Related papers: A generalized conservation law for main-chain poly…
Dendronized polymers consist of an elastic backbone with a set of iterated branch structures (dendrimers)attached at every base point of the backbone. The conformations of such molecules depend on the elastic deformation of the backbone and…
Semiflexible macromolecules in dilute solution under very good solvent conditions are modeled by self-avoiding walks on the simple cubic lattice ($d=3$ dimensions) and square lattice ($d=2$ dimensions), varying chain stiffness by an energy…
We develop topological methods for characterizing the relationship between polymer chain entanglement and bulk viscoelastic responses. We introduce generalized Linking Number and Writhe characteristics that are applicable to open linear…
A class of generalized nonlinear p-Laplacian evolution equations is studied. These equations model radial diffusion-reaction processes in $n\geq 1$ dimensions, where the diffusivity depends on the gradient of the flow. For this class, all…
We develop off-lattice simulations of semiflexible polymer chains subjected to applied mechanical forces using Markov Chain Monte Carlo. Our approach models the polymer as a chain of fixed-length bonds, with configurations updated through…
The time-dependent transverse response of stiff polymers, represented as weakly-bending wormlike chains (WLCs), is well-understood on the linear level, where transverse degrees of freedom evolve independently from the longitudinal ones. We…
Active nematics undergo spontaneous symmetry breaking and show phase separation instability. Within the prevailing notion that macroscopic properties depend only on symmetries and conservation laws, different microscopic models are used out…
We present a Bethe approximation to study lattice models of linear polymers. The approach is variational in nature and based on the cluster variation method (CVM). We focus on a model with $(i)$ a nearest neighbor attractive energy…
We explore matrix product state approximations to wavefunctions which have spontaneously broken symmetries or are critical. We are motivated by the fact that symmetries, and their associated conservation laws, lead to block-sparse matrix…
We analyse the elastic energy of an intercalated smectic where orientationally ordered polymers with an average orientation varying from layer to layer are intercalated between smectic planes. The lowest order terms in the coupling between…
We employ a first principles, force-level approach to self-consistently construct the anharmonic tube confinement field for entangled fluids of rigid needles and for primitive-path (PP) level chains in two limiting situations where chain…
We present results of Monte Carlo study of the monomer-monomer correlation functions, static structure factor and asphericity characteristics of a single homopolymer in the coil and globular states for three distinct architectures of the…
We demonstrate that hyperuniformity, the suppression of density fluctuations at large length scales, emerges generically from the interplay between conservation laws and non-equilibrium driving. The underlying mechanism for this emergence…
We propose a general connection between entanglement-entropy scaling laws and the linear response functions of particle-conserving fermionic systems in their ground state. Specifically, we show that the response to perturbations coupled to…
Polymer models play the special role of elucidating the elementary features describing the physics of long molecules and become essential to interpret the measurements of their magnitudes. In this work the end-to-end distance of an…
Bending of worm-like polymers carries an energy penalty which results in the appearance of a persistence length l such that the polymer is straight on length scales smaller than l and bends only on length scales larger than this length.…
We study the linear instability with respect to necking of a filament of polymeric fluid undergoing uniaxial extension. Contrary to the widely discussed Considere criterion, we find the onset of instability to relate closely to the onset of…
A polymer-chain network is a collection of interconnected polymer-chains, made themselves of the repetition of a single pattern called a monomer. Our first main result establishes that, for a class of models for polymer-chain networks, the…
Amorphous packings of non-spherical particles such as ellipsoids and spherocylinders are known to be hypostatic: the number of mechanical contacts between particles is smaller than the number of degrees of freedom, thus violating Maxwell's…
A long-standing problem with the many-body approximations for interacting condensed bosons has been the dichotomy between the ``conserving'' and ``gapless'' approximations, which either obey the conservations laws or satisfy the…