Related papers: Normal modes. The true story
Recently, a general expression for Eckart-frame Hamilton operators has been obtained by the gateway Hamiltonian method ({\it J. Chem. Phys.} {\bf 142}, 174107 (2015); {\it ibid.} {\bf 143}, 064104 (2015)). The kinetic energy operator in…
An estimate on the number of distinct relative periodic orbits around a stable relative equilibrium in a Hamiltonian system with continuous symmetry is given. This result constitutes a generalization to the Hamiltonian symmetric framework…
In classical mechanics, the 'geometry of motion' refers to a development to visualize the motion of freely spinning bodies. In this paper, such an approach of studying the rotational motion of axisymmetric variable mass systems is…
A microscopic quantum ideal rotor-model Hamiltonian (distinct from that of Bohr's rotational model) is derived for a rotation about a single axis by applying a dynamic rotation operator to the deformed nuclear ground-state wavefunction. It…
In this paper we demonstrate how asymmetric molecular rotational spectra may be introduced to students both "pictorially" and with simple formulae. It is shown that the interpretation of such spectra relies heavily upon pattern recognition.…
A collective model is proposed to describe the chiral rotation and vibration and applied to a system with one $h_{11/2}$ proton particle and one $h_{11/2}$ neutron hole coupled to a triaxial rigid rotor. The collective Hamiltonian is…
The scattering of electromagnetic waves by resonant systems is determined by the excitation of quasinormal modes (QNMs), i.e., the eigenmodes of the system. This Review addresses three fundamental concepts in relation with the…
Through the introduction of a class of trial wave functions portraying combined rotations and vibrations of molecules formed through particle localization in concentric polygonal rings, a correlated basis is constructed that spans the…
The behavior of polyatomic molecules around their equilibrium positions can be regarded as quantum coupled anharmonic oscillators. Solving the corresponding Schr\"odinger equations can interpret or predict experimental spectra of molecules.…
In a special representation of complex action theory that we call ``future-included'', we study a harmonic oscillator model defined with a non-normal Hamiltonian $\hat{H}$, in which a mass $m$ and an angular frequency $\omega$ are taken to…
Complete description of the classical and quantum dynamics of a particle in an anisotropic, rotating, harmonic trap is given. The problem is studied in three dimensions and no restrictions on the geometry are imposed. In the generic case,…
A single frictional elastic disk, supported against gravity by two others, rotates steadily when the supports are vibrated and the system is tilted with respect to gravity. Rotation is here studied using Molecular Dynamics Simulations, and…
Consider a "simplicial molecule": $n$ equal point masses placed at the vertices of a regular $(n-1)$-simplex, connected by ${n \choose 2}$ identical springs. We apply the representation theory of the symmetric group $S_n$ to compute its…
We present a perturbative method for ab initio calculations of rotational and rovibrational effective Hamiltonians of both rigid and non-rigid molecules. Our approach is based on a curvilinear implementation of second order vibrational…
In a soliton sector of a quantum field theory, it is often convenient to expand the quantum fields in terms of normal modes. Normal mode creation and annihilation operators can be normal ordered, and their normal ordered products have…
We propose a Hamiltonian formalism for a generalized Friedmann-Roberson-Walker cosmology model in the presence of both a variable equation of state (EOS) parameter $w(a)$ and a variable cosmological constant $\Lambda(a)$, where $a$ is the…
Herein we develop a simple first-principles methodology to determine the modulation that vibrations exert on spin energy levels, a key for the rational design of high-temperature molecular spin qubits and single-molecule magnets. This…
This article investigates entanglement of the motional states of massive coupled oscillators. The specific realization of an idealized diatomic molecule in one-dimension is considered, but the techniques developed apply to any massive…
We introduce the Anharmonic Oscillator Symmetry Model to describe vibrational excitations in molecular systems exhibiting high degree of symmetry. A systematic procedure is proposed to establish the relation between the algebraic and…
We study the most general form of a three dimensional classical integrable system with axial symmetry and invariant under the axis reflection. We assume that the three constants of motion are the Hamiltonian, $H$, with the standard form of…