies of core-level X-ray photoelectron spectroscopy (XPS) spectra of silicene on ZrB$_2$(0001) were found to be inconsistent with the density of states (DOS) of a planar-like structure that has been proposed as the ground state by…

The optical and electronic properties of the {\alpha}-SiTe, {\beta}-SiTe, and RX-SiTe_2 are investigated. A detailed analysis of electronic properties is done using standard density functional theory (DFT) and hybrid functional (HSE06)…

Materials Science · Physics 2021-06-30 Romakanta Bhattarai , Xiao Shen

The Bethe-Salpeter formalism represents the most accurate method available nowadays for computing neutral excitation energies and optical spectra of crystalline systems from first principles. Bethe-Salpeter calculations yield very good…

Materials Science · Physics 2016-05-04 Yannick Gillet , Matteo Giantomassi , Xavier Gonze

Protein electrostatics tune excitation energies in the Photosystem II reaction center (PSII-RC), yet a fully quantum-mechanical many-body description of how the surrounding protein environment renormalizes excitons has remained…

Chemical Physics · Physics 2026-02-25 Tucker Allen , Barry Y. Li , Nadine C. Bradbury , Daniel Neuhauser

This work is an extension of the work in \cite{bhatnagar18} to ground and excited states of $0^{++}, 0^{-+}$, and $1^{--}$ of heavy-light ($c\overline{u}, c\overline{s}, b\overline{u}, b\overline{s}$, and $b\overline{c}$) quarkonia in the…

High Energy Physics - Phenomenology · Physics 2019-10-02 Eshete Gebrehana , Shashank Bhatnagar , Hluf Negash

Absorption spectra, exciton energy levels and wave functions for solid Ne and Ar have been calculated from first principles using many-body techniques. Electronic band structures of Ne and Ar were calculated using the GW approximation.…

Other Condensed Matter · Physics 2009-11-10 S. Galamic-Mulaomerovic , C. H. Patterson

Photon-induced electronic excitations are ubiquitously observed in organic chromophore. In this context, we present a simple, alternative time-independent DFT procedure, for computation of single-particle excitation energies, in particular,…

Chemical Physics · Physics 2021-03-01 Abhisek Ghosal , Tarun Gupta , Kishalay Mahato , Amlan K. Roy

We present a first-principles method for relaxing a material's geometry in an optically excited state. This method, based on the Bethe-Salpeter equation, consists of solving coupled equations for exciton wavefunctions and atomic…

Computational Physics · Physics 2022-12-29 Mao Yang , Claudia Draxl

The last ten years have witnessed fast spreading of massively parallel computing clusters, from leading supercomputing facilities down to the average university computing center. Many companies in the private sector have undergone a similar…

Computational Engineering, Finance, and Science · Computer Science 2021-07-28 Xiao Zhang , Sebastian Achilles , Jan Winkelmann , Roland Haas , André Schleife , Edoardo Di Napoli

X-ray absorption spectroscopy yields direct access to the electronic and geometric structure of hybrid inorganic-organic interfaces formed upon adsorption of complex molecules at metal surfaces. The unambiguous interpretation of…

Chemical Physics · Physics 2017-06-19 Katharina Diller , Reinhard J. Maurer , Moritz Müller , Karsten Reuter

First principles calculations based on many-electron perturbation theory methods, such as the \textit{ab initio} GW and GW plus Bethe-Salpeter equation (GW-BSE) approach, are reliable ways to predict quasiparticle and optical properties of…

Materials Science · Physics 2017-01-11 Felipe H. da Jornada , Diana Y. Qiu , Steven G. Louie

We introduce an active-space embedding framework for core-level spectroscopies that connects localized atomic multiplets to continuum resonances within a plane-wave DFT/PAW description. The approach is complementary to widely used…

Strongly Correlated Electrons · Physics 2026-04-17 Alessandro Mirone , Mauro Rovezzi , Christoph Sahle , Alessandro Longo

Resonant X-ray scattering (RXS) is a spectroscopy where both the power of site selective diffraction and the power of local absorption spectroscopy regarding atomic species are combined. By virtue of the dependence on the core level state…

Materials Science · Physics 2007-11-12 Yves Joly , Elena S. Nazarenko , José-Emilio Lorenzo , Sergio Di Matteo , Calogero R. Natoli

We systematically investigate the underlying relations among different levels of approximation for simulating electronic de-excitations, with a focus on modeling X-ray emission spectroscopy (XES). Using Fermi's golden rule and explicit…

Materials Science · Physics 2022-08-31 Subhayan Roychoudhury , Leonardo A. Cunha , Martin Head-Gordon , David Prendergast

We present a modification of the $\Delta$SCF method of calculating energies of excited states, in order to make it applicable to resonance calculations of molecules adsorbed on metal surfaces, where the molecular orbitals are highly…

Materials Science · Physics 2009-03-06 Jeppe Gavnholt , Thomas Olsen , Mads Engelund , Jakob Schiøtz

To fully capitalize on the potential and versatility of resonant inelastic x-ray scattering (RIXS), it is essential to develop the capability to interpret different RIXS contributions through calculations, including the dependence on…

An ab initio approach to the calculation of excitonic effects in the optical absorption spectra of semiconductors and insulators is formulated. It starts from a quasiparticle bandstructure calculation and is based on the relevant…

Condensed Matter · Physics 2016-08-31 Stefan Albrecht , Lucia Reining , Rodolfo Del Sole , Giovanni Onida

This paper considers an intelligent reflecting sur-face (IRS)-aided simultaneous wireless information and power transfer (SWIPT) network, where multiple users decode data and harvest energy from the transmitted signal of a transmit-ter. The…

Information Theory · Computer Science 2021-03-24 Shayan Zargari , Ata Khalili , Qingqing Wu , Mohammad Robat Mili , Derrick Wing Kwan Ng
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