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The evaluation of the electrostatic potential is fundamental to the study of condensed phase systems. We discuss the calculation of the relevant lattice summations by Ewald-type techniques. A model charge density is introduced, that cancels…

Materials Science · Physics 2026-04-14 Chiara Ribaldone , Jacques Kontak Desmarais

The properties of metallic systems with important and structured excitations at low energies, such as Cu, are challenging to describe with simple models like the plasmon pole approximation (PPA), and more accurate and sometimes prohibitive…

Materials Science · Physics 2023-04-26 Dario A. Leon , Andrea Ferretti , Daniele Varsano , Elisa Molinari , Claudia Cardoso

Using the recently developed version of the GW method employing the one-site approximation and self-consistent quasiparticle basis set we calculated the electronic structure of 3d and 4d transition metals at experimental atomic volumes. The…

Strongly Correlated Electrons · Physics 2007-08-16 K. D. Belashchenko , V. P. Antropov , N. E. Zein

The frozen Gaussian approximation provides a highly efficient computational method for high frequency wave propagation. The derivation of the method is based on asymptotic analysis. In this paper, for general linear strictly hyperbolic…

Numerical Analysis · Mathematics 2010-12-23 Jianfeng Lu , Xu Yang

Hedin's $GW$ approximation to the electronic self-energy has been impressively successful to calculate quasiparticle energies, such as ionization potentials, electron affinities, or electronic band structures. The success of this fairly…

Chemical Physics · Physics 2024-10-31 Arno Förster , Fabien Bruneval

Recently, the $GW$ approach has emerged as a valuable tool for computing deep core-level binding energies as measured in X-ray photoemission spectroscopy. However, $GW$ fails to accurately predict shake-up satellite features, which arise…

Chemical Physics · Physics 2024-12-24 Jannis Kockläuner , Dorothea Golze

The dielectric response function and its inverse are crucial physical quantities in materials science. We propose an accurate and efficient strategy to invert the dielectric function matrix. The GW approximation, a powerful approach to…

Numerical Analysis · Mathematics 2024-06-13 Zhengbang Zhou , Huanhuan Ma , Wentiao Wu , Weiguo Gao , Jinlong Yang , Meiyue Shao , Wei Hu

We provide an in-depth examination of the $GW$ approximation of Green's function many-body perturbation theory by detailing both its theoretical and practical aspects in the realm of quantum chemistry. First, the quasiparticle context is…

Chemical Physics · Physics 2024-03-20 Antoine Marie , Abdallah Ammar , Pierre-François Loos

We use an all-electron implementation of the GW approximation to analyze several possible sources of error in the theory and its implementation. Among these are convergence in the polarization and Green's functions, the dependence of QP…

Materials Science · Physics 2013-05-29 M. van Schilfgaarde , T. Kotani , S. Faleev

We introduce an alternative route to quasiparticle self-consistent $GW$ calculations ($\mathrm{qs}GW$) on the basis of a Joint Approximate Diagonalization of the one-body $GW$ Green's functions $G(\varepsilon_n^{QP})$ taken at the input…

Materials Science · Physics 2024-12-05 Ivan Duchemin , Xavier Blase

The important problem of weighted sum rate maximization (WSRM) in a multicellular environment is intrinsically sensitive to channel estimation errors. In this paper, we study ways to maximize the weighted sum rate in a linearly precoded…

Information Theory · Computer Science 2013-10-21 Muhammad Fainan Hanif , Le-Nam Tran , Antti Tölli , Markku Juntti , Savo Glisic

We introduce a method that allows for the calculation of quasi-particle spectra in the GW approximation, yet avoiding any explicit reference to empty one-electron states. This is achieved by expressing the irreducible polarizability…

Materials Science · Physics 2015-05-14 P. Umari , G. Stenuit , S. Baroni

We develop an open-source python workflow package, $py$GWBSE to perform automated first-principles calculations within the GW-BSE (Bethe-Salpeter) framework. GW-BSE is a many body perturbation theory based approach to explore the…

Materials Science · Physics 2022-10-06 Tathagata Biswas , Arunima K. Singh

We present a new all-electron, augmented-wave implementation of the GW approximation using eigenfunctions generated by a recent variant of the full-potential LMTO method. The dynamically screened Coulomb interaction W is expanded in a mixed…

Materials Science · Physics 2009-11-07 Takao Kotani , Mark van Schilfgaarde

A new cumulant-based $GW$ approximation for the retarded one-particle Green's function is proposed, motivated by an exact relation between the improper Dyson self-energy and the cumulant generating function. Qualitative aspects of this…

Strongly Correlated Electrons · Physics 2016-09-21 Matthew Z. Mayers , Mark S. Hybertsen , David R. Reichman

Calculations of ground-state and excited-state properties of materials have been one of the major goals of condensed matter physics. Ground-state properties of solids have been extensively investigated for several decades within the…

Strongly Correlated Electrons · Physics 2009-10-30 F. Aryasetiawan , O. Gunnarsson

An efficient mixed deterministic/sparse-stochastic plane-wave approach is developed for bandstructure calculations of large supercell periodic generalized-Kohn-Sham density functional theory, for any hybrid-exchange density functional. The…

Materials Science · Physics 2025-09-11 Tucker Allen , Barry Y. Li , Tim Duong , Kajsa Williams , Daniel Neuhauser

The performance of many-body perturbation theory for calculating ground-state properties is investigated. We present fully numerical results for the electron gas in three and two dimensions in the framework of the GW approximation. The…

Condensed Matter · Physics 2009-10-31 P. Garcia-Gonzalez , R. W. Godby

Charge-transfer excited states are highly relevant for applications in molecular electronics. However, the accurate calculation of these states in large systems is challenging since wave function methods are prohibitively expensive,…

Chemical Physics · Physics 2025-05-20 Nicola Bogo , Zeyi Zhang , Martin Head-Gordon , Christopher J. Stein

This paper analyses the GW method for finite electronic systems. In a first step, we provide a mathematical framework for the usual one-body operators that appear naturally in many-body perturbation theory. We then discuss the GW equations…

Mathematical Physics · Physics 2025-05-20 Eric Cancès , David Gontier , Gabriel Stoltz
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