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We present a computer program to calculate the quantised rotational and hyperfine energy levels of $^{1}\Sigma $ diatomic molecules in the presence of dc electric, dc magnetic, and off-resonant optical fields. Our program is applicable to…

Computational Physics · Physics 2022-09-28 Jacob A. Blackmore , Philip D. Gregory , Jeremy M. Hutson , Simon L. Cornish

A theoretical scheme for the analysis of experimental data on IR spectroscopy for a quantum particle in a double well potential (DWP) is suggested. The analysis is based on the trigonometric DWP for which the exact analytic solution of the…

Chemical Physics · Physics 2019-06-06 A. E. Sitnitsky

We derive the spectral curves for $q$-part double Hurwitz numbers, $r$-spin simple Hurwitz numbers, and arbitrary combinations of these cases, from the analysis of the unstable (0,1)-geometry. We quantize this family of spectral curves and…

Algebraic Geometry · Mathematics 2024-06-26 Motohico Mulase , Sergey Shadrin , Loek Spitz

An alternative method is introduced to solve a simple two-dimensional models describing vibrational excitation and dissociation processes during the electron-molecule collisions. The model works with one electronic and one nuclear degree of…

Chemical Physics · Physics 2018-12-19 Roman Čurík , Dávid Hvizdoš , Chris H. Greene

We consider the Schroedinger operator on graphs and study the spectral statistics of a unitary operator which represents the quantum evolution, or a quantum map on the graph. This operator is the quantum analogue of the classical evolution…

chao-dyn · Physics 2009-10-31 Holger Schanz , Uzy Smilansky

We show how to divide a coupled multi-spin system into a small subset of ``active'' spins that evolve under chemical shift or scalar coupling operators, and a larger subset of ``spectator'' spins which are returned to their initial states,…

Quantum Physics · Physics 2009-10-31 N Linden , H Barjat , RJ Carbajo , R Freeman

We formulate the theory for a diatomic molecule in a spatially degenerate electronic state interacting with a non-resonant laser field and investigate its rovibrational structure in the presence of the field. We report on \textit{ab initio}…

A general algorithm for computing the quadrupole-hyperfine effects in the rovibrational spectra of polyatomic molecules is presented for the case of ammonia (NH$_3$). The method extends the general variational approach TROVE by adding the…

Chemical Physics · Physics 2017-10-25 Andrey Yachmenev , Jochen Küpper

The Double Operator Integral (DOI) framework provides a powerful tool for analyzing perturbations and interactions between self-adjoint operators in functional analysis and spectral theory. However, most existing DOI formulations rely on…

Functional Analysis · Mathematics 2025-03-21 Shih-Yu Chang

A theoretical spin-based scheme for performing a variety of quantum computations is presented. It makes use of an array of multiple identical computer vectors of phosphorus-doped silicon where the nuclei serve as logical qubits and the…

Quantum Physics · Physics 2013-02-08 Aharon Blank

In this article, we present a simulation study of the linear and nonlinear spectroscopy of dense atomic vapors. Motivated by recent experiments, we focus on double quantum spectroscopy which directly probes dipole-dipole interactions. By…

Atomic Physics · Physics 2023-07-17 Cyril Falvo , Hebin Li

Differentiable programming allows for derivatives of functions implemented via computer code to be calculated automatically. These derivatives are calculated using automatic differentiation (AD). This thesis explores two applications of…

Plasma Physics · Physics 2024-10-16 Nick McGreivy

The two matrix model is considered, with measure given by the exponential of a sum of polynomials in two different variables. It is shown how to derive a sequence of pairs of ``dual'' finite size systems of ODEs for the corresponding…

Exactly Solvable and Integrable Systems · Physics 2007-05-23 M. Bertola , B. Eynard , J. Harnad

We present an efficient algorithm for one- and two-component relativistic exact-decoupling calculations. Spin-orbit coupling is thus taken into account for the evaluation of relativistically transformed (one-electron) Hamiltonian. As the…

Chemical Physics · Physics 2013-05-10 Daoling Peng , Nils Middendorf , Florian Weigend , Markus Reiher

Molecular Docking (MD) is an important step of the drug discovery process which aims at calculating the preferred position and shape of one molecule to a second when they are bound to each other. During such analysis, 3D representations of…

Quantum Physics · Physics 2021-07-30 Kevin Mato , Riccardo Mengoni , Daniele Ottaviani , Gianluca Palermo

The quantum mechanical motion of the atomic nuclei is considered over a single- or a multi-dimensional subspace of electronic states which is separated by a gap from the rest of the electronic spectrum over the relevant range of nuclear…

Chemical Physics · Physics 2019-07-24 Edit Matyus , Stefan Teufel

A general analytical expression for the double differential cross section of inclusive deuteron stripping reaction on nuclei at intermediate energies of incident particles was obtained in the diffraction approximation. Nucleon-nucleus…

Nuclear Theory · Physics 2016-03-30 V. I. Kovalchuk

WavePacket is an open-source program package for numeric simulations in quantum dynamics. It can solve time-independent or time-dependent linear Schr\"odinger and Liouville-von Neumann-equations in one or more dimensions. Also coupled…

Quantum Physics · Physics 2023-02-09 Burkhard Schmidt , Carsten Hartmann

A method for storing quantum information is presented for $3$-level atomic systems interacting dipolarly with a single radiation field. The method involves performing simple local SU(2) rotations on the Hamiltonian. Under equal detuning,…

Quantum Physics · Physics 2023-06-02 R. López-Peña , S. Cordero , E. Nahmad-Achar , O. Castaños

Numerical solutions of partial differential equations enable a broad range of scientific research. The Dedalus Project is a flexible, open-source, parallelized computational framework for solving general partial differential equations using…

Instrumentation and Methods for Astrophysics · Physics 2020-04-29 Keaton J. Burns , Geoffrey M. Vasil , Jeffrey S. Oishi , Daniel Lecoanet , Benjamin P. Brown