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Related papers: Non-adiabatic dynamics of molecules in optical cav…

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Using cold atoms to simulate strongly interacting quantum systems represents an exciting frontier of physics. However, as atoms are nominally neutral point particles, this limits the types of interactions that can be produced. We propose to…

Quantum Physics · Physics 2015-11-04 J. S. Douglas , H. Habibian , C. -L. Hung , A. V. Gorshkov , H. J. Kimble , D. E. Chang

Nonlinear spectroscopy is widely used to study the transient dynamics of molecules under strong light-matter coupling, though it remains unclear to what extent uncoupled intracavity molecules obscure signals from the strongly-coupled…

Chemical Physics · Physics 2026-04-08 Alexander M. McKillop , Marissa L. Weichman

The rapidly developing and converging fields of polaritonic chemistry and quantum optics necessitate a unified approach to predict strongly-correlated light-matter interactions with atomic-scale resolution. Combining concepts from both…

Quantum Physics · Physics 2018-09-19 Johannes Flick , Prineha Narang

Polariton chemistry has been hailed as a potential new route to direct molecular processes with electromagnetic fields. To make further strides, it is essential for the community to clarify which unusual polaritonic phenomena are true…

Chemical Physics · Physics 2025-11-19 Alexander M. McKillop , Marissa L. Weichman

We describe the decoherence-free subspace of N atoms in a cavity, in which decoherence due to the leakage of photons through the cavity mirrors is suppressed. We show how the states of the subspace can be entangled with the help of weak…

Quantum Physics · Physics 2009-10-31 Almut Beige , Daniel Braun , Peter L. Knight

Strongly coupled dissipative optical cavities with nonlinear interactions give new opportunities to explore symmetry breaking phenomena and phase transitions, Josephson dynamics and quantum criticality. Among the different experimental…

In this paper we develop quantum dynamical methods capable of treating the dynamics of chemically reacting systems in an optical cavity in the vibrationally strong-coupling (VSC) limit at finite temperatures and in the presence of a…

Quantum Physics · Physics 2025-02-11 Lachlan P. Lindoy , Arkajit Mandal , David R. Reichman

We explore the quantum dynamics of photoassociation of Bose-Einstein condensed atoms into molecules using an optical cavity field. Inside of an optical resonator, photoassociation of quantum degenerate atoms involves the interaction of…

Quantum Gases · Physics 2015-05-13 Christopher P. Search , J. Mauricio Campuzano , Marko Zivkovic

The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties such as lasing, room temperature polariton condensation, and the modification of excited electronic landscapes…

We present an approach for carrying out non-adiabatic molecular dynamics simulations of systems in which non-adiabatic transitions arise from the coupling between the classical atomic motions and a quasi-continuum of electronic quantum…

Computational Physics · Physics 2018-11-21 Jerome Daligault , Dmitry Mozyrsky

The linear driving for a single-mode optical field in a cavity can result from the external driving of classical field even when the coupling between the classical field and the cavity is weak. We revisit this well known effect with a…

Quantum Physics · Physics 2014-08-06 Yusuf Turek , L. P. Yang , W. Maimaiti , Yong Li , C. P. Sun

We develop a fully quantum mechanical methodology to describe the static properties and the dynamics of a single anharmonic vibrational mode interacting with a quantized infrared cavity field in the strong and ultrastrong coupling regimes.…

Chemical Physics · Physics 2020-06-22 Johan F. Triana , Federico J. Hernández , Felipe Herrera

Cavity quantum electrodynamics provides an ideal platform to engineer and control light-matter interactions with polariton quasiparticles. In this work, we investigate collective phenomena in a system of many particles in a harmonic trap…

Quantum Physics · Physics 2023-06-21 V. Rokaj , S. I. Mistakidis , H. R. Sadeghpour

The experimental realization of strong light-matter coupling with molecules initiated the rapidly evolving field of molecular polaritonics. Most studies focus on how exciton polaritons, which combine electronic excitations with confined…

Chemical Physics · Physics 2025-09-10 Lucas Borges , Thomas Schnappinger , Markus Kowalewski

Non-adiabatic molecular phenomena, arising from the breakdown of the Born-Oppenheimer approximation, govern the fate of virtually all photo-physical and photochemical processes and limit the quantum efficiency of molecules and other…

Quantum Physics · Physics 2024-05-15 N. S. Bassler , M. Reitz , R. Holzinger , A. Vibók , G. J. Halász , B. Gurlek , C. Genes

A dressed-state perturbation theory beyond the rotating waveapproxi-mation (RWA) is presented to investigate the interaction between a two level electronic transition of the polar molecules and a quantized cavity field. Analytical…

Quantum Physics · Physics 2015-11-03 Jing-Yun Zhao , Li-Guo Qin , Xun-Ming Cai , Qiang Lin , Zhong-Yang Wang

Atoms coupled to cavities provide an exciting playground for the study of fundamental interactions of atoms mediated through a common channel. Many of the applications of cavity-QED and cold-atom experiments more broadly, suffer from…

Nonadiabatic effects appear due to avoided crossings or conical intersections that are either intrinsic properties in field-free space or induced by a classical laser field in a molecule. It was demonstrated that avoided crossings in…

Chemical Physics · Physics 2019-11-12 András Csehi , Markus Kowalewski , Gábor J. Halász , Ágnes Vibók

We study theoretically the interaction between two photons in a nonlinear cavity. The photons are loaded into the cavity via a method we propose here, in which the input/output coupling of the cavity is effectively controlled via a tunable…

Quantum Physics · Physics 2020-04-29 Mikkel Heuck , Kurt Jacobs , Dirk R. Englund

Intramolecular energy transfer driven by near-field effects plays an important role in applications ranging from biophysics and chemistry to nano-optics and quantum communications. Advances in strong light-matter coupling in molecular…

Mesoscale and Nanoscale Physics · Physics 2025-07-14 Kristin B. Arnardottir , Piper Fowler-Wright , Christos Tserkezis , Brendon W. Lovett , Jonathan Keeling