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The strong-interaction functionals $W_\infty[n]$ and ${W'}_\infty[n]$ play an important role in the adiabatic-connection method of Density Functional Theory. The strictly-correlated electron approach can be used to exactly compute these…

Other Condensed Matter · Physics 2026-03-09 L. A. Constantin , F. Naeem , 3 E. Fabiano , F. Sarcinella , F. Della Sala

We develop a semiclassical density functional theory in the context of quantum dots. Coulomb blockade conductance oscillations have been measured in several experiments using nanostructured quantum dots. The statistical properties of these…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Denis Ullmo , Tatsuro Nagano , Steven Tomsovic , Harold U. Baranger

We present a novel analytical method for calculating the spectral function and the density of states in speckle potentials, valid in the semiclassical regime. Our approach relies on stationary phase approximations, allowing us to describe…

Disordered Systems and Neural Networks · Physics 2016-08-24 Tony Prat , Nicolas Cherroret , Dominique Delande

A general semiclassical theory for the calculation of reaction rate constants is developed. The theory can be understood as a formal framework that encompasses existing semiclassical methods: instanton theory and semiclassical transition…

Chemical Physics · Physics 2025-10-09 Joseph E. Lawrence

The S-matrix theory formulation of closed-orbit theory recently proposed by Granger and Greene is extended to atoms in crossed electric and magnetic fields. We then present a semiclassical quantization of the hydrogen atom in crossed…

Chaotic Dynamics · Physics 2009-11-07 T. Bartsch , J. Main , G. Wunner

We show how one can construct \alert{a simple} exchange functional by extending the well-know local-density approximation (LDA) to finite uniform electron gases. This new generalized local-density approximation (GLDA) functional uses only…

Chemical Physics · Physics 2017-05-01 Pierre-François Loos

We analyze the methodology and the performance of subsystem density functional theory (DFT) with meta-generalized gradient approximation (meta-GGA) exchange-correlation functionals for non-bonded systems. Meta-GGA functionals depend on the…

Other Condensed Matter · Physics 2015-05-05 S. Śmiga , E. Fabiano , S. Laricchia , L. A. Constantin , F. Della Sala

We have shown an example of semiclassical transition in $\phi^{4}$ theory with positive coupling constant. This process can be described by the classical $O(4)$-invariant solution, considered on a contour in the complex time plane. The…

High Energy Physics - Phenomenology · Physics 2010-11-01 Alexander Kyatkin

We investigate a semiclassical momentum density energy functional for atoms and show that it yields the same value as the well-known Thomas-Fermi functional. In fact, we show an explicit relation between the minimizers of the two…

Mathematical Physics · Physics 2013-11-18 Verena von Conta , Heinz Siedentop

The derivative discontinuity of the exchange-correlation functional of density-functional theory is cast as the difference of two types of electron affinities. We show that standard Kohn-Sham calculations can be used to calculate both…

Chemical Physics · Physics 2007-12-13 F. P. Rosselli , A. B. F. da Silva , K. Capelle

Density Functional Theory (DFT) is widely used for atomistic simulations. However, its reach stays limited due to several limitations such as lack of accurate exchange-correlation functional, requirement of costly O(N 3) diagonalization…

Quantum Physics · Physics 2026-05-18 Namrata Manglani , Samrit Kumar Maity , Shashank Sharma , Soham Phulare , Sanjay Wandhekar

The earlier proposed Dynamics-Generating Approach (DGA) is reviewed and extended. Starting from an arbitrarily chosen group or semigroup which have structure similar to the structure of Galilei group, DGA allows one to construct…

Mathematical Physics · Physics 2013-12-10 Michael B. Mensky

Density Functional Theory (DFT) is one of the most widely used methods for "ab initio" calculations of the structure of atoms, molecules, crystals, surfaces, and their interactions. Unfortunately, the customary introduction to DFT is often…

Physics Education · Physics 2010-12-07 Nathan Argaman , Guy Makov

Nuclear mean-field models are briefly reviewed to illustrate its foundation and necessity of state dependence in effective interactions. This state dependence is successfully taken into account by the density dependence, leading to the…

Nuclear Theory · Physics 2015-06-11 Takashi Nakatsukasa

Density-potential functional theory (DPFT) is an alternative formulation of orbital-free density functional theory that may be suitable for modeling the electronic structure of large systems. To date, DPFT has been applied mainly to quantum…

Materials Science · Physics 2023-04-21 Martin-Isbjörn Trappe , William C. Witt , Sergei Manzhos

One of the standard generalized-gradient approximations (GGAs) in use in modern electronic-structure theory, PBE, and a recently proposed modification designed specifically for solids, PBEsol, are identified as particular members of a…

Materials Science · Physics 2015-05-13 Luana S. Pedroza , Antonio J. R. da Silva , Klaus Capelle

We test Laplacian-level meta-generalized gradient approximation (meta-GGA) non-interacting kinetic energy functionals based on the fourth-order gradient expansion (GE4). We consider several well known Laplacian-level meta-GGAs from…

Chemical Physics · Physics 2014-03-19 S. Laricchia , L. A. Constantin , E. Fabiano , F. Della Sala

We review various semiclassical models for strong-field physics. These semiclassical models employ ensembles of classical trajectories to simulate electron motion in the continuum after being released from an atom or molecule by an external…

Atomic Physics · Physics 2025-10-16 Nikolay Shvetsov-Shilovski

We show that it is possible to still use semiclassical gravity together with quantum field theory beyond the regimes where the field state is coherent. In particular, we identify families of cat states (superposition of…

Quantum Physics · Physics 2024-01-29 Shahnewaz Ahmed , Caroline Lima , Eduardo Martín-Martínez

Closed-orbit theory provides a general approach to the semiclassical description of photo-absorption spectra of arbitrary atoms in external fields, the simplest of which is the hydrogen atom in an electric field. Yet, despite its apparent…

Chaotic Dynamics · Physics 2009-11-07 T. Bartsch , J. Main , G. Wunner