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We report a detailed theoretical study of the bonding and conduction properties of an hydrogen molecule joining either platinum or palladium electrodes. We show that an atomic arrangement where the molecule is placed perpendicular to the…

Materials Science · Physics 2007-05-23 V. M. Garcia-Suarez , A. R. Rocha , S. W. Bailey , C. J. Lambert , S. Sanvito , J. Ferrer

A single molecule break junction device serves as a tunable model system for probing the many body Kondo state. The low-energy properties of this state are commonly described in terms of a Kondo model, where the response of the system to…

Strongly Correlated Electrons · Physics 2013-06-28 Gavin D. Scott , Douglas Natelson , Stefan Kirchner , Enrique Muñoz

We provide a simple set of rules for predicting interference effects in off-resonant transport through single-molecule junctions. These effects fall in two classes, showing respectively an odd or an even number of nodes in the linear…

Mesoscale and Nanoscale Physics · Physics 2014-09-12 Kim G. L. Pedersen , Mikkel Strange , Martin Leijnse , Per Hedegård , Gemma Solomon , Jens Paaske

We study dc-transport and magnetization dynamics in a junction of arbitrary transparency consisting of two spin-singlet superconducting leads connected via a single classical spin precessing at the frequency $\Omega$. The presence of the…

Mesoscale and Nanoscale Physics · Physics 2010-05-06 S. Teber , C. Holmqvist , M. Fogelstrom

Understanding how the mechanism of charge transport through molecular tunnel junctions depends on temperature is crucial to control electronic function in molecular electronic devices. With just a few systems investigated as a function of…

Mesoscale and Nanoscale Physics · Physics 2016-05-27 Alvar R. Garrigues , Lejia Wang , Enrique del Barco , Christian A. Nijhuis

The phase behavior of a cross-linked polymer blend made of two incompatible species, $A$ and $B$, of different chemical nature is analyzed. Besides a homogeneous phase, this system also exhibits two microphases and a phase of total…

Condensed Matter · Physics 2007-05-23 Edilson Vargas , Marcia C. Barbosa

We propose an objective and robust method to extract the electrical conductance of single molecules connected to metal electrodes from a set of measured conductance data. Our method roots in the physics of tunneling and is tested on…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. Teresa González , Songmei Wu , Roman Huber , Sense J. van der Molen , Christian Schönenberger , Michel Calame

We measure the low bias conductance of a series of substituted benzene diamine molecules while breaking a gold point contact in a solution of the molecules. Transport through these substituted benzenes is by means of nonresonant tunneling…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Latha Venkataraman , Young S. Park , Adam C. Whalley Colin Nuckolls , Mark S. Hybertsen , Michael L. Steigerwald

We present a first-principles investigation to show that the contact conductance of a half conductance quantum ($G_0/2$) found previously does not generally hold for single-atom magnetic junctions composed of a tip and an adatom dsorbed on…

Mesoscale and Nanoscale Physics · Physics 2013-06-17 Yi-qun Xie , Qiang Li , Lei Huang , Xiang Ye , San-Huang Ke

We have measured the effect of bonding of a CO molecule on the conductance of Au, Cu, Pt, and Ni atomic contacts at 4.2 K. When CO gas is admitted to the metal nano contacts, a conductance feature appears in the conductance histogram near…

Materials Science · Physics 2015-06-25 M. Kiguchi , D. Djukic , J. M. van Ruitenbeek

We have studied the effect of thermal effects on the structural and transport response of Ag atomic-size nanowires generated by mechanical elongation. Our study involves both time-resolved atomic resolution transmission electron microscopy…

Materials Science · Physics 2012-06-13 M. J. Lagos , P. A. S. Autreto , D. S. Galvao , D. Ugarte

Redox molecular junctions are molecular conduction junctions that involve more than one oxidation state of the molecular bridge. This property is derived from the ability of the molecule to transiently localize transmitting electrons,…

Mesoscale and Nanoscale Physics · Physics 2013-06-21 Agostino Migliore , Abraham Nitzan

We investigate on the same footing the time-dependent electronic transport properties and vibrational dynamics of a molecular junction. We show that fluctuations of both the molecular vibron displacement and the electronic current across…

Mesoscale and Nanoscale Physics · Physics 2019-03-27 Rémi Avriller , R Souto , A. Martin-Rodero , A Yeyati

We report the fabrication and photoluminescence properties of laterally-coupled GaAs/AlGaAs quantum dots. The coupling in the quantum dot molecules is tuned by an external electric field. An intricate behavior, consisting of spectral line…

Materials Science · Physics 2011-11-09 L. Wang , A. Rastelli , S. Kirawittaya , M. Benyoucef , O. G. Schmidt

The breaking of a chemical bond is fundamental in most chemical reactions. To understand chemical processes in heterogeneous catalysis or on-surface polymerization the study of bond dissociation in molecules adsorbed on crystalline surfaces…

Chemical Physics · Physics 2023-08-07 Donato Civita , Jutta Schwarz , Stefan Hecht , Leonhard Grill

Many nanoelectronic devices rely on thin dielectric barriers through which electrons tunnel. For instance, aluminium oxide barriers are used as Josephson junctions in superconducting electronics. The reproducibility and drift of circuit…

Mesoscale and Nanoscale Physics · Physics 2020-02-05 M. J. Cyster , J. S. Smith , J. A. Vaitkus , N. Vogt , S. P. Russo , J. H. Cole

The effect of anchoring group on the electrical conductance of a single molecule bridging two Au electrodes was studied using di-substituted (isocyanide (CN-), thiol (S-) or cyanide (NC-)) benzene. The conductance of a single…

Materials Science · Physics 2009-11-11 Manabu Kiguchi , Shinichi Miura , Kenji Hara , Masaya Sawamura , Kei Murakoshi

The influence of decoherence and bonding on the linear conductance of single double-stranded DNA molecules is examined by fitting a phenomenological statistical model developed recently (EPJB {\bf 68}, 237 (2009)) to experimental results.…

Soft Condensed Matter · Physics 2010-09-30 M. Zilly , O. Ujsaghy , D. E. Wolf

The solid-state structures of organic charge transfer (CT) salts are critical in determining their mode of charge transport, and hence their unusual electrical properties, which range from semiconducting through metallic to superconducting.…

Mesoscale and Nanoscale Physics · Physics 2016-01-05 Andrea Vezzoli , Iain Grace , Carly Brooke , Kun Wang , Colin J. Lambert , Bingqian Xu , Richard J. Nichols , Simon J. Higgins

We investigate charge transport in C$_{60}$-based single-molecule junctions with graphene electrodes employing a combination of density functional theory (DFT) electronic structure calculations and Landauer transport theory. In particular,…

Mesoscale and Nanoscale Physics · Physics 2017-01-12 Susanne Leitherer , Pedro B. Coto , Konrad Ullmann , Heiko B. Weber , Michael Thoss