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The discovery of superconductivity in CaC6 with a critical temperature (Tc) of 11.5 K reignites much interest in exploring high-temperature superconductivity in graphite intercalation compounds (GICs). Here we identify a GIC NaC4,…

In this letter we report the discovery of superconductivity in the isostructural graphite intercalation compounds C6Yb and C6Ca, with transition temperatures of 6.5K and 11.5K respectively. A structural characterisation of these compounds…

Superconductivity · Physics 2015-06-25 Thomas E. Weller , Mark Ellerby , Siddharth S. Saxena , Robert P. Smith , Neal T. Skipper

The superconducting state of Ca-intercalated graphite CaC6 has been investigated by specific heat measurements. The characteristic anomaly at the superconducting transition (Tc = 11.4 K) indicates clearly the bulk nature of the…

Superconductivity · Physics 2009-11-11 J. S. Kim , R. K. Kremer , L. Boeri , F. S. Razavi

Graphite intercalation compounds (GICs) have long been recognized as promising candidates for high-temperature superconductivity by intercalation or charge doping, yet experimental progress has stalled with transition temperatures (Tc)…

In this letter, we report the discovery of superconductivity in Li3Ca2C6. Several graphite intercalation compounds (GICs) with electron donors, are well known as superconductors. It is probably not astonishing, since it is generally…

We have studied the evolution, with hydrostatic pressure, of the recently discovered superconductivity in the graphite intercalation compounds C$_6$Yb and C$_6$Ca. We present pressure-temperature phase diagrams, for both superconductors,…

Using density functional theory we investigate the occurrence of superconductivity in AC$_6$ with A=Mg,Ca,Sr,Ba. We predict that at zero pressure, Ba and Sr should be superconducting with critical temperatures (T$_c$) 0.2 K and 3.0 K,…

Superconductivity · Physics 2009-11-11 Matteo Calandra , Francesco Mauri

We discuss the current status of the theory of the "high-temperature" superconductivity in intercalated graphites YbC6 and CaC6. We emphasize that while the general picture of conventional, phonon-driven superconductivity has already…

Superconductivity · Physics 2009-11-11 I. I. Mazin , L. Boeri , O. V. Dolgov , A. A. Golubov , G. B. Bachelet , M. Giantomassi , O. K. Andersen

The field of superconductivity in the class of materials known as graphite intercalation compounds has a history dating back to the 1960s. This paper recontextualizes the field in light of the discovery of superconductivity in CaC6 and YbC6…

We report experimental results indicating possible high-temperature superconductivity in graphite intercalation compounds synthesized with lithium-based alloys. Temperature-dependent measurements of magnetization, trapped magnetic flux, and…

A review is given for the theoretical framework to give a reliable prediction of the superconducting transition temperature Tc from first principles, together with a practical strategy for its application to actual materials with…

Superconductivity · Physics 2016-01-15 Yasutami Takada

The pressure effect on the superconducting transition temperature ($T_c$) of the newly-discovered Ca-intercalated graphite compound CaC$_6$ has been investigated up to $\sim$ 16 kbar. $T_c$ is found to increase under pressure with a large…

Superconductivity · Physics 2015-06-25 J. S. Kim , L. Boeri , R. K. Kremer , F. S. Razavi

We report the discovery of superconductivity below 1.65(6) K in Sr-intercalated graphite SrC6, by susceptibility and specific heat (Cp) measurements. In comparison with CaC6, we found that the anisotropy of the upper critical fields for…

Superconductivity · Physics 2009-11-13 J. S. Kim , L. Boeri , J. R. O'Brien , F. S. Razavi , R. K. Kremer

Recently deiscovered superconductivity in YbC$_6$ and CaC$_6$ at temperatures substantially higher than previously known for intercalated graphites, raised several new questions: (1) Is the mechanism considerably different from the…

Superconductivity · Physics 2009-11-11 I. I. Mazin

The deposition and intercalation of metal atoms can induce superconductivity in monolayer and bilayer graphenes. For example, it has been experimentally proved that Li-deposited graphene is a superconductor with critical temperature $T_{c}$…

Superconductivity · Physics 2024-05-07 Jin-Han Tan , Hao Wang , Ying-Jie Chen , Na Jiao , Meng-Meng Zheng , Hong-Yan Lu , Ping Zhang

Terahertz reflectance spectra of the Ca-intercalated graphite CaC6 reveal a superconducting gap below 11K. The gap signature lacks a sharp onset to full reflectivity at 2Delta, but rather shows a distribution of gap values consistent with…

Superconductivity · Physics 2009-11-13 U. Nagel , D. Huvonen , E. Joon , J. S. Kim , R. K. Kremer , T. Room

Search for new high-temperature superconductors and insight into their superconducting mechanism are of fundamental importance in condensed matter physics. The discovery of near-room temperature superconductivity at more than a million…

We report the superconductivity in Ca-intercalated bilayer graphene C$_6$CaC$_6$, the thinnest limit of Ca graphite intercalation compound. We performed \textit{in situ} electrical transport measurements on pristine bilayer graphene,…

Superconductivity · Physics 2016-02-02 S. Ichinokura , K. Sugawara , A. Takayama , T. Takahashi , S. Hasegawa

The dependence of the superconducting transition temperature Tc of CaC6 has been determined as a function of hydrostatic pressure in both helium-loaded gas and diamond-anvil cells to 0.6 and 32 GPa, respectively. Following an initial…

Superconductivity · Physics 2015-05-13 M. Debessai , J. J. Hamlin , J. S. Schilling , Y. Meng , D. Rosenmann , D. G. Hinks , H. Claus

High transition temperature (high-Tc) superconductivity is associated with layered crystal structures. This work considers superconductivity in ultra-thin crystals (of thickness equal to the transverse structural periodicity distance d for…

Superconductivity · Physics 2012-02-03 Dale R. Harshman , Anthony T. Fiory
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