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Present-day thermodynamics has long outgrown the initial frames of the heat-engine theory and transmuted into a rather general macroscopic method for studying kinetics of various transfer processes in their inseparable connection with the…

General Physics · Physics 2014-04-02 V. A Etkin

The usual formulation of thermodynamics is based on the additivity of macroscopic systems. However, there are numerous examples of macroscopic systems that are not additive, due to the long-range character of the interaction among the…

Statistical Mechanics · Physics 2022-06-22 Ivan Latella , Agustín Pérez-Madrid , Alessandro Campa , Lapo Casetti , Stefano Ruffo

Approach of mesoscopic state variables to time independent equilibrium sates (zero law of thermodynamics) gives birth to the classical equilibrium thermodynamics. Approach of fluxes and forces to fixed points (equilibrium fluxes and forces)…

Statistical Mechanics · Physics 2023-10-25 Miroslav Grmela

We consider stochastic thermodynamics as a theory of statistical inference for experimentally observed fluctuating time-series. To that end, we introduce a general framework for quantifying the knowledge about the dynamical state of the…

Statistical Mechanics · Physics 2015-05-19 Bernhard Altaner , Jürgen Vollmer

Quantifying energy flows at nanometer scales promises to guide future research in a variety of disciplines, from microscopic control and manipulation, to autonomously operating molecular machines. A general understanding of the…

Statistical Mechanics · Physics 2018-11-26 Steven J. Large , Raphaël Chetrite , David A. Sivak

A comparative analysis of two concepts aimed at microscopic substantiation of thermodynamics and kinetics has been performed. The first concept is based on the idea of microscopic reversibility of the dynamics of a system of particles,…

Statistical Mechanics · Physics 2024-02-28 A. Yu. Zakharov

Multiscale thermodynamics is a theory of relations among levels of description. Energy and entropy are its two main ingredients. Their roles in the time evolution describing approach of a level (starting level) to another level involving…

Statistical Mechanics · Physics 2024-02-26 Miroslav Grmela

This paper shows how mesoscopic nonequilibrium thermodynamics can be applied to condensation and evaporation. By extending the normal set of thermodynamic variables with two internal variables, we are able to give a new theoretical…

Statistical Mechanics · Physics 2009-11-10 D. Bedeaux , S. Kjelstrup , J. M. Rubi

Application of thermodynamics to driven systems is discussed. As particular examples, simple traffic flow models are considered. On a microscopic level, traffic flow is described by Bando's optimal velocity model in terms of accelerating…

Statistical Mechanics · Physics 2007-07-16 R. Mahnke , J. Kaupuzs , J. Hinkel , H. Weber

A multiscale theory of interacting continuum mechanics and thermodynamics of mixtures of fluids, electrodynamics, polarization and magnetization is proposed. The mechanical (reversible) part of the theory is constructed in a purely…

Classical Physics · Physics 2020-08-26 Petr Vagner , Michal Pavelka , Ogul Esen

Extended Thermodynamics is a very important theory: for example, it predicts hyperbolicity, finite speeds of propagation waves as well as continuous dependence on initial data. Therefore, it constitutes a significative improvement of…

Mathematical Physics · Physics 2007-05-23 Sebastiano Pennisi , Maria Cristina Carrisi , Antonio Scanu

What is really measured in dynamic calorimetric experiments is still an open question. This paper is devoted to this question, which can be usefully envisaged by means of macroscopic non-equilibrium thermodynamics. From the pioneer work of…

Soft Condensed Matter · Physics 2007-07-15 Jean-Luc Garden

A sudden change in the macroscopic parameters of a system will cause it to depart from equilibrium. In this paper we study how a lack of change can also inform of such a departure, and allow for work extraction. Potential events that are…

Statistical Mechanics · Physics 2022-02-03 Sushrut Ghonge , Dervis Can Vural

Computational studies of the thermodynamic properties of materials at the mesoscopic and macroscopic scales -- involving lengths and times of at least $\mu$m and $\mu$s, respectively -- rely on a coarse-graining approximation such that only…

Materials Science · Physics 2026-05-12 Mauro Pulzone , Iñigo Robredo-Magro , Jorge Íñiguez-González

The thermodynamics with medium effects expressed by the dispersion relation of the temperature and density dependent particle mass is studied. Many previous treatments have been reviewed. A new thermodynamical treatment based on the…

Nuclear Theory · Physics 2007-05-23 Shaoyu Yin , Ru-Keng Su

The concept of entropy in nonequilibrium macroscopic systems is investigated in the light of an extended equation of motion for the density matrix obtained in a previous study. It is found that a time-dependent information entropy can be…

Statistical Mechanics · Physics 2009-11-10 W. T. Grandy

A principle on the macroscopic motion of systems in thermodynamic equilibrium, rarely discussed in texts, is reviewed: Very small but still macroscopic parts of a fully isolated system in thermal equilibrium move as if points of a rigid…

General Physics · Physics 2017-03-09 Juan R. Sanmartin

In a first part the scope of classical thermodynamics and statistical mechanics is discussed in the broader context of formal dynamical systems, including computer programmes. In this context classical thermodynamics appears as a particular…

Statistical Mechanics · Physics 2009-11-11 Daniel Pfenniger

A thermodynamics for systems at a stationary states is formulated. It is based upon the assumption of the existence of local equilibrium in phase space which enables one to interpret the probability density ans its conjugated nonequilibrium…

Statistical Mechanics · Physics 2007-05-23 I. Santamaria-Holek , J. M. Rubi , A. Perez-Madrid

We consider macroscopic systems in weak contact with boundary reservoirs and under the action of external fields. We present an explicit formula for the Hamiltonian of such systems, from which we deduce the equation of motions, the action…

Probability · Mathematics 2022-11-14 Angèle Bouley , Claudio Landim