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Nitrogen doping of the carbon is an important method to improve the performance and durability of catalysts for proton exchange membrane fuel cells by platinum-nitrogen and carbon-nitrogen bonds. This study shows that p-phenyl groups and…

The relaxation dynamics of photoexcited quasiparticles of three-dimensional (3D) Dirac semimetals are vital towards their application in high performance electronic and optoelectronic devices. In this work, the relaxation dynamics of…

Optics · Physics 2018-10-03 Wei Lu , Jiwei Ling , Faxian Xiu , Dong Sun

Making devices with graphene necessarily involves making contacts with metals. We use density functional theory to study how graphene is doped by adsorption on metal substrates and find that weak bonding on Al, Ag, Cu, Au and Pt, while…

Materials Science · Physics 2009-11-13 G. Giovannetti , P. A. Khomyakov , G. Brocks , V. M. Karpan , J. van den Brink , P. J. Kelly

We show that charge doping can induce transitions between three distinct adsorbate phases in hydrogenated and fluorinated graphene. By combining ab initio, approximate density functional theory and tight binding calculations we identify a…

Mesoscale and Nanoscale Physics · Physics 2014-10-10 Tim Wehling , Bernhard Grundkötter-Stock , Bálint Aradi , Thomas Niehaus , Thomas Frauenheim

Graphene is an ideal material for integrated nonlinear optics thanks to its strong light-matter interaction and large nonlinear optical susceptibility. Graphene has been used in optical modulators, saturable absorbers, nonlinear frequency…

The linear, gapless bandstructure of graphene provides ideal conditions for Auger processes. They are of great importance for fundamental research and technological applications, since they qualitatively change the carrier dynamics. Time-,…

Mesoscale and Nanoscale Physics · Physics 2015-01-20 Torben Winzer , Ermin Malic

Since lattice strain and charge density affect various material properties of graphene, a reliable and efficient method is required for quantification of the two variables. While Raman spectroscopy is sensitive and non-destructive, its…

Mesoscale and Nanoscale Physics · Physics 2020-08-10 Gwanghyen Ahn , Sunmin Ryu

Graphene, a one-atom thick zero gap semiconductor [1, 2], has been attracting an increasing interest due to its remarkable physical properties ranging from an electron spectrum resembling relativistic dynamics [3-12] to ballistic transport…

Mesoscale and Nanoscale Physics · Physics 2011-11-09 T. O. Wehling , K. S. Novoselov , S. V. Morozov , E. E. Vdovin , M. I. Katsnelson , A. K. Geim , A. I. Lichtenstein

Controlled modulation of electronic band structure in two-dimensional (2D) materials via doping is crucial for devices fabrication. For instance doped graphene has been envisaged for various applications like sensors, super-capacitors,…

Materials Science · Physics 2025-01-08 Imtiaz Noor Bhatti , J. Avila , Z. Chen , A. Baron , Y. Zhang , A. Shukla , P. Dudin

Motivated by a recent experiment reporting on the possible application of graphene as sensors, we calculate transport properties of 2D graphene monolayers in the presence of adsorbed molecules. We find that the adsorbed molecules, acting as…

Mesoscale and Nanoscale Physics · Physics 2007-11-16 E. H. Hwang , S. Adam , S. Das Sarma

Nonlinear optical properties and carrier relaxation dynamics in graphene, suspended in three different solvents, are investigated using femtosecond (80 fs pulses) Z-scan and degenerate pumpprobe spectroscopy at 790 nm. The results…

Materials Science · Physics 2015-05-14 Sunil Kumar , M. Anija , N. Kamaraju , K. S. Vasu , K. S. Subrahmanyam , A. K. Sood , C. N. R. Rao

For many of the envisioned optoelectronic applications of graphene it is crucial to understand the sub-picosecond carrier dynamics immediately following photoexcitation, as well as the effect on the electrical conductivity - the…

Novel uses for 2-dimensional materials like graphene and hexagonal boron nitride (h-BN) are being frequently discovered especially for membrane and catalysis applications. Still however, a great deal remains to be understood about the…

Materials Science · Physics 2016-05-25 Yasmine S. Al-Hamdani , Dario Alfè , O. Anatole von Lilienfeld , Angelos Michaelides

On the basis of self-consistent Born approximation for Dirac fermions under charged impurity scatterings in graphene, the theory for calculating the thermo-electric power is developed by using the heat current-current correlation function.…

Strongly Correlated Electrons · Physics 2009-10-23 Xin-Zhong Yan , Yousef Romiah , C. S. Ting

The remarkable gapless and linear band structure of graphene opens up new carrier relaxation channels bridging the valence and the conduction band. These Auger scattering processes change the number of charge carriers and can give rise to a…

Mesoscale and Nanoscale Physics · Physics 2017-01-17 Ermin Malic , Torben Winzer , Florian Wendler , Andreas Knorr

Ab-initio density functional perturbation theory (DFPT) has been employed to study thermodynamical properties of pure and doped graphene sheet and the results have been compared with available theoretical and experimental data. The…

Mesoscale and Nanoscale Physics · Physics 2020-05-22 Sarita Mann , Pooja Rani , Ranjan Kumar , Girija S. Dubey , V. K. Jindal

Graphene is a promising candidate for optoelectronic applications such as photodetectors, terahertz imagers, and plasmonic devices. The origin of photoresponse in graphene junctions has been studied extensively and is attributed to either…

Mesoscale and Nanoscale Physics · Physics 2013-01-30 Marcus Freitag , Tony Low , Fengnian Xia , Phaedon Avouris

The unusual electrical and optical properties of graphene make it a promising candidate for optoelectronic applications. An important, but as yet unexplored aspect is the role of photo-excited hot carriers in charge and energy transport at…

Mesoscale and Nanoscale Physics · Physics 2011-08-18 Dong Sun , Grant Aivazian , Aaron M. Jones , Wang Yao , David Cobden , Xiaodong Xu

Graphene is a 2-dimensional material with high carrier mobility and thermal conductivity, suitable for high-speed electronics. Conduction and valence bands touch at the Dirac point. The absorptivity of single-layer graphene is 2.3%, nearly…

Mesoscale and Nanoscale Physics · Physics 2010-10-11 Marcus Freitag , Hsin-Ying Chiu , Mathias Steiner , Vasili Perebeinos , Phaedon Avouris

Two-dimensional (2d) nano-electronics, plasmonics, and emergent phases require clean and local charge control, calling for layered, crystalline acceptors or donors. Our Raman, photovoltage, and electrical conductance measurements combined…