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We calculate thermal transport in the Falicov-Kimball model on an infinite-coordination-number Bethe lattice. We perform numerical calculations of the thermoelectric characteristics and concentrate on finding materials parameters for which…

Strongly Correlated Electrons · Physics 2009-11-10 A. V. Joura , D. O. Demchenko , J. K. Freericks

Half-Heusler (HH) compounds have shown high Figure of merits up to 1.5. The key to these high thermoelectric efficiencies is an intrinsic phase separation, which occurs in multicomponent Half-Heusler compounds and leads to an significantly…

Materials Science · Physics 2015-02-09 Julia Krez , Benjamin Balke , Claudia Felser , Wilfried Hermes , Markus Schwind

Half-Heusler alloys such as the (Zr,Hf)NiSn intermetallic compounds are important thermoelectric materials for converting waste heat into electricity. Reduced electrical resistivity at the hot interface between the half-Heusler material and…

Materials Science · Physics 2018-12-19 Catalin D. Spataru , Yuping He , François Léonard

The electronic and phonon transport properties of quaternary tetradymite BiSbSeTe2 are investigated using first-principles approach and Boltzmann transport theory. Unlike the binary counterpart Bi2Te3, we obtain a pair of Rashba splitting…

Materials Science · Physics 2018-08-01 Z. Z. Zhou , H. J. Liu , D. D. Fan , B. Y. Zhao , C. Y. Sheng , G. H. Cao , S. Huang

We use first-principles electronic structure methods to calculate the electronic thermoelectric properties (i.e. due to electronic transport only) of single-crystalline bulk $n$-type silicon-germanium alloys vs Ge composition, temperature,…

Materials Science · Physics 2025-02-03 F. Murphy-Armando

Diminution of the thermal conductivity is a crucial aspect in thermoelectric research. We report a systematic and significant reduction of the cross-plane thermal conductivity in a model system consisting of DC sputtered TiNiSn and HfNiSn…

Low band gap thermoelectric materials suffer from bipolar effects at high temperatures, with increased electronic thermal conductivity and reduced Seebeck coefficient, leading to reduced power factor and low ZT figure of merit. In this work…

Materials Science · Physics 2022-03-14 Patrizio Graziosi , Zhen Li , Neophytos Neophytou

Improving the figure of merit $zT$ of thermoelectric materials requires simultaneously a high power factor and low thermal conductivity. An effective approach for increasing the power factor is to align the band extremum and achieve high…

Materials Science · Physics 2019-03-06 Jiangang He , Yi Xia , S. Shahab Naghavi , Vidvuds Ozoliņš , Chris Wolverton

Here, we investigate the thermoelectric properties of the marcasite-type compounds MSb$_2$ (M = Ta, Nb) in the temperature range of 310-730 K. These compounds were synthesized by a solid-state reaction followed by the spark plasma sintering…

Materials Science · Physics 2024-03-20 Shamim Sk , Naoki Sato , Takao Mori

Although the electrical transport properties of mesoscopic metallic samples have been investigated extensively over the past two decades, the thermal properties have received far less attention. This may be due in part to the difficulty of…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 D. A. Dikin , S. Jung , V. Chandrasekhar

PbTe, one of the most promising thermoelectric materials, has recently demonstrated thermoelectric figure of merit ($ZT$) of above 2.0 when alloyed with group II elements. The improvements are due mainly to significant reduction of lattice…

Materials Science · Physics 2018-05-04 Yi Xia , James M. Hodges , Mercouri G. Kanatzidis , Maria K. Y. Chan

The thermoelectric transport properties of $\text{Bi}_2\text{Te}_3/\text{Sb}_2\text{Te}_3$superlattices are analyzed on the basis of first-principles calculations and semi-classical Boltzmann theory. The anisotropy of the thermoelectric…

Materials Science · Physics 2012-09-11 N. F. Hinsche , B. Yu. Yavorsky , M. Gradhand , M. Czerner , M. Winkler , J. König , H. Böttner , I. Mertig , P. Zahn

Half-Heusler compounds (space group Fm3m) has garnered increasing attention in recent years in the thermoelectric community. Three decades ago, refractory RNiSn half-Heusler compounds (R represents refractory metals such as Hf, Zr, Ti) were…

Materials Science · Physics 2020-01-08 S. Joseph Poon

Improving the thermoelectric efficiency is one of the greatest challenges in materials science. The recent discovery of excellent thermoelectric performance in simple orthorhombic SnSe crystal offers new promise in this prospect [Zhao et…

Materials Science · Physics 2015-05-12 Guangqian Ding , Guoying Gao , Kailun Yao

Whether porosity can effectively improve thermoelectric performance is still an open question. Herein we report that thermoelectric performance can be significantly enhanced by creating porosity in n-type Mg3.225Mn0.025Sb1.5Bi0.49Te0.01,…

The electronic structure and thermoelectric properties of are studied by the first principles and the semiclassical BoltzTrap theory.

Materials Science · Physics 2017-09-13 Gui Yang , jueming Yang , Yuli Yan , Yuanxu Wang

The interplay between half-metallic ferromagnetism and spin-orbit coupling within the inversion symmetry-broken structure of half Heuslers provides an ideal platform for various spintronics functionalities. Taking advantage of good lattice…

In the last few decades, the study of topological materials has been carried out on an extensive scale. Half-Heusler alloys are well known for their topological behaviours. In this work, we present a detailed study of topological properties…

Materials Science · Physics 2021-09-22 Vivek Pandey , Antik Sihi , Sudhir K. Pandey

The thermoelectric properties of n type semiconductor, TiNiSn is optimized by partial substitution with metallic, MnNiSb in the half Heusler structure. Herein, we study the transport properties and intrinsic phase separation in the system.…

Disordered Systems and Neural Networks · Physics 2016-12-06 T. Berry , S. Ouardi , G. H. Fecher , B. Balke , G. Kreiner , G. Auffermann , W. Schnelle , C. Felser

We compute the thermoelectric and thermal transport in the weakly disordered non-Fermi liquid phase of the Luttinger semimetals at zero doping, where the decay rate associated with the (strong) Coulomb interactions is much larger than the…

Strongly Correlated Electrons · Physics 2024-06-25 Hermann Freire , Ipsita Mandal
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