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We develop a geometric framework for irreversible transport phenomena in which macroscopic evolution equations arise from the combined structure of a thermodynamic state metric and an Onsager-based dissipation metric. The construction…
In this paper we clarify the role of heat flux in the hydrodynamic balance equations, facilitating the formulation of an Onsager relation within the framework of this theory. Previously thought to be unobtainable from the present form of…
Extended irreversible thermodynamics is a theory that expands the classical framework of nonequilibrium thermodynamics by going beyond the local-equilibrium assumption. A notable example of this is the Maxwell-Cattaneo heat flux model,…
In this work, we present a new model for the interpretation of the local dynamic behavior and the mechanical reinforcement mechanism in polymer nanocomposites. The temperature dependence of the dynamics in the glassy region is described by…
The existence of large-data weak solutions to a steady compressible Navier-Stokes-Fourier system for chemically reacting fluid mixtures is proved. General free energies are considered satisfying some structural assumptions, with a pressure…
The exact evolution in time and space of a distribution of the temperature (or density of diffusing matter) in an isotropic homogeneous medium is determined where the initial distribution is described by a piecewise polynomial. In two…
The continuum equations of fluid mechanics are rederived with the intention of keeping certain mechanical and thermodynamic concepts separate. A new "mechanical" mass density is created to be used in computing inertial quantities, whereas…
We introduce a diffuse interface model describing the evolution of a mixture of two different viscous incompressible fluids of equal density. The main novelty of the present contribution consists in the fact that the effects of temperature…
The objective of this work is to determine the nonlinear flux-force relations for systems out of Onsager's region that respect the existing thermodynamic theorems for systems far from equilibrium. To this aim, a thermodynamic theory for…
Hydrodynamic projections, the projection onto conserved charges representing ballistic propagation of fluid waves, give exact transport results in many-body systems, such as the exact Drude weights. Focussing one one-dimensional systems, I…
The application of a temperature gradient along a fluid-solid interface generates stresses in the fluid causing "thermo-osmotic" flow. Much of the understanding of this phenomenon is based on Derjaguin's work relating thermo-osmotic flows…
We study the shear-induced diffusion effect and the transition to irreversibility in suspensions under oscillatory shear flow by performing an analysis of the entropy production associated to the motion of the particles. We show that the…
We analyze diffusion of small particles in a solid polymeric medium taking into account a short range particle-polymer interaction. The system is modeled by a particle diffusion on a ternary lattice where the sites occupied by polymer…
We study thermal diffusion in binary mixtures in the framework of non-equilibrium thermodynamics. Our formal result displays the role of partial enthalpies and Onsager's generalized mobilities. The mobility ratio provides a measure for the…
Properties of an infinite system of nonlinearly coupled ordinary differential equations are discussed. This system models some properties present in the equations of motion for an inviscid fluid such as the skew symmetry and the…
The influence of short-range interactions between a multi-phase, multi-component mixture and a solid wall in confined geometries is crucial in life sciences and engineering. In this work, we extend the Cahn-Hilliard model with dynamic…
We introduce the idea of {\it collisional models} for Brownian particles, in which a particle is sequentially placed in contact with distinct thermal environments and external forces. Thermodynamic properties are exactly obtained,…
The original Cahn-Hilliard model in an arbitrary domain with two prescribed boundary conditions is extended to a Cahn-Hilliard-type model in a larger, regular domain with homogeneous Neumann boundary conditions. The extension is based on…
Irreversible processes play a major role in the description and prediction of atmospheric dynamics. In this paper, we present a variational derivation of the evolution equations for a moist atmosphere with rain process and subject to the…
The Boltzmann kinetic equation is considered to compute the transport coefficients associated with the mass flux of intruders in a granular gas. Intruders and granular gas are immersed in a gas of elastic hard spheres (molecular gas). We…