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Real-time time-dependent density functional theory, in conjunction with the Ehrenfest molecular dynamics scheme, is becoming a popular methodology to investigate ultrafast phenomena on the nanoscale. Thanks to recent developments, it is…

Materials Science · Physics 2020-08-18 Jannis Krumland , Ana M. Valencia , Stefano Pittalis , Carlo A. Rozzi , Caterina Cocchi

Time-dependent density functional theory (TDDFT) is a widely used method to investigate electron dynamics under external time-dependent perturbations such as laser fields. In this work, we present a machine learning approach to accelerate…

Materials Science · Physics 2025-12-02 Karan Shah , Attila Cangi

We propose a theoretical approach for the interpretation of pump-probe measurements where an attosecond pulse is absorbed in the presence of an intense laser pulse. This approach is based on abstractly defined dressed bound states, which…

Quantum Physics · Physics 2012-01-30 Vladislav S. Yakovlev , Michael Korbman , Armin Scrinzi

Measuring fluctuations in matter's low energy excitations is the key to unveil the nature of the nonequilibrium response of materials. A promising outlook in this respect is offered by spectroscopic methods that address matter fluctuations…

We use analytic (current) density-potential maps of time-dependent (current) density functional theory (TD(C)DFT) to inverse engineer analytically solvable time-dependent quantum problems. In this approach the driving potential (the control…

Quantum Physics · Physics 2016-06-01 Mehdi Farzanehpour , I. V. Tokatly

Time-resolved studies have so far relied on rapidly triggering a photo-induced dynamic in chemical or biological ions or molecules and subsequently probing them with a beam of fast moving photons or electrons that crosses the studied…

Chemical Physics · Physics 2021-03-19 Hazem Daoud , R. J. Dwayne Miller

The squeezed photons, as a quantum-correlated light with reduced noise, have emerged as a great resource for sensing the structures of matter. Here we study the transient absorption (TA) scheme using the squeezed photons whose spectral…

Quantum Physics · Physics 2026-05-29 Jiahao Joel Fan , Feihong Liu , Dangyuan Lei , Zhedong Zhang

This chapter provides a basic introduction to excited-state extensions of density functional theory (DFT), including time-dependent (TD-)DFT in both its linear-response and its explicitly time-dependent formulations. As applied to the…

Chemical Physics · Physics 2023-05-02 John M. Herbert

Optical pump-probe spectroscopy is a powerful tool for the study of non-equilibrium electronic dynamics and finds wide applications across a range of fields, from physics and chemistry to material science and biology. However, a shortcoming…

Based on our earlier works [Phys. Rev. B 75, 195127 (2007) & J. Chem. Phys. 128, 234703 (2008)], we propose a formally exact and numerically convenient approach to simulate time-dependent quantum transport from first-principles. The…

Chemical Physics · Physics 2015-05-18 Xiao Zheng , GuanHua Chen , Yan Mo , SiuKong Koo , Heng Tian , ChiYung Yam , YiJing Yan

Time-dependent density-functional theory (TDDFT) is deemed to be a formally rigorous way of dealing with the time-evolution of a many-electron system at the level of electron densities rather than the underlying wavefunctions, which in turn…

Chemical Physics · Physics 2024-11-26 Jochen Schirmer

Many application models in quantum physics and chemistry require to control multi-electron systems to achieve a desired target configuration. This challenging task appears possible in the framework of time-dependent density functional…

Optimization and Control · Mathematics 2018-03-14 Martin Sprengel , Gabriele Ciaramella , Alfio Borzì

We theoretically investigate a relation between the crystalline symmetry and the transient modulation of optical properties of crystalline dielectrics in pump-probe measurements using intense pump and attosecond probe fields. When the…

Materials Science · Physics 2020-04-29 Shunsuke Yamada , Kazuhiro Yabana

Quantum Optimal Control Theory (QOCT) provides the necessary tools to theoretically design driving fields capable of controlling a quantum system towards a given state or along a prescribed path in Hilbert space. This theory must be…

Atomic and Molecular Clusters · Physics 2013-05-30 Alberto Castro , Jan Werschnik , Eberhard K. U. Gross

We calculate the dielectric response of crystalline silicon following irradiation by a high-intensity laser pulse, modeling the dynamics by time-dependent density functional theory (TDDFT). The pump-probe measurements are numerically…

Materials Science · Physics 2014-02-19 S. A. Sato , K. Yabana , Y. Shinohara , T. Otobe , G. F. Bertsch

We present a theoretical description of femtosecond laser induced dynamics of the hydrogen molecule and of singly ionised sodium dimers, based on a real-space, real-time, implementation of time-dependent density functional theory (TDDFT).…

Condensed Matter · Physics 2007-05-23 Alberto Castro , M. A. L. Marques , Julio A. Alonso , George F. Bertsch , Angel Rubio

We propose a time-dependent approach to investigate the motion of electrons in quantum pump device configurations. The occupied one-particle states are propagated in real time and used to calculate the local electron density and current. An…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 G. Stefanucci , S. Kurth , A. Rubio , E. K. U. Gross

We present an effective linear response approach to pump-probe femtosecond coherence spectroscopy in the well separated pulse limit. The treatment presented here is based on a displaced and squeezed state representation for the…

Chemical Physics · Physics 2009-11-06 Anand T. N. Kumar , Florin Rosca , Allan Widom , Paul M. Champion

Strong-field quantum-state control is investigated, taking advantage of the full---amplitude and phase---characterization of the interaction between matter and intense ultrashort pulses via transient-absorption spectroscopy. A sequence of…

Atomic Physics · Physics 2017-04-26 Stefano M. Cavaletto , Zoltán Harman , Thomas Pfeifer , Christoph H. Keitel

Abrupt time variations of the properties of optical materials have been at the center of intense research efforts in recent years, with the prospect of enabling extreme wave transformations and of leveraging time as a degree of freedom for…