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We investigate theoretically the optical properties associated to plasmon resonances of metal nanowires with cross section given by low-order Chebyshev nanoparticles (like rounded-tip nanostars or nanoflowers). The impact of the nanoflower…

Optics · Physics 2009-10-23 V. Giannini , R. Rodriguez-Oliveros , J. A. Sanchez-Gil

We present a microscopic model for surface-enhanced Raman scattering (SERS) from molecules adsorbed on small noble-metal nanoparticles. In the absence of direct overlap of molecular orbitals and electronic states in the metal, the main…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Vitaliy N. Pustovit , Tigran V. Shahbazyan

We present a method to locally probe spatially varying chemical composition of soft matter systems by use of optically controlled and elastically self-assembled plasmonic nanoantennae. Disc-shaped metal particles with sharp irregular edges…

Localized surface plasmons are confined collective oscillations of electrons in metallic nanoparticles. When driven by light, the optical response is dictated by geometrical parameters and the dielectric environment and plasmons are…

The effect of smooth shape changes of metallic nanoparticles on localized surface plasmon resonances is assessed with a boundary integral equation method. The boundary integral equation method allows compact expressions of nanoparticle…

Mesoscale and Nanoscale Physics · Physics 2013-02-19 Titus Sandu

The influence of morphology on the optical properties of silver nanoparticles is studied. A general relationship between the surface plasmon resonances and the morphology of each nanoparticle is established. The optical response is…

Chemical Physics · Physics 2007-05-23 A. L. Gonzalez , C. Noguez

We predict the simultaneous occurrence of two fundamental phenomena for metal nanoparticles possessing sharp corners: First, the main plasmonic dipolar mode experiences strong red shift with decreasing corner curvature radius; its resonant…

Optics · Physics 2015-06-05 B. Sturman , E. Podivilov , M. Gorkunov

We have investigated the effects of tuning the localized surface plasmon resonances (LSPRs) of silver nanoparticles on the fluorescence intensity, lifetime, and Raman signal from nearby fluorophores. The presence of a metallic structure can…

Other Condensed Matter · Physics 2009-11-13 N. I. Cade , T. Ritman-Meer , D. Richards

We study Raman scattering in active media placed in proximity of different types of metal nanostructures, at wavelengths that display either Fabry-Perot or plasmonic resonances, or a combination of both. We use a semi-classical approach to…

Optics · Physics 2015-06-05 M. Scalora , M. A. Vincenti , D. de Ceglia , M. Grande , J. W. Haus

In this paper we provide a mathematical framework for localized plasmon resonance of nanoparticles. Using layer potential techniques associated with the full Maxwell equations, we derive small-volume expansions for the electromagnetic…

Mathematical Physics · Physics 2015-10-28 Habib Ammari , Youjun Deng , Pierre Millien

We study the role of strong electron confinement in surface-enhanced Raman scattering from molecules adsorbed on small noble-metal particles. We describe a new source of Raman signal enhancement which originates from different behavior of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Vitaliy N. Pustovit , Tigran V. Shahbazyan

We study the linewidth of the surface plasmon resonance in the optical absorption spectrum of metallic nanoparticles, when the decay into electron-hole pairs is the dominant channel. Within a semiclassical approach, we find that the…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Rafael A. Molina , Dietmar Weinmann , Rodolfo A. Jalabert

Sharp metal corners and tips support plasmons localized on the scale of the curvature radius -- superlocalized plasmons. We analyze plasmonic properties of nanoparticles with small and sharp corner- and tip-shaped surface perturbations in…

Optics · Physics 2016-01-20 M. V. Gorkunov , B. I. Sturman , E. V. Podivilov

Acoustic vibrations of nanoparticles made of materials with anisotropic elasticity and nanoparticles with non-spherical shapes are theoretically investigated using a homogeneous continuum model. Cubic, hexagonal and tetragonal symmetries of…

Mesoscale and Nanoscale Physics · Physics 2009-06-02 Lucien Saviot , Daniel B. Murray

Graphene covered metal nanoparticles constitute a novel type of hybrid materials, which provide a unique platform to study plasmonic effects, surface-enhanced Raman scattering (SERS), and metal-graphene interactions at the nanoscale. Such a…

Two possible mechanisms of surface plasmon (SP) oscillations damping in metallic nanoparticles (MNPs), not connected with electron-phonon interaction are investigated theoretically: a) the radiation damping of SP, b) resonant coupling of SP…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Armen Melikyan , Hayk Minassian

Transient absorption and Raman scattering measurements on noble metal nanoparticles offer complimentary information on their vibrational modes and mechanical interactions with their surroundings. We have developed a comprehensive modeling…

Mesoscale and Nanoscale Physics · Physics 2024-10-29 Rachel Gelfand , Matthew Pelton

Experiments have shown strong effects of some substrates on the localized plasmons of metallic nano particles but they are inconclusive on the affecting parameters. Here we have used Discrete Dipole Approximation in conjunction with…

Optics · Physics 2015-06-04 Murugesan Venkatapathi , Abhay K. Tiwari

Low-frequency Raman scattering experiments have been performed on thin films consisting of nickel-silver composite nanoparticles embedded in alumina matrix. It is observed that the Raman scattering by the quadrupolar modes, strongly…

Condensed Matter · Physics 2007-05-23 H. Portales , L. Saviot , E. Duval , M. Gaudry , E. Cottancin , M. Pellarin , J. Lerme , M. Broyer

In this work, we proposed new shape nanoparticles in the name of supershape nanoparticles by manipulation in the morphology of a disk nanoparticle. The electric field distribution of supershape nanoparticles were investigated at resonance…

Materials Science · Physics 2017-09-19 F. Babaei , M. Javidnasab , A. Rezaei
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